Developing measures of quantum ergodicity and chaos stands as a foundational task in the study of quantum many-body systems. In this work, we propose metrics for these effects based on Hamiltonian learning that unify multiple advantages of existing metrics. In particular, we show how ergodicity and chaos improve the robustness of Hamiltonian learning to small errors and furthermore demonstrate that this robustness can be used as a metric for such phenomena. We analytically and numerically show that our metrics not only distinguish between integrable and ergodic regimes in various spin chains but also quantify chaos and ergodicity, allowing us to locate regions of parameter space displaying maximal ergodicity and maximal sensitivity to local perturbations. Our approach not only provides conceptual ways to study quantum chaos and ergodicity but also presents viable experimental methods for quantum simulators.
We demonstrate that realistic excitonic many-body Hamiltonians obtained from first-principles GW-Bethe-Salpeter equation calculations can exhibit quantum chaos governed by random-matrix universality. Considering a prototypical van der Waals heterostructure (WS
2-graphene), with and without lattice disorder, we analyze their energy-resolved spectral correlations and identify a disorder-driven crossover from regular to complete chaotic dynamics. We show that while pristine samples exhibit incomplete chaos (non-ergodicity) due to an approximate valley symmetry that restricts excitonic mixing, the presence of disorder-induced electronic flat bands act as a catalyst for valley mixing to drive the system into a fully developed chaotic (ergodic) regime with reduced symmetry. Crucially, fluctuations in many-body oscillator strengths are shown to follow universal Porter-Thomas statistics, directly linking the underlying quantum chaos and experimentally accessible optical observables. Finally, by examining long-range spectral correlations, we estimate the Thouless time associated to excitonic mixing across the entire many-body bandwidth. Our results establish excitons as a highly tunable platform for probing many-body ergodicity and its spectroscopic signatures in realistic interacting 2D materials.
Quantum chaos remains a challenging concept because classical signatures of chaos do not directly transfer to quantum systems. This thesis investigates which indicators of chaos are shared between classical and quantum mechanics and how they can be used to characterise non-integrable many-body systems. We examine ergodicity and thermalisation by means of the Eigenstate Thermalisation Hypothesis (ETH) as signatures of non-integrability, and study the Out-of-Time-Ordered Correlator (OTOC) as a probe of information scrambling and as a measure of sensitivity to initial conditions. We briefly discuss the appearance of chaotic wavefunctions and observations such as quantum scars and quantum ergodicity in individual eigenmodes of the Bunimovich stadium potential. Using the OTOC, we discuss extensions of the Lyapunov exponent to quantum systems and apply these ideas to the Sachdev–Ye–Kitaev (SYK) model. In the large-N limit, and using the AdS/CFT correspondence, we find that the model might potentially be the dual of a black hole and that it is maximally chaotic. We conclude by discussing additional proposed signatures of quantum chaos and prospects for experimental realisations of the SYK model.