Motivated by the recent observation that exponentially long coherence times can be achieved for edge spins in models with strong zero modes, we study the impact of level crossings in finite-length spin chains on the dynamics of the edge spins. Focusing on the $XY$ spin-$1/2$ chain with a transverse or longitudinal magnetic field, two models relevant to understanding recent experimental results on cobalt adatoms, we show that the edge spins can remain coherent for an infinite time even for a finite-length chain if the magnetic field is tuned to a value at which there is a level crossing. Furthermore, we show that the edge spins remain coherent for any initial state for the integrable case of a transverse field because all states have level crossings at the same value of the field, while the coherence time is increasingly large for lower temperatures in the case of a longitudinal field, which is nonintegrable.
Motivated by the recent observation that exponentially long coherence times can be achieved for edge spins in models with strong zero modes, we study the impact of level crossings in finite-length spin chains on the dynamics of the edge spins. Focusing on the XY spin-1/2 chain with a transverse or longitudinal magnetic field, two models relevant to understanding recent experimental results on cobalt adatoms, we show that the edge spins can remain coherent for an infinite time even for a finite-length chain if the magnetic field is tuned to a value at which there is a level crossing. Furthermore, we show that the edge spins remain coherent for any initial state for the integrable case of a transverse field because all states have level crossings at the same value of the field, while the coherence time is increasingly large for lower temperatures in the case of a longitudinal field, which is nonintegrable.
Abstract We show that in certain one-dimensional spin chains with open boundary conditions, the edge spins retain memory of their initial state for very long times, even at infinite temperature. The long coherence times do not require disorder, only an ordered phase. In the integrable Ising and XYZ chains, the presence of a strong zero mode means the coherence time is infinite. When Ising is perturbed by interactions breaking the integrability, the coherence time remains exponentially long in the perturbing couplings. We show that this is a consequence of an edge ‘almost’ strong zero mode that almost commutes with the Hamiltonian. We compute this operator explicitly, allowing us to estimate accurately the plateau value of edge spin autocorrelator.
I will discuss how edge spins in certain one-dimensional spin chains retain memory of their initial state for very long times, even with interactions and at infinite temperature. These long coherence times do not require disorder or integrability. I will show how this is a consequence of an "almost" strong edge zero mode that almost commutes with the Hamiltonian, and explain how to compute this operator explicitly with computer-aided algebra. I will examine the effect of this almost strong zero mode on the behaviour of a wide variety of one-dimensional systems analytically, from the ground state to infinite temperature, and from finite size to the thermodynamic limit. I will also examine the effect of the almost strong zero mode on the eigenstate spectrum and the matrix elements of the edge spin, and show that despite the long coherence time of the edge spin, the almost strong zero mode does not induce degeneracies in the entire spectrum, unlike its counterpart exact strong zero mode in non-interacting systems. At special values of the couplings, resonances dramatically limit the coherence time. I will explain how these resonances are related to physical processes which flip the edge spin for no change in the energy of the system, and calculate the coupling strengths for which they appear. I will propose an experimental test of the almost strong zero mode and the long coherence time of the edge spin in a trapped ion chain which is feasible to implement with current technology. Lastly, I will explain how these almost strong edge zero modes in a system with symmetry-protected topological order can be used to form a boundary qubit with both long decoherence and dephasing times.
The topological phase of a one-dimensional triplet superconductor support fractionalized edge states described by Majorana fermions. Generically, these edge states are not completely decoupled. Their wave functions decay exponentially, and the tails induce a coupling that decays exponentially with the length of the system. This is not the whole story, however. In an appropriate parameter range (if the pairing is smaller than the hopping in the simplest model, the Kitaev model), the Majorana wave functions oscillate on top of decaying, and these oscillations induce exact zero modes, at which the Majorana edge states are rigorously decoupled. In the present paper, motivated by the observation of ground-state level crossings in chains of cobalt adatoms, which, up to a Jordan-Wigner transformation, are described by the same model, the authors explicitly calculate the Majorana edge-state wave functions, and they fully characterize the number and positions of the level crossings induced by the wave-function oscillations.
The work presented in this thesis is divided into two main parts: strong zero modes in quantum spin chains with open boundaries and large deviations in classical spin systems. The results concerning the strong zero modes are presented in chapters 2 and 3, while chapter 4 contains the results about large deviations in systems of many, but independent, classical degrees of freedom. These two distinct classes of problems in spin chains are both about aspects of slow relaxation to equilibrium in many-body systems. Nowadays slow dynamics and non-ergodicity in many-body quantum systems are receiving much attention due to their notable technological potential for storing and processing, for very long times, the quantum information encoded in boundary degrees of freedom. In the first part of the work presented in this thesis we mainly focus on quantum spin chains with open boundaries, which can display coherence times for edge spins, that diverge with the system size, as a consequence of the emergence, in the thermodynamic limit, of conserved local quantities, called strong zero modes. First, we discuss the fate of these coherence times when dynamics becomes dissipative. Understanding the behavior of these long correlation times in open quantum systems, undergoing Markovian (memoryless) dynamics, would allow for the possibility of exploiting the protected information encoded in the boundary spins for applications in quantum devices in realistic non-equilibrium settings. Second, we study one possible simple generalization of the transverse field Ising model to a class of ladder spin systems with plaquette interactions in the presence of a transverse field. Also for these systems one can explicitly construct the strong zero mode operators and understand the behavior of the consequential long coherence times for the edge degrees of freedom under isolated (unitary) dynamics. This is possible because the models we consider, while appearing complex superficially, can be brought to simple forms by exploiting an extensive number of conserved quantities they possess. The results presented in chapters 2 and 3 are closely related, even if they focus on different models and investigate different aspects of their dynamics. Nevertheless, the underlying concept they are based on is the same one, that is, an eigenstate phase transition for the strong zero modes that has interesting consequences for the full energy spectrum. In the second part of the thesis we focus on a different type of phase transitions. Here we address the issue of dynamical large deviation phase transitions from a disordered phase to an ordered one, in classical systems which consist in a collection of independent Ising spins evolving stochastically. Surprisingly, by reweighing trajectories accordingly to a certain type of time-integrated observable, even a system of independently evolving spins can display some critical behavior, at the fluctuation level, in trajectory space in the large size and long time limit. By making use of the tilted generator techniques we study the statistics of two particular time-integrated observables. Their associated tilted generators have an exact Kramers-Wannier duality and they look like, up to a sign and an additive constant, some specific well known quantum Hamiltonians. In this sense, the dynamical large deviation phase transitions we observe in these classical stochastic systems translate in ground state quantum phase transitions taking place at the self dual point of the tilted generators we study.
We investigate the occurrence of exact zero modes in one-dimensional quantum magnets of finite length that possess edge states. Building on conclusions first reached in the context of the spin-1/2XY chain in a field and then for the spin-$1{J}_{1}\ensuremath{-}{J}_{2}$ Heisenberg model, we show that the development of incommensurate correlations in the bulk invariably leads to oscillations in the sign of the coupling between edge states, and hence to exact zero energy modes at the crossing points where the coupling between the edge states rigorously vanishes. This is true regardless of the origin of the frustration (e.g., next-nearest-neighbor coupling or biquadratic coupling for the spin-1 chain), of the value of the bulk spin (we report on spin-1/2, spin-1, and spin-2 examples), and of the value of the edge-state emergent spin (spin-1/2 or spin-1).
We derive exact strong zero mode (ESZM) operators for integrable spin-S chains with open boundary conditions and a boundary field. Their locality properties are generally weaker than in the previously known cases, but they still imply infinite coherence times in the vicinity of the edges. We explain how such integrable chains possess multiple ground states describing a first-order quantum phase transition, and that the odd number of such states for integer S makes the weaker locality properties necessary. We make contact with more traditional approaches by showing how the ESZM for S=1/2 acts on energy eigenstates given by solutions of the Bethe equations.