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arXiv:1706.00823 · New Journal of Physics

Ultracold molecule assembly with photonic crystals

Jesús Pérez‐Ríos, May E. Kim, Chen-Lung Hung

Published Nov 17, 2017• 18 citations
arXivHTMLPDF

Abstract

Photoassociation (PA) is a powerful technique to synthesize molecules directly and continuously from cold and ultracold atoms into deeply bound molecular states.In freespace, however, PA efficiency is constrained by the number of spontaneous decay channels linking the initial excited molecular state to a sea of final (meta)stable rovibronic levels.Here, we propose a novel scheme based on molecules strongly coupled to a guided photonic mode in a photonic crystal waveguide that turns PA into a powerful tool for near deterministic formation of ultracold molecules in their ground rovibrational level.Our example shows a potential ground state molecule production efficiency 90% > , and a saturation rate 10 6 > molecules per second.By combining state-of-the-art cold atomic and molecular physics with nanophotonic engineering, our scheme presents a novel experimental package for trapping, cooling, and optically manipulating ultracold molecules, thus opening up new possibilities in the direction of ultracold chemistry and quantum information.

DOI
10.1088/1367-2630/aa9b49

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Photoassociation (PA) is a powerful technique to synthesize molecules directly and continuously from cold and ultracold atoms into deeply bound molecular states.In freespace, however, PA efficiency is constrained by the number of spontaneous decay channels linking the initial excited molecular state to a sea of final (meta)stable rovibronic levels.Here, we propose a novel scheme based on molecules strongly coupled to a guided photonic mode in a photonic crystal waveguide that turns PA into a powerful tool for near deterministic formation of ultracold molecules in their ground rovibrational level.Our example shows a potential ground state molecule production efficiency 90% > , and a saturation rate 10 6 > molecules per second.By combining state-of-the-art cold atomic and molecular physics with nanophotonic engineering, our scheme presents a novel experimental package for trapping, cooling, and optically manipulating ultracold molecules, thus opening up new possibilities in the direction of ultracold chemistry and quantum information.
The integration of cold neutral atoms with nanophotonic circuits offers significant potential as a light–matter interface for a wide range of applications ranging from fundamental studies in quantum optics, quantum many– body physics, quantum networks to even ultracold chemistry. Here, we describe the design and realization of a novel platform where an efficiently–coupled microring photonic circuit on a chip is integrated with a cold atom system. This platform is fully compatible with laser cooling and trapping atoms, which allows for direct loading of cold atoms in close vicinity of a microring circuit. We discuss our experimental scheme and efforts to prepare for an array of individually trapped atoms within the near field region of a whispering-gallery mode (WGM) in a microring resonator for realizing strong atom–light interactions. Beyond our original motivations in creating an atom-photon quantum interface, we also discuss a novel application – for direct photoassociation (PA) synthesis and quantum state detection of cold diatomic molecules without closed optical transitions. We estimate that the transfer efficiency to a molecular ground state and the subsequent state detection efficiency can approach unity with strong photon–molecule coupling that could be realized in our microring resonator circuit.
Photoassociation is a process by which two cold, trapped atoms can be optically excited during a collision to make a vibrational level of an excited electronic state of a molecular dimer. High-resolution photoassociation spectra are now well-known for most alkali dimers. The upper level normally decays by spontaneous emission to a number of final molecular levels, bound and unbound. A laser of a second color can be used to stimulate a transition from the upper level to a particular ground state vibrational level. Such a Raman photoassociation process can be used to form translationally cold molecules in a cold atomic gas or a Bose-Einstein condensate. Coupled channels scattering calculations show that the collisional rate coefficient for coherent production of molecules in specific target states, >10−10cm3/s,> 10^{-10} cm^{3}/s,>10−10cm3/s, can greatly exceed the rate coefficient for forming products due to excited state spontaneous decay. This implies the feasibility of rapid coherent conversion of atom pairs in a condensate to molecules on a time scale short compared to the trap oscillation time. The untrapped molecules can form a coherent molecular beam. We will examine the prospects for the experimental realization of photoassociative molecule formation in cold alkali gases or condensates.
Using a nonselective broadband detection scheme we discovered an efficient mechanism of formation of ultracold Cs2{\mathrm{Cs}}_{2}Cs2​ molecules in deeply bound vibrational levels (v=1−−9)(v=1--9)(v=1−−9) of their electronic ground state $X\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Sigma}_{g}^{+}$. They are formed by a one-photon photoassociation of ultracold cesium atoms in a manifold of excited electronic states, followed by a two-step spontaneous emission cascade. This process creates about 105−−106moleculespersecond{10}^{5}--{10}^{6}\phantom{\rule{0.3em}{0ex}}\text{molecules}\phantom{\rule{0.3em}{0ex}}\text{per}\phantom{\rule{0.3em}{0ex}}\text{second}105−−106moleculespersecond. This detection scheme is an advancement compare to previous ones and could be generalized to other molecular species for the systematic investigation of cold molecule formation mechanisms.
Abstract Integrating nanophotonics and cold atoms has drawn increasing interest in recent years due to diverse applications in quantum information science and the exploration of quantum many‐body physics. For example, dispersion‐engineered photonic crystal waveguides (PCWs) permit not only stable trapping and probing of ultracold neutral atoms via interactions with guided‐mode light, but also the possibility to explore the physics of strong, photon‐mediated interactions between atoms, as well as atom‐mediated interactions between photons. While diverse theoretical opportunities involving atoms and photons in 1D and 2D nanophotonic lattices have been analyzed, a grand challenge remains the experimental integration of PCWs with ultracold atoms. Here, an advanced apparatus that overcomes several significant barriers to current experimental progress is described, with the goal of achieving strong quantum interactions of light and matter by way of single‐atom tweezer arrays strongly coupled to photons in 1D and 2D PCWs. Principal technical advances relate to efficient free‐space coupling of light to and from guided modes of PCWs, silicate bonding of silicon chips within small glass vacuum cells, and deterministic, mechanical delivery of single‐atom tweezer arrays to the near fields of photonic crystal waveguides.
In the ultracold regime, where the interactions between atoms become quantum mechanical in nature, we can investigate the fundamental properties of matter. A natural progression from the catalogue of pioneering experiments using ultracold atoms is to extend the size of our quantum system by producing ultracold molecules in prescribed low-energy internal states. Techniques for cold molecule production are split into two methods: direct and indirect cooling. While direct cooling methods have yet to realize ultracold temperatures, collisional relaxation in the molecules leads to low internal energy states. By contrast, indirect cooling — the association of molecules from pre-cooled atoms—has produced a range of molecules at ultracold temperatures; the challenge with this technique is to control the internal state.This thesis concentrates on a technique that is complementary to those already in existence: ultrafast photoassociation. Key to this technique is the formation of time non-stationary wavepackets in the excited-state in order to improve FranckCondon overlap of the excited state with deeply bound ground-state vibrational levels. A pump-probe experiment was designed and built to demonstrate the formation of bound excited-state dimers. In this work we show that the initial state from which the wavepacket originates is of critical importance to the evolution of excited-state population. We find that the internuclear separation of the wavepacket produced in a rubidium magneto-optical trap is too large to observe coherent oscillations in the excited state. The implications of this are discussed along with recommendations for future ultrafast photoassociation experiments. Consequently, a new ultracold atom apparatus was built utilizing magnetic and dipole-force trapping to increase the density of the atomic sample; this apparatus will enable future experiments combining the exciting fields of ultracold matter and ultrafast light.
Integrating ultracold atoms with nanophotonics enables the exploration of new paradigms in quantum optics and many body physics. Advanced fabrication capabilities for low-loss dielectric materials provide powerful tools to engineer light-matter coupling of photons and atoms. For example, dispersion-engineered photonic crystal waveguides (PCWs) permit not only stable trapping and probing of atoms via interactions with guided mode (GM) light, but also the possibility to study the physics of strong photon-mediated interactions between atoms. This thesis describes the design of a quasi-one-dimensional structure, the alligator photonic crystal waveguide (APCW), which has already allowed for the observation of some of those features. Furthermore, external illumination schemes allow for the trapping and transport of atoms near the dielectric device. Here, atoms loaded into a one-dimensional optical lattice are transported through the APCW. As the atoms trapped in the lattice approach the APCW, the combination of lattice and GM potential can smoothly guide atoms into the gap between the two dielectric nanobeams. Therefore, the transmission of a weak guided mode probe is modulated at the rate determined by the lattice moving through the APCW. In the near future, single atoms can then be transferred from the moving lattice into optical traps formed in each unit cell by GMs of the APCW. Moreover, a characterization of a simple 2D photonic crystal slabs design is presented.