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arXiv:1705.06404 · Chinese Physics B

Velocity-selective spectroscopy measurements of Rydberg fine structure states in a hot vapor cell

Jun He, Dong-Liang Pei, Jieying Wang, Junmin Wang

Published Oct 1, 2017• 1 citation
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Abstract

A velocity-selective spectroscopy technique for studying the spectra of Rydberg gases is presented. This method provides high-resolution spectrum measurements. We present experimental results for a ladder system 6S 1/2 → 6P 3/2 → n S(D) electromagnetically-induced transparency involving highly-excited Rydberg states. Based on a radio-frequency modulation technique, we measure the hyperfine structure splitting of intermediate states and the fine structure splitting of Rydberg states in a room temperature 133 Cs vapor cell. The experimental data and theoretical predictions show excellent agreement.

DOI
10.1088/1674-1056/26/11/113202

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Alisher Duspayev, Georg A. Raithel

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A velocity-selective spectroscopy technique for studying the spectra of Rydberg gases is presented. This method provides high-resolution spectrum measurements. We present experimental results for a ladder system 6S 1/2 → 6P 3/2 → n S(D) electromagnetically-induced transparency involving highly-excited Rydberg states. Based on a radio-frequency modulation technique, we measure the hyperfine structure splitting of intermediate states and the fine structure splitting of Rydberg states in a room temperature 133 Cs vapor cell. The experimental data and theoretical predictions show excellent agreement.
The spectra of Rydberg atoms are of great significance for studying the energy levels of Rydberg atoms and the interaction between neutral atoms, especially, the high-precision spectra of Rydberg atoms can be used to measure the energy level shifts of Rydberg atoms resulting from the dipole-dipole interactions in room-temperature vapor cells. In this paper we report the preparation of cesium Rydberg states based on the cascaded two-photon excitation of 509 nm laser and 852 nm laser in opposite, and the measurements of the fine structure of cesium Rydberg states. In this experiment, the 509 nm laser is generated by the cavity-enhanced second-harmonic generation from 1018 nm laser with a periodically-poled KTP crystal and has a maximum power of about 1 W, and the 852 nm probe laser is provided by an external-cavity diode laser with a maximum output power of 5 mW and a typical linewidth of 1 MHz. By scanning the frequency of 509 nm coupling laser, it is presented that the Doppler-free spectra based on electromagnetically-induced transparency (EIT) of 509 nm coupling laser and 852 nm probe laser. The velocity-selective EIT spectra are used to study the spectral splitting of 6S1/26P3/257S(D) ladder-type system of cesium Rydberg atoms in a room-temperature vapor cell. The powers of 852 nm probe laser and 509 nm coupling laser are 0.3 upW and 200 mW, respectively. Their waist radii are both approximately 50 m. The intervals of hyperfine splitting of the intermediate state 6P3/2(F'=3, 4, 5) and fine splitting of 57D3/2 and 57D5/2 Rydberg states are measured by a frequency calibrating. Concretely, the velocity-selective spectrum with a radio frequency (RF) modulation of 30 MHz is used as a reference to calibrate the Rydberg fine-structure states in the hot vapor cell, where the RF frequency precision is smaller than a hertz on long time scales and the EIT linewidth is smaller than 13 MHz. The experimental value of the fine structure splitting of 57D3/2 and 57D5/2 Rydberg states is (354.72.5) MHz, that is in consistence with the value of 346.8 MHz calculated by Rydberg-Ritz equation and quantum defects of 57D3/2 and 57D5/2 Rydberg states. The experimental values of hyperfine splitting of intermediate state 6P3/2(F'=3, 4, 5) are also coincident with the theoretical calculated values. The dominant discrepancy existing between the experimental and calculated results may arise from the nonlinear correspondence of the PZT while the 509 nm wavelength cavity is scanned, and the measurement accuracy influenced by the spectral linewidth. The velocity-selective spectroscopy technique can also be used to measure the energy level shifts caused by the interactions of Rydberg atoms.
A high sensitivity spectroscopy of Rydberg atoms is presented by using electromagnetically induced transparency (EIT) in the 6S(1/2)-6P(3/2)-n D ladder-type system of cesium vapor cell at room temperature. The EIT spectra of 40 D Rydberg state are measured and the dependences of the EIT magnitude and linewidth on the coupling laser power are investigated in detail. The Rydberg EIT linewidth is measured to be about 5.6 MHz when the powers of probe and coupling lasers are 50 microW and 5.2 mW, respectively, and which is close to the natural linewidth of cesium atoms. The effect of double resonance optical pumping on EIT is also investigated. The fine structures of nD (n = 39-55) are measured and the experimental result is in agreement with quantum defect theory.
We study resonance redistribution mechanisms inside a hot vapor cell. This is achieved by pumping cesium atoms on the 6S 1/2 →6P 1/2 resonance and subsequently probing the velocity distribution of the 6P 1/2 population by a linear absorption experiment on the 6P 1/2 →16S 1/2 or 6P 1/2 →15D 3/2 transitions at 514 nm and 512 nm, respectively. We demonstrate that despite the existence of thermalization processes, traces of the initial velocity selection, imposed by the pump, survive in both hyperfine levels of the intermediate (6P 1/2 ) state. This observation allows us to perform sub-Doppler resolution vapor cell spectroscopy on Rydberg states using a simple pump–probe setup. At high cesium densities, redistribution mechanisms dominate, and the velocity selection vanishes. However, spectral analysis provides the collisional shifts and broadenings of the probed Rydberg states.
We present direct measurements of the hyperfine splitting of Rydberg states in 87{}^{87}87Rb using electromagnetically induced transparency (EIT) spectroscopy in a room-temperature vapor cell. With this method, and in spite of Doppler broadening, linewidths of 3.7 MHz FWHM, i.e., significantly below the intermediate-state natural linewidth, are reached. This allows resolving hyperfine splittings for Rydberg sss states with n=20,...,24n=20,...,24n=20,...,24. With this method we are able to determine Rydberg state hyperfine splittings with an accuracy of approximately 100 kHz. Ultimately, our method allows accuracies of order 5 kHz to be reached. Furthermore, we present a direct measurement of hyperfine-resolved Rydberg-state Stark shifts. These results will be of great value for future experiments relying on excellent knowledge of Rydberg-state energies and polarizabilities.
We demonstrate a velocity selection scheme that mitigates suppression of electromagnetically induced transparency (EIT) by Doppler shifts for coupling wavelengths larger than the probe wavelength. An optical pumping beam counterpropagating with the EIT probe beam transfers atoms between hyperfine states in a velocity-selective fashion. Measurement of the transmitted probe beam synchronous with chopping of the optical pumping beam enables a Doppler-free EIT signal to be detected. Transition frequencies between 5P1/25{P}_{1/2}5P1/2​ and nS1/2n{S}_{1/2}nS1/2​ states for n=26n=26n=26, 27, and 28 in 39K^{39}\mathrm{K}39K are obtained via EIT spectroscopy in a heated vapor cell with a probe beam stabilized to the $4{S}_{1/2}\ensuremath{\rightarrow}5{P}_{1/2}$ transition. Using previous high-resolution measurements of the $4{S}_{1/2}\ensuremath{\rightarrow}n{S}_{1/2}$ transitions, we make a determination of the absolute frequency of the $4{S}_{1/2}\ensuremath{\rightarrow}5{P}_{1/2}$ transition. Our measurement is shifted by 560 MHz from the currently accepted value with a twofold improvement in uncertainty. These measurements will enable novel experiments with Rydberg-dressed ultracold Fermi gases composed of 40K^{40}\mathrm{K}40K atoms.
Multiphoton electromagnetically induced transparency (EIT) of atomic vapors involves several intermediate atomic levels. The substructure of these levels and their collisional interactions can drastically alter experimental EIT signals. Here we report on hyperfine structure and collision effects in three-photon Rydberg EIT on the cascade $5{S}_{1/2}\ensuremath{\rightarrow}\phantom{\rule{4pt}{0ex}}5{P}_{1/2}\ensuremath{\rightarrow}5{D}_{3/2}\phantom{\rule{4pt}{0ex}}\ensuremath{\rightarrow}25{F}_{5/2}$ in a room-temperature 85Rb^{85}\mathrm{Rb}85Rb vapor cell. In our measurements of EIT spectra, we identify two types of EIT signatures that correspond with distinct excitation pathways and atomic velocity classes in the atomic vapor. The 5D3/25{D}_{3/2}5D3/2​ hyperfine structure and Autler-Townes splittings lead to complex patterns in the EIT spectra, which we analyze with the aid of 10-level EIT simulations. Adding 50 mTorr of Ar gas alters the EIT spectra and induces an additional, third EIT mode. Based on our simulation results, we attribute these changes to hyperfine collisions in the Rb 5D3/25{D}_{3/2}5D3/2​ level. Our study may become useful in quantum technologies involving Rydberg EIT and hyperfine collisions in vapor cells, including noninvasive spatiotemporally resolved electric-field sensing of electric fields in low-pressure plasmas.