The Röntgen term is an often neglected contribution to the interaction between an atom and an electromagnetic field in the electric dipole approximation. In this work we discuss how this interaction term leads to a difference between the kinetic and canonical momentum of an atom which, in turn, leads to surprising radiation forces acting on the atom. We use a number of examples to explore the main features of this interaction, namely forces acting against the expected dipole force or accelerations perpendicular to the beam propagation axis.
The Röntgen term is an often neglected contribution to the interaction between an atom and an electromagnetic field in the electric dipole approximation. In this work we discuss how this interaction term leads to a difference between the kinetic and canonical momentum of an atom which, in turn, leads to surprising radiation forces acting on the atom. We use a number of examples to explore the main features of this interaction, namely forces acting against the expected dipole force or accelerations perpendicular to the beam propagation axis.
A theory for a bound system of charges interacting with electromagnetic fields is developed, with special emphasis on the radiation-pressure effects imposed by the fields on the gross motion of the charges. The theory is particularly simple and transparent for the case of two opposite charges of finite mass M in the electric-dipole approximation. This enables a rigorous description to be given for the quantum electrodynamics of the problem with the various interaction terms affecting the gross motion being easily identified. Here, too, it becomes clear that, even in the dipole approximation, the conventional interaction term should be supplemented by the so-called R\"ontgen term. Besides ensuring the consistency of the theory for the overall (charges plus fields) system regarding conservation laws, the R\"ontgen term has dynamical consequences. This is established by explicit calculations of the expectation values of the mechanical momentum 〈MR\ifmmode \dot{}\else \.{}\fi{}〉 and the radiation pressure force 〈MR\ifmmode\ddot\else\textasciidieresis\fi{}〉 on a two-level atom in the dipole approximation. Results of calculations are displayed for the case of a single light beam and for counterpropagating beams. The feasibility of experimentally observing the transverse force is explored. Generalizations of the well-known friction force arising in one-dimensional optical molasses are given and discussed.
A theory of radiation pressure and its effects on the gross motion of an aggregrate of charges is established within a canonical framework. The theory indicates the existence of radiation-pressure effects arising from an additional interaction--the R\"ontgen interaction--whose origin is the classical R\"ontgen current. A careful development of the formalism reveals the importance of distinguishing between the canonical and mechanical momenta of the gross motion of the aggregate and of incorporating the R\"ontgen-type interaction terms when calculating the gross-motion dynamics. A form of the R\"ontgen interaction is present even in the dipole approximation: an effect which has previously been ignored but which is necessary to ensure gauge invariance of the radiation-induced mechanical force. Explicit calculations of the rates of change of canonical and mechanical momenta are presented for a general atomic dipole, with specializations to a two-level atom, revealing the presence of velocity-dependent terms in a natural way. The formalism is consistent with the Minkowski form of the classical momentum density of an electromagnetic field.
The quantum description of the electromagnetic (EM) field, even in the absence of sources, reveals that the vacuum exhibits fluctuations in the energy and of the components of the field, known as quantum vacuum fluctuations. The coupling of these quantum fluctuations of the vacuum to electric charges leads to experimentally observable phenomena, such as the spontaneous emission of an excited atom, the Lamb effect, the Casimir effect, and the van der Waals interactions, which have been historically fundamental for the confirmation of the existence of these fluctuations. The optical response of simple atoms and the EM interaction between two atoms constitute the simplest realistic phenomena for studying these effects. This thesis focuses on the fundamental study of the properties of interatomic interactions, addressing aspects such as their dependence on the interatomic distance, their time dependence, and the emergence of nonreciprocal interatomic forces due to parity breaking. In particular, the detailed analysis of the electric dipole forces in a system of two atoms, one of which is initially excited, is carried out, along with the study of the implication of the resonant interactions in the appearance of collective effects in absorption and emission processes of many-atom systems. Due to the inherently time-dependent nature of the resonant forces between excited atoms, a time-dependent Hamiltonian approach is employed. The atomic interaction processes are represented with time-ordered diagrams. It is obtained that the atoms are subjected to resonant conservative forces, directed along the interatomic axis, which exert a net force on the system. This result implies an apparent violation of the action-reaction principle due to the lack of conservation of the kinetic momentum of the atoms. However, this net force on the atomic system is compensated by the time derivative of the transversal momentum of the EM field, associated with the resonant photons that mediate the interaction, ensuring the conservation of the total momentum of the system. In addition to these conservative forces, there are nonconservative forces which are a consequence of the time derivative of the so-called longitudinal momentum of the electromagnetic field and contain components perpendicular to the interatomic axis. We analyze the particular case of the interaction between identical atoms. In this scenario, the net force on the system becomes time-dependent. Furthermore, states with degenerate energy arise and evolve coherently through the periodic transfer of resonant photons between the atoms. This implies that in these degenerate states, there are contributions from interatomic interactions that cannot be expressed as an energy shift in the atomic wave functions. Consequently, these interactions give rise to collective phenomena observable in photon absorption and emission processes. At the same time, the strength of these forces is markedly superior to that calculated for different atoms, which makes this scenario a more favorable set-up for the experimental observation of the nonreciprocal forces and the associated coherent phenomena. Concerning collective effects and their application in the design of multi-atomic qubits, these phenomena have significant implications for the scalability and connectivity of such systems. To describe these collective properties, we have formulated a Hamiltonian that incorporates both the interaction processes, i.e., those that give rise to dynamic coherence and incoherence effects, and the stationary interaction processes that renormalize the energy of the atomic states. It is found that the photon absorption probability is determined by the ratio between the interatomic interaction and the intensity of the laser that excites the system. On the other hand, the spontaneous emission of photons is proportional to the number of decay channels, which decrease when the interatomic interaction between excited states breaks the degeneracy in the subspaces associated with the same number of excitations.
It has been known for some time that the interaction of laser light with a free atom can give rise to electromagnetic pressure forces that act on its centre of mass. These forces have been extensively examined both theoretically and experimentally: see, for example Metcalf and van der Straten (5.1) or Adams and Riis (5.2). A simple model of a two-level atom subject to a plane electromagnetic wave may be shown to give rise to two kinds of force acting on the atom centre of mass. These are, a dissipative force arising from the absorption of the light by the atom and its subsequent spontaneous emission in a random direction and a dipole force arising from the non-uniformity of the field distribution which can attract the atom to the regions of intense field. These forces underpin the manipulation of atoms by lasers in a variety of beam configurations. The dissipative force has been exploited in the Doppler cooling of the atomic motion (5.3, 5.4) and the dipole force used for trapping (5.5), while a combination of these effects has led to the realisation of Bose-Einstein condensation (5.6). These forces are, of course, closely related to the ones discussed in Section 4.
We present a time-dependent calculation of the velocity-dependent forces which act on an excited atomic dipole in relative motion with respect to ground state atoms of a different kind. Both its interaction with a single atom and with a dilute atomic plate are evaluated. In either case, the total force consists of a conservative van der Waals component and a nonconservative R\"ontgen component. On physical grounds, the former corresponds to the velocity-dependent recoil experienced by the excited atom in the processes of absorption and emission of the photons that it exchanges with the ground-state atoms on a periodic basis. The latter corresponds to the time-variation of the R\"ontgen momentum, which is also mediated by the periodic exchange of quasiresonant photons. We find that, at leading order, all these interactions are linear in velocity. In the nonretarded regime the van der Waals force dominates, being antiparallel to the velocity. On the contrary, in the retarded regime the velocity-dependent forces oscillate in space, van der Waals and R\"ontgen forces are of the same order in the atom-atom interaction, and the R\"ontgen component dominates in the atom-surface interaction.
A theory of the changes in momenta suffered by the translational motion of a two-level atom due to interaction near resonance within uniform light, is presented. The leading changes in the translational energy are first derived and the changes in the momenta due to the irradiation are then deduced from these in a simple and transparent manner. The derivation depends on the inclusion of a quantum interaction term whose classical origin is the Rontgen current in the electric dipole approximation. Thus the theory presented differs considerably from conventional approaches which are normally based on considerations of the transition rates and do not include the effects of the Rontgen term. The momentum changes obtained can be expressed in terms of the susceptibility and its first derivative, and are shown to be independent of the state of the atomic translation. They depend, mainly in sign, on whether the atom is in its ground or excited state. These features lead to a simple derivation of the average momentum changes induced by the irradiation of an atomic system.