Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:1707.06584 · Journal of Mathematical Physics

Fundamental limits on quantum dynamics based on entropy change

Siddhartha Das, Sumeet Khatri, George Siopsis, Mark M. Wilde

Published Jan 1, 2018• 50 citations
arXivHTMLPDF

Abstract

It is well known in the realm of quantum mechanics and information theory that the entropy is non-decreasing for the class of unital physical processes. However, in general, the entropy does not exhibit monotonic behavior. This has restricted the use of entropy change in characterizing evolution processes. Recently, a lower bound on the entropy change was provided in the work of Buscemi, Das, and Wilde [Phys. Rev. A 93(6), 062314 (2016)]. We explore the limit that this bound places on the physical evolution of a quantum system and discuss how these limits can be used as witnesses to characterize quantum dynamics. In particular, we derive a lower limit on the rate of entropy change for memoryless quantum dynamics, and we argue that it provides a witness of non-unitality. This limit on the rate of entropy change leads to definitions of several witnesses for testing memory effects in quantum dynamics. Furthermore, from the aforementioned lower bound on entropy change, we obtain a measure of non-unitarity for unital evolutions.

DOI
10.1063/1.4997044

Related papers

How rare are Markovian quantum dynamics?

Charlotte Bäcker, Nick Maryshchak, Walter T. Strunz

A profound understanding of decoherence and dissipation in quantum dynamics is crucial for the realistic modeling of the evolution of quantum systems. In open quantum dynamics one distinguishes between a memoryless, so-called Markovian evolution and dynamics incorporating memory effects, termed non-Markovian. In this work we study how prevalent memory effects are in the set of all such dynamics. We thus investigate how often a Markovian description is applicable. This question is approached by investigating randomly generated two-step qubit dynamics with respect to different concepts and witnesses of non-Markovianity. We observe that almost all dynamics are non-Markovian, and only a small (yet finite) fraction is Markovian. Furthermore, we study how this proportion changes when considering certain subclasses such as lower rank or mixed-unitary dynamics. Importantly, our results shed light on the relative ratios of -- and interrelations between -- the sets of dynamics that are non-Markovian with respect to different criteria. Finally, we investigate the fraction of dynamics in which the memory effects are necessarily of quantum nature and establish a connection between two recently developed concepts that characterize the quantumness of memory in non-Markovian dynamics.

quant-pharXiv:2606.24511•Jun 24, 2026•0 citations

Non-Markovianity and memory effects in quantum open systems

S. C. Hou, Shiuan-Ni Liang, X. X. Yi

Although a number of measures for quantum non-Markovianity have been proposed recently, it is still an open question whether these measures directly characterize the memory effect of the environment, i.e., the dependence of a quantum state on its past in a time evolution. In this paper, we present a criterion and propose a measure for non-Markovianity with clear physical interpretations of the memory effect. The non-Markovianity is defined by the inequality $T({t}_{2},{t}_{0})\ensuremath{\ne}T({t}_{2},{t}_{1})T({t}_{1},{t}_{0})$ in terms of memoryless dynamical map $T$ introduced in this paper. This definition is conceptually distinct from that based on divisibility used by Rivas et al. [Phys. Rev. Lett. 105, 050403 (2010)], whose violation is manifested by noncomplete positivity of the dynamical map. We demonstrate via a typical quantum process that without Markovian approximation, nonzero memory effects (non-Markovianity) always exist even if the non-Markovianity is zero by the other non-Markovianity measures.

arXiv:1501.06712•Physical Review A•Jan 15, 2015•36 citations

Formulations of Quantum Thermodynamics and Applications in Open Systems

J. M. Z. Choquehuanca

Quantum thermodynamics has emerged as a central field for understanding how energy conversion processes occur in microscopic systems. In these systems, effects such as coherence, entanglement, and non-Markovianity play key roles. In this thesis, we explore different ways to describe quantum thermodynamics, using two main approaches: one based on entropy and the other on ergotropy. First, we introduce a generalized approach to quantify non-Markovianity through the breakdown of monotonicity in thermodynamic functions. In this context, the entropy-based heat flow serves as a practical tool to witness and measure quantum memory in unital maps that do not reverse the sign of the internal energy. Next, we analyze the dynamics of ergotropy in open qubits under both Markovian and non-Markovian evolutions. We identify phenomena such as freezing and sudden death of ergotropy, and we establish an analytical relation between the change in ergotropy and the environment-induced work . This provides a clear physical interpretation for the additional term in the first law in the entropy-based formulation. Finally, we propose an ergotropy-based thermodynamic formulation, in which heat is reinterpreted in terms of the change of the passive state associated with the density operator governing the quantum dynamics. This approach allows one to measure non-Markovianity of unital maps more generally and accurately than the entropy-based heat flow. This advantage comes from the direct link between heat and von Neumann entropy, a property ensured by invariance under passive transformations. Moreover, the out-of-equilibrium temperature naturally remains non-negative, similarly to equilibrium thermodynamics.

quant-pharXiv:2512.00923•Dec 2, 2025•0 citations

Entropic witness for quantum memory in open system dynamics

Charlotte Bäcker, Konstantin Beyer, Walter T. Strunz

The dynamics of open quantum systems are often modeled by non-Markovian processes that account for memory effects arising from interactions with the environment. It is well known that the memory provided by the environment can be classical or quantum in nature. Remarkably, the quantumness of the memory can be witnessed locally by measurements on the open system alone, without requiring access to the environment. However, existing witnesses are computationally challenging for systems beyond qubits, which severely limits their practical applicability. In this work, we present a tractable criterion for quantum memory based on the von Neumann entropy, which is easily computable for systems of any dimension. Using this witness, we investigate the nature of memory in a class of physically motivated finite-dimensional qudit dynamics. Moreover, we demonstrate that this criterion is also suitable for detecting quantum memory in continuous-variable systems. As an illustrative example, we analyze non-Markovian Gaussian dynamics of a damped harmonic oscillator.

arXiv:2501.17660•Physical Review Research•Jul 21, 2025•3 citations

H-theorem and Maxwell demon in quantum physics

N. S. Kirsanov, A. V. Lebedev, Ivan Sadovskyy +4 more

The Second Law of Thermodynamics states that temporal evolution of an isolated system occurs with non-diminishing entropy. In quantum realm, this holds for energy-isolated systems the evolution of which is described by the so-called unital quantum channel. The entropy of a system evolving in a non-unital quantum channel can, in principle, decrease. We formulate a general criterion of unitality for the evolution of a quantum system, enabling a simple and rigorous approach for finding and identifying the processes accompanied by decreasing entropy in energy-isolated systems. We discuss two examples illustrating our findings, the quantum Maxwell demon and heating-cooling process within a two-qubit system.

arXiv:1804.06886•AIP conference proceedings•Jan 1, 2018•5 citations

Time evolution of the von Neumann entropy in open quantum system

Kohei Kobayashi

Control of open quantum dynamics is of great interest for realizing quantum technologies. Therefore, it is an important task to quantify and characterize the entropy for open quantum systems under decoherence. In this paper, we study the time evolution of the von Neumann entropy for open quantum systems described by the Lindblad master equation. Note that, in particular, when the decoherence corresponds to the measurement for the observable in the system, the von Neumann entropy tends to monotonically increases as the variance becomes larger. Furthermore, we present a lower bound of the von Neumann entropy in the long-time limit. This lower bound has advantages of being straightforwardly calculated and applicable to a general Markovian open quantum system.

arXiv:2405.11824•May 20, 2024•1 citation
It is well known in the realm of quantum mechanics and information theory that the entropy is non-decreasing for the class of unital physical processes. However, in general, the entropy does not exhibit monotonic behavior. This has restricted the use of entropy change in characterizing evolution processes. Recently, a lower bound on the entropy change was provided in the work of Buscemi, Das, and Wilde [Phys. Rev. A 93(6), 062314 (2016)]. We explore the limit that this bound places on the physical evolution of a quantum system and discuss how these limits can be used as witnesses to characterize quantum dynamics. In particular, we derive a lower limit on the rate of entropy change for memoryless quantum dynamics, and we argue that it provides a witness of non-unitality. This limit on the rate of entropy change leads to definitions of several witnesses for testing memory effects in quantum dynamics. Furthermore, from the aforementioned lower bound on entropy change, we obtain a measure of non-unitarity for unital evolutions.
A profound understanding of decoherence and dissipation in quantum dynamics is crucial for the realistic modeling of the evolution of quantum systems. In open quantum dynamics one distinguishes between a memoryless, so-called Markovian evolution and dynamics incorporating memory effects, termed non-Markovian. In this work we study how prevalent memory effects are in the set of all such dynamics. We thus investigate how often a Markovian description is applicable. This question is approached by investigating randomly generated two-step qubit dynamics with respect to different concepts and witnesses of non-Markovianity. We observe that almost all dynamics are non-Markovian, and only a small (yet finite) fraction is Markovian. Furthermore, we study how this proportion changes when considering certain subclasses such as lower rank or mixed-unitary dynamics. Importantly, our results shed light on the relative ratios of -- and interrelations between -- the sets of dynamics that are non-Markovian with respect to different criteria. Finally, we investigate the fraction of dynamics in which the memory effects are necessarily of quantum nature and establish a connection between two recently developed concepts that characterize the quantumness of memory in non-Markovian dynamics.
Although a number of measures for quantum non-Markovianity have been proposed recently, it is still an open question whether these measures directly characterize the memory effect of the environment, i.e., the dependence of a quantum state on its past in a time evolution. In this paper, we present a criterion and propose a measure for non-Markovianity with clear physical interpretations of the memory effect. The non-Markovianity is defined by the inequality $T({t}_{2},{t}_{0})\ensuremath{\ne}T({t}_{2},{t}_{1})T({t}_{1},{t}_{0})$ in terms of memoryless dynamical map TTT introduced in this paper. This definition is conceptually distinct from that based on divisibility used by Rivas et al. [Phys. Rev. Lett. 105, 050403 (2010)], whose violation is manifested by noncomplete positivity of the dynamical map. We demonstrate via a typical quantum process that without Markovian approximation, nonzero memory effects (non-Markovianity) always exist even if the non-Markovianity is zero by the other non-Markovianity measures.
Quantum thermodynamics has emerged as a central field for understanding how energy conversion processes occur in microscopic systems. In these systems, effects such as coherence, entanglement, and non-Markovianity play key roles. In this thesis, we explore different ways to describe quantum thermodynamics, using two main approaches: one based on entropy and the other on ergotropy. First, we introduce a generalized approach to quantify non-Markovianity through the breakdown of monotonicity in thermodynamic functions. In this context, the entropy-based heat flow serves as a practical tool to witness and measure quantum memory in unital maps that do not reverse the sign of the internal energy. Next, we analyze the dynamics of ergotropy in open qubits under both Markovian and non-Markovian evolutions. We identify phenomena such as freezing and sudden death of ergotropy, and we establish an analytical relation between the change in ergotropy and the environment-induced work . This provides a clear physical interpretation for the additional term in the first law in the entropy-based formulation. Finally, we propose an ergotropy-based thermodynamic formulation, in which heat is reinterpreted in terms of the change of the passive state associated with the density operator governing the quantum dynamics. This approach allows one to measure non-Markovianity of unital maps more generally and accurately than the entropy-based heat flow. This advantage comes from the direct link between heat and von Neumann entropy, a property ensured by invariance under passive transformations. Moreover, the out-of-equilibrium temperature naturally remains non-negative, similarly to equilibrium thermodynamics.
The dynamics of open quantum systems are often modeled by non-Markovian processes that account for memory effects arising from interactions with the environment. It is well known that the memory provided by the environment can be classical or quantum in nature. Remarkably, the quantumness of the memory can be witnessed locally by measurements on the open system alone, without requiring access to the environment. However, existing witnesses are computationally challenging for systems beyond qubits, which severely limits their practical applicability. In this work, we present a tractable criterion for quantum memory based on the von Neumann entropy, which is easily computable for systems of any dimension. Using this witness, we investigate the nature of memory in a class of physically motivated finite-dimensional qudit dynamics. Moreover, we demonstrate that this criterion is also suitable for detecting quantum memory in continuous-variable systems. As an illustrative example, we analyze non-Markovian Gaussian dynamics of a damped harmonic oscillator.
The Second Law of Thermodynamics states that temporal evolution of an isolated system occurs with non-diminishing entropy. In quantum realm, this holds for energy-isolated systems the evolution of which is described by the so-called unital quantum channel. The entropy of a system evolving in a non-unital quantum channel can, in principle, decrease. We formulate a general criterion of unitality for the evolution of a quantum system, enabling a simple and rigorous approach for finding and identifying the processes accompanied by decreasing entropy in energy-isolated systems. We discuss two examples illustrating our findings, the quantum Maxwell demon and heating-cooling process within a two-qubit system.
Control of open quantum dynamics is of great interest for realizing quantum technologies. Therefore, it is an important task to quantify and characterize the entropy for open quantum systems under decoherence. In this paper, we study the time evolution of the von Neumann entropy for open quantum systems described by the Lindblad master equation. Note that, in particular, when the decoherence corresponds to the measurement for the observable in the system, the von Neumann entropy tends to monotonically increases as the variance becomes larger. Furthermore, we present a lower bound of the von Neumann entropy in the long-time limit. This lower bound has advantages of being straightforwardly calculated and applicable to a general Markovian open quantum system.