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arXiv:1709.07289 · Quantum Studies Mathematics and Foundations

On the equivalence of complex and quaternionic quantum mechanics

Jonathan Gantner

Published Nov 2, 2017• 30 citations
arXivHTMLPDF
DOI
10.1007/s40509-017-0147-5

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Abstract In this chapter we discuss a number of methods for handling stationary state problems in quaternionic quantum mechanics and then consider more generally methods in which the phase of the wave function plays a primary role. We first describe exact methods for reducing the anti Hermitian quaternionic Hamiltonian H to a complex Hermitian Hamiltonian H for an equivalent complex quantum mechanics problem. We then develop stationary state perturbation theory, and as an application compute the leading approximation to the Hamiltonian phase operator IH. We also give a quaternionic analog of the Rayleigh-Ritz variational principle. We proceed next to an extended discussion of the geometric phase in quaternionic quantum mechanics, in both the adiabatic and the nonadiabatic cases. Finally, we give the quaternionic generalization of the eikonal or WKB approximation.
While real Hamiltonian mechanics and Hermitian quantum mechanics can both be cast in the framework of complex canonical equations, their complex generalizations have hitherto remained tangential. In this communication, quaternionic and coquaternionic (split-signature analogue of quaternions) extensions of Hamiltonian mechanics are introduced and are shown to offer a unifying framework for complexified classical and quantum mechanics. In particular, quantum theories characterized by complex Hamiltonians invariant under spacetime reflection are shown to be equivalent to certain coquaternionic extensions of Hermitian quantum theories. One of the interesting consequences is that the spacetime dimension of these systems is six, not four, on account of the structures of coquaternionic quantum mechanics.