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arXiv:1703.04945 · The European Physical Journal D

Quantum dynamics of a hydrogen-like atom in a time-dependent box: non-adiabatic regime

S. Rakhmanov, Davron Matrasulov, Victor I. Matveev

Published Oct 1, 2018• 10 citations
arXivHTMLPDF
DOI
10.1140/epjd/e2018-90195-6

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The quantum dynamics of a hydrogen-like atom confined in one-dimensional box with oscillating walls is studied.The description of the system is reduced to a one-dimensional Schrödinger equation for Coulomb potential with time-dependent boundary conditions, which is solved numerically.Using the obtained solution, the average kinetic energy and binding energies are calculated as a function of time.It is found that both the average kinetic energy and the binding energies are periodic in time with the period depending on the wall's oscillation parameters.The probability density is also analyzed as a function of time and coordinate.

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We study quantum dynamics of one-electron atom confined in a spherical impenetrable box with time-dependent radius. The behavior of the atomic electron interacting with the moving walls of the box is analyzed by computing average binding energy, average force and pressure. Linearly extending, contracting and harmonically breathing boxes are considered in the non-adiabatic regime i.e. when the wall of the box moves with high velocities. It is shown that linearly extending box leads to de-excitation of the atom, while the rapidly contracting box causes the creation of very high pressure on the atom and transition of the atomic electron into the unbound state. In harmonically breathing box diffusive excitation of atomic electron and ionization may occur in analogy with that for atom in a microwave field.
A method is proposed to drive an ultrafast non-adiabatic dynamics of an ultracold gas trapped in a time-dependent box potential. The resulting state is free from spurious excitations associated with the breakdown of adiabaticity, and preserves the quantum correlations of the initial state up to a scaling factor. The process relies on the existence of an adiabatic invariant and the inversion of the dynamical self-similar scaling law dictated by it. Its physical implementation generally requires the use of an auxiliary expulsive potential. The method is extended to a broad family of interacting many-body systems. As illustrative examples we consider the ultrafast expansion of a Tonks-Girardeau gas and of Bose-Einstein condensates in different dimensions, where the method exhibits an excellent robustness against different regimes of interactions and the features of an experimentally realizable box potential.
The quantum dynamics of a hydrogen-like atom confined in one-dimensional box with oscillating walls is studied.The description of the system is reduced to a one-dimensional Schrödinger equation for Coulomb potential with time-dependent boundary conditions, which is solved numerically.Using the obtained solution, the average kinetic energy and binding energies are calculated as a function of time.It is found that both the average kinetic energy and the binding energies are periodic in time with the period depending on the wall's oscillation parameters.The probability density is also analyzed as a function of time and coordinate.