Optimal (reversible) processes in thermodynamics can be modelled as step-by-step processes, where the system is successively thermalized with respect to different Hamiltonians by an external thermal bath. However, in practice interactions between system and thermal bath will take finite time, and precise control of their interaction is usually out of reach. Motivated by this observation, we consider finite-time and uncontrolled operations between system and bath, which result in thermalizations that are only partial in each step. We show that optimal processes can still be achieved for any non-trivial partial thermalizations at the price of increasing the number of operations, and characterise the corresponding tradeoff. We focus on work extraction protocols and show our results in two different frameworks: A collision model and a model where the Hamiltonian of the working system is controlled over time and the system can be brought into contact with a heat bath. Our results show that optimal processes are robust to noise and imperfections in small quantum systems, and can be achieved by a large set of interactions between system and bath.Optimal (reversible) processes in thermodynamics can be modelled as step-by-step processes, where the system is successively thermalized with respect to different Hamiltonians by an external thermal bath. However, in practice interactions between system and thermal bath will take finite time, and precise control of their interaction is usually out of reach. Motivated by this observation, we consider finite-time and uncontrolled operations between system and bath, which result in thermalizations that are only partial in each step. We show that optimal processes can still be achieved for any non-trivial partial thermalizations at the price of increasing the number of operations, and characterise the corresponding tradeoff. We focus on work extraction protocols and show our results in two different frameworks: A collision model and a model where the Hamiltonian of the working system is controlled over time and the system can be brought into contact with a heat bath. Our results show that optimal processes are robust to noise and imperfections in small quantum systems, and can be achieved by a large set of interactions between system and bath.

Jun 24, 201920 citations

Finite steps optimise dissipation in stochastically controlled quantum systems

Theodore McKeever, Harry J. D. Miller, Ahsan Nazir

Motivated by the need for precise, energy-efficient, and experimentally realistic quantum control protocols, we investigate the thermodynamic cost of performing quantum step-equilibration processes under the influence of classical stochastic control fields. Whereas purely deterministic protocols exhibit dissipation that scales inversely with the number of steps, we show that weak Gaussian noise in the control variables induces dissipative contributions that grow linearly with the number of steps. Consequently, we derive the finite optimal number of steps and minimal achievable average dissipated work and its variance using the quantum thermodynamic length. These results are demonstrated using two paradigmatic examples: a Landau-Zener sweep of a qubit strongly coupled to a thermal bath and the erasure of a transverse-field Ising model.Motivated by the need for precise, energy-efficient, and experimentally realistic quantum control protocols, we investigate the thermodynamic cost of performing quantum step-equilibration processes under the influence of classical stochastic control fields. Whereas purely deterministic protocols exhibit dissipation that scales inversely with the number of steps, we show that weak Gaussian noise in the control variables induces dissipative contributions that grow linearly with the number of steps. Consequently, we derive the finite optimal number of steps and minimal achievable average dissipated work and its variance using the quantum thermodynamic length. These results are demonstrated using two paradigmatic examples: a Landau-Zener sweep of a qubit strongly coupled to a thermal bath and the erasure of a transverse-field Ising model.

quant-pharXiv:2605.04681May 7, 20260 citations

Second law of thermodynamics under control restrictions

Henrik Wilming, R. Gallego, Jens Eisert

The second law of thermodynamics, formulated as an ultimate bound on the maximum extractable work, has been rigorously derived in multiple scenarios. However, the unavoidable limitations that emerge due to the lack of control on small systems are often disregarded when deriving such bounds, which is specifically important in the context of quantum thermodynamics. Here we study the maximum extractable work with limited control over the working system and its interaction with the heat bath. We derive a general second law when the set of accessible Hamiltonians of the working system is arbitrarily restricted. We then apply our bound to particular scenarios that are important in realistic implementations: limitations on the maximum energy gap and local control over many-body systems. We hence demonstrate in what precise way the lack of control affects the second law. In particular, contrary to the unrestricted case, we show that the optimal work extraction is not achieved by simple thermal contacts. Our results not only generalize the second law to scenarios of practical relevance, but also take first steps in the direction of local thermodynamics.The second law of thermodynamics, formulated as an ultimate bound on the maximum extractable work, has been rigorously derived in multiple scenarios. However, the unavoidable limitations that emerge due to the lack of control on small systems are often disregarded when deriving such bounds, which is specifically important in the context of quantum thermodynamics. Here we study the maximum extractable work with limited control over the working system and its interaction with the heat bath. We derive a general second law when the set of accessible Hamiltonians of the working system is arbitrarily restricted. We then apply our bound to particular scenarios that are important in realistic implementations: limitations on the maximum energy gap and local control over many-body systems. We hence demonstrate in what precise way the lack of control affects the second law. In particular, contrary to the unrestricted case, we show that the optimal work extraction is not achieved by simple thermal contacts. Our results not only generalize the second law to scenarios of practical relevance, but also take first steps in the direction of local thermodynamics.

arXiv:1411.3754Physical review. EApr 22, 201665 citations

Cooling and work extraction under memory-assisted Markovian thermal processes

Yuancheng Liu, Xueyuan Hu

We investigate the limits on cooling and work extraction via Markovian thermal processes assisted by a finite-dimensional memory. Here the memory is a $d$ -dimensional quantum system with trivial Hamiltonian and initially in a maximally mixed state. For cooling a qubit system, we consider two paradigms: cooling under coherent control and cooling under incoherent control. For both paradigms, we derive the optimal ground-state populations under the set of general thermal processes (TP) and the set of Markovian thermal processes (MTP), and we further propose memory-assisted protocols, which bridge the gap between the performances of TP and MTP. For the task of work extraction, we prove that when the target system is a qubit in the excited state the minimum extraction error achieved by TP can be approximated by Markovian thermal processes assisted by a large enough memory. Our results can bridge the performances of TP and MTP in thermodynamic tasks including cooling and work extraction.We investigate the limits on cooling and work extraction via Markovian thermal processes assisted by a finite-dimensional memory. Here the memory is a $d$-dimensional quantum system with trivial Hamiltonian and initially in a maximally mixed state. For cooling a qubit system, we consider two paradigms: cooling under coherent control and cooling under incoherent control. For both paradigms, we derive the optimal ground-state populations under the set of general thermal processes (TP) and the set of Markovian thermal processes (MTP), and we further propose memory-assisted protocols, which bridge the gap between the performances of TP and MTP. For the task of work extraction, we prove that when the target system is a qubit in the excited state the minimum extraction error achieved by TP can be approximated by Markovian thermal processes assisted by a large enough memory. Our results can bridge the performances of TP and MTP in thermodynamic tasks including cooling and work extraction.

arXiv:2306.06883Physical Review ASep 22, 20231 citation

Correlated thermal machines in the micro-world

R. Gallego, Arnau Riera, Jens Eisert

How much work can be extracted from a heat bath using a thermal machine operating at the quantum level? In this work, we establish a framework of work extraction in the presence of quantum correlations as they naturally emerge in quantum thermodynamics beyond the weak-coupling regime. Quantum correlations and entanglement, as they are ubiquitously encountered when putting systems into contact with a bath, emerge as a limitation to work extraction, rather than as an advantage. We bring together concepts of quantum thermodynamics with those of non-equilibrium dynamics, in a rigorous but physically motivated approach. We discuss various limits that relate to known results and put our work into context of approaches to finite-time quantum thermodynamics.How much work can be extracted from a heat bath using a thermal machine operating at the quantum level? In this work, we establish a framework of work extraction in the presence of quantum correlations as they naturally emerge in quantum thermodynamics beyond the weak-coupling regime. Quantum correlations and entanglement, as they are ubiquitously encountered when putting systems into contact with a bath, emerge as a limitation to work extraction, rather than as an advantage. We bring together concepts of quantum thermodynamics with those of non-equilibrium dynamics, in a rigorous but physically motivated approach. We discuss various limits that relate to known results and put our work into context of approaches to finite-time quantum thermodynamics.

Oct 30, 20131 citation

Quantum thermodynamics with local control

Jaqueline Lekscha, Henrik Wilming, Jens Eisert +1 more

We investigate the limitations that emerge in thermodynamic tasks as a result of having local control only over the components of a thermal machine. These limitations are particularly relevant for devices composed of interacting many-body systems. Specifically, we study protocols of work extraction that employ a many-body system as a working medium whose evolution can be driven by tuning the on-site Hamiltonian terms. This provides a restricted set of thermodynamic operations, giving rise to alternative bounds for the performance of engines. Our findings show that those limitations in control render it, in general, impossible to reach Carnot efficiency; in its extreme ramification it can even forbid to reach a finite efficiency or finite work per particle. We focus on the one-dimensional Ising model in the thermodynamic limit as a case study. We show that in the limit of strong interactions the ferromagnetic case becomes useless for work extraction, while the antiferromagnetic case improves its performance with the strength of the couplings, reaching Carnot in the limit of arbitrary strong interactions. Our results provide a promising connection between the study of quantum control and thermodynamics and introduce a more realistic set of physical operations well suited to capture current experimental scenarios.We investigate the limitations that emerge in thermodynamic tasks as a result of having local control only over the components of a thermal machine. These limitations are particularly relevant for devices composed of interacting many-body systems. Specifically, we study protocols of work extraction that employ a many-body system as a working medium whose evolution can be driven by tuning the on-site Hamiltonian terms. This provides a restricted set of thermodynamic operations, giving rise to alternative bounds for the performance of engines. Our findings show that those limitations in control render it, in general, impossible to reach Carnot efficiency; in its extreme ramification it can even forbid to reach a finite efficiency or finite work per particle. We focus on the one-dimensional Ising model in the thermodynamic limit as a case study. We show that in the limit of strong interactions the ferromagnetic case becomes useless for work extraction, while the antiferromagnetic case improves its performance with the strength of the couplings, reaching Carnot in the limit of arbitrary strong interactions. Our results provide a promising connection between the study of quantum control and thermodynamics and introduce a more realistic set of physical operations well suited to capture current experimental scenarios.

arXiv:1612.00029Physical review. EFeb 27, 201831 citations

We investigate the limits on cooling and work extraction via Markovian thermal processes assisted by a finite-dimensional memory. Here the memory is a

d

-dimensional quantum system with trivial Hamiltonian and initially in a maximally mixed state. For cooling a qubit system, we consider two paradigms: cooling under coherent control and cooling under incoherent control. For both paradigms, we derive the optimal ground-state populations under the set of general thermal processes (TP) and the set of Markovian thermal processes (MTP), and we further propose memory-assisted protocols, which bridge the gap between the performances of TP and MTP. For the task of work extraction, we prove that when the target system is a qubit in the excited state the minimum extraction error achieved by TP can be approximated by Markovian thermal processes assisted by a large enough memory. Our results can bridge the performances of TP and MTP in thermodynamic tasks including cooling and work extraction.