Precision measurements of frequency are critical to accurate time keeping and are fundamentally limited by quantum measurement uncertainties. While for time-independent quantum Hamiltonians the uncertainty of any parameter scales at best as 1/T, where T is the duration of the experiment, recent theoretical works have predicted that explicitly time-dependent Hamiltonians can yield a 1/T^{2} scaling of the uncertainty for an oscillation frequency. This quantum acceleration in precision requires coherent control, which is generally adaptive. We experimentally realize this quantum improvement in frequency sensitivity with superconducting circuits, using a single transmon qubit. With optimal control pulses, the theoretically ideal frequency precision scaling is reached for times shorter than the decoherence time. This result demonstrates a fundamental quantum advantage for frequency estimation.
Precision measurements of frequency are critical to accurate time keeping and are fundamentally limited by quantum measurement uncertainties. While for time-independent quantum Hamiltonians the uncertainty of any parameter scales at best as 1/T, where T is the duration of the experiment, recent theoretical works have predicted that explicitly time-dependent Hamiltonians can yield a 1/T^{2} scaling of the uncertainty for an oscillation frequency. This quantum acceleration in precision requires coherent control, which is generally adaptive. We experimentally realize this quantum improvement in frequency sensitivity with superconducting circuits, using a single transmon qubit. With optimal control pulses, the theoretically ideal frequency precision scaling is reached for times shorter than the decoherence time. This result demonstrates a fundamental quantum advantage for frequency estimation.
We investigate the fundamental limits in precision allowed by quantum mechanics from Landau-Zener transitions, concerning Hamiltonian parameters. While the Landau-Zener transition probabilities depend sensitively on the system parameters, much more precision may be obtained using the acquired phase, quantified by the quantum Fisher information. This information scales with a power of the elapsed time for the quantum case, whereas it is time independent if the transition probabilities alone are used. We add coherent control to the system and increase the permitted maximum precision in this time-dependent quantum system. The case of multiple passes before measurement, Landau-Zener-Stueckelberg interferometry, is considered, and we demonstrate that proper quantum control can cause the quantum Fisher information about the oscillation frequency to scale as T4, where T is the elapsed time. These results are foundational for frequency standards and quantum clocks.
Frequency estimation, a cornerstone of quantum metrology, has been significantly enhanced by advanced quantum sensing strategies. However, most protocols rely either on static or time-independent encoding mechanisms, inherently limiting their achievable precision scaling, or on control strategies requiring changing the Hamiltonian and/or implementing feedback mechanisms. To overcome this, we investigate a simpler dynamical encoding protocol where the quantum oscillator is driven by a general continuous temporal frequency modulation Ω(t)=ω0f(t). We analytically demonstrate that for a given modulation profile f(t) and its corresponding time-integral F(t), the quantum Fisher information (QFI) scales as O(F(t)2). This enhancement stems from the fact that temporal encoding fundamentally alters the mechanism of dynamical phase accumulation. Crucially, when evaluated under the energy and evolution-time constraints, this framework reveals a genuine precision enhancement over the conventional time-independent baseline. By analyzing explicit polynomial and exponential modulations, we establish that arbitrary precision scaling can be deterministically engineered, with ultimate bounds that are asymptotically saturable via optimal homodyne detection. Our framework provides a universal paradigm for exploiting time-dependent quantum control in next-generation sensors.
Abstract Quantum metrology has been studied for a wide range of systems with time-independent Hamiltonians. For systems with time-dependent Hamiltonians, however, due to the complexity of dynamics, little has been known about quantum metrology. Here we investigate quantum metrology with time-dependent Hamiltonians to bridge this gap. We obtain the optimal quantum Fisher information for parameters in time-dependent Hamiltonians, and show proper Hamiltonian control is generally necessary to optimize the Fisher information. We derive the optimal Hamiltonian control, which is generally adaptive, and the measurement scheme to attain the optimal Fisher information. In a minimal example of a qubit in a rotating magnetic field, we find a surprising result that the fundamental limit of T2 time scaling of quantum Fisher information can be broken with time-dependent Hamiltonians, which reaches T4 in estimating the rotation frequency of the field. We conclude by considering level crossings in the derivatives of the Hamiltonians, and point out additional control is necessary for that case.
Quantum sensing uses nonclassical states to improve measurement sensitivity, but the same states that provide metrological gain also decohere more rapidly. This limits the usable interrogation time and, in practice, often precludes improvement in ultimate sensitivity - realized useful quantum advantage has consequently remained rare. Here, we restore persistent quantum advantage by embedding Fock-state enhancement within a quantum heterodyne (Qdyne) protocol, decoupling sensitivity from the decoherence-limited interrogation time τ. Measurements are acquired at short τ where the quantum-enhanced gain is optimal, while precision accumulates with the total measurement time. Demonstrated on the motional mode of a trapped 40Ca+ ion, we observe quantum-enhanced precision that persists to measurement times seven orders of magnitude beyond the dephasing limit, scaling as T^{-3/2} with no indication of saturation. Using the n=3 Fock state, we reach a frequency precision of 0.5uHz relative to an 86MHz carrier, achieving a fractional precision ~6x10^{-15}. This represents a quantum-enhanced gain of 7.1(10) dB over the n=0 state, in agreement with Fisher information predictions. This is the first demonstration of Qdyne beyond solid-state spin-defects. Further, by using the quantum harmonic oscillator to perform frequency mixing, we extend operation beyond 1GHz, two orders of magnitude above the ceiling of pulsed dynamical-decoupling implementations. These results recover quantum advantage at the long timescales required to improve ultimate sensitivity, with direct implications for nanoscale NMR and quantum logic spectroscopy.
We present and experimentally implement a real-time protocol for calibrating the frequency of a resonantly driven qubit, achieving exponential scaling in calibration precision with the number of measurements, up to the limit imposed by decoherence. The real-time processing capabilities of a classical controller dynamically generate adaptive probing sequences for qubit-frequency estimation. Each probing evolution time and drive frequency are calculated to divide the prior probability distribution into two branches, following a locally optimal strategy that mimics a conventional binary search. The scheme does not require repeated measurements at the same setting, as it accounts for state preparation and measurement errors. Its use of a parametrized probability distribution favors numerical accuracy and computational speed. We show the efficacy of the algorithm by stabilizing a flux-tunable transmon qubit, leading to improved coherence and gate fidelity. As benchmarked by gate-set tomography, the field-programmable gate array (FPGA) powered control electronics partially mitigates non-Markovian noise, which is detrimental to quantum error correction. The mitigation is achieved by dynamically updating and feeding forward the qubit frequency. Our protocol highlights the importance of feedback in improving the calibration and stability of qubits subject to drift and can be readily applied to other qubit platforms.
We present and experimentally implement a real-time protocol for calibrating the frequency of a resonantly driven qubit, achieving exponential scaling in calibration precision with the number of measurements, up to the limit imposed by decoherence. The real-time processing capabilities of a classical controller dynamically generate adaptive probing sequences for qubit-frequency estimation. Each probing evolution time and drive frequency are calculated to divide the prior probability distribution into two branches, following a locally optimal strategy that mimics a conventional binary search. The scheme does not require repeated measurements at the same setting, as it accounts for state preparation and measurement errors. Its use of a parametrized probability distribution favors numerical accuracy and computational speed. We show the efficacy of the algorithm by stabilizing a flux-tunable transmon qubit, leading to improved coherence and gate fidelity. As benchmarked by gate-set tomography, the field-programmable gate array (FPGA) powered control electronics partially mitigates non-Markovian noise, which is detrimental to quantum error correction. The mitigation is achieved by dynamically updating and feeding forward the qubit frequency. Our protocol highlights the importance of feedback in improving the calibration and stability of qubits subject to drift and can be readily applied to other qubit platforms.