A pure quantum state can fully describe thermal equilibrium as long as one focuses on local observables. The thermodynamic entropy can also be recovered as the entanglement entropy of small subsystems. When the size of the subsystem increases, however, quantum correlations break the correspondence and mandate a correction to this simple volume law. The elucidation of the size dependence of the entanglement entropy is thus essentially important in linking quantum physics with thermodynamics. Here we derive an analytic formula of the entanglement entropy for a class of pure states called cTPQ states representing equilibrium. We numerically find that our formula applies universally to any sufficiently scrambled pure state representing thermal equilibrium, i.e., energy eigenstates of non-integrable models and states after quantum quenches. Our formula is exploited as diagnostics for chaotic systems; it can distinguish integrable models from non-integrable models and many-body localization phases from chaotic phases.
A pure quantum state can fully describe thermal equilibrium as long as one focuses on local observables. The thermodynamic entropy can also be recovered as the entanglement entropy of small subsystems. When the size of the subsystem increases, however, quantum correlations break the correspondence and mandate a correction to this simple volume law. The elucidation of the size dependence of the entanglement entropy is thus essentially important in linking quantum physics with thermodynamics. Here we derive an analytic formula of the entanglement entropy for a class of pure states called cTPQ states representing equilibrium. We numerically find that our formula applies universally to any sufficiently scrambled pure state representing thermal equilibrium, i.e., energy eigenstates of non-integrable models and states after quantum quenches. Our formula is exploited as diagnostics for chaotic systems; it can distinguish integrable models from non-integrable models and many-body localization phases from chaotic phases.
Thermal equilibrium in quantum many-body systems can be fully described by pure quantum states as far as local observables are concerned, while the conventional description of it is based on mixed-state ensembles.The thermodynamic entropy, in that case, is identified with the entanglement entropy of small subsystems.It scales with the size of the subsystem, which is called the volume law of entanglement.When the size of the subsystem increases, however, the correspondence between thermal and entanglement entropies fails and there appears a quantum correction to the simple volume-law scaling.Explicating the scaling of the entanglement entropy with the subsystem size is hence of great importance in connecting quantum physics to thermodynamics as well as analyzing recent experiments on ultracold atoms.In this thesis, we study the volume law of entanglement for pure quantum states representing thermal equilibrium.We derive an analytic formula of the volume law of entanglement for a certain class of pure states called canonical Thermal Pure Quantum (cTPQ) states which represent thermal equilibrium.We illustrate an advantage of the formula by numerically calculating the entanglement entropy of the cTPQ states and applying the formula to it.Furthermore, we argue that our formula universally applies to any sufficiently scrambled pure state, even if the state is not thermal.We consider two examples of such scrambled states, namely, stationary pure states after quantum quench and energy eigenstates of general Hamiltonians with and without integrability.The entanglement entropy of the former states, including actual experimental data in ultracold atoms, is in an excellent agreement with our formula as long as the states are scrambled.For the latter states, we find that our formula works as a good fitting function in non-integrable models to extract information in the thermodynamic limit from finite size systems.We also show that our formula can distinguish eigenstates of integrable models from non-integrable ones.4.3.1 Review of result by Lu and Grover for eigenstates of non-integrable models . . . . . . . . . . . .
The entanglement entropy of subsystems of typical eigenstates of quantum many-body Hamiltonians has recently been conjectured to be a diagnostic of quantum chaos and integrability. In quantum chaotic systems it has been found to behave as in typical pure states, while in integrable systems it has been found to behave as in typical pure Gaussian states. In this tutorial, we provide a pedagogical introduction to known results about the entanglement entropy of subsystems of typical pure states and of typical pure Gaussian states. They both exhibit a leading term that scales with the volume of the subsystem, when smaller than one half of the volume of the system, but the prefactor of the volume law is fundamentally different. It is constant (and maximal) for typical pure states, and it depends on the ratio between the volume of the subsystem and of the entire system for typical pure Gaussian states. Since particle-number conservation plays an important role in many physical Hamiltonians, we discuss its effect on typical pure states and on typical pure Gaussian states. We prove that, while the behavior of the leading volume-law terms does not change qualitatively, the nature of the subleading terms can change. In particular, subleading corrections can appear that depend on the square root of the volume of the subsystem. We unveil the origin of those corrections. Finally, we discuss the connection between the entanglement entropy of typical pure states and analytical results obtained in the context of random matrix theory, as well as numerical results obtained for physical Hamiltonians.
Using arguments built on ergodicity, we derive an analytical expression for the Renyi entanglement entropies which, we conjecture, applies to the finite-energy density eigenstates of chaotic many-body Hamiltonians. The expression is a universal function of the density of states and is valid even when the subsystem is a finite fraction of the total system-a regime in which the reduced density matrix is not thermal. We find that in the thermodynamic limit, only the von Neumann entropy density is independent of the subsystem to the total system ratio V_{A}/V, while the Renyi entropy densities depend nonlinearly on V_{A}/V. Surprisingly, Renyi entropies S_{n} for n>1 are convex functions of the subsystem size, with a volume law coefficient that depends on V_{A}/V, and exceeds that of a thermal mixed state at the same energy density. We provide two different arguments to support our results: the first one relies on a many-body version of Berry's formula for chaotic quantum-mechanical systems, and is closely related to the eigenstate thermalization hypothesis. The second argument relies on the assumption that for a fixed energy in a subsystem, all states in its complement allowed by the energy conservation are equally likely. We perform an exact diagonalization study on quantum spin-chain Hamiltonians to test our analytical predictions.
By numerically exact calculations of spin-1/2 antiferromagnetic Heisenberg models on small clusters up to 24 sites, we demonstrate that quantum entanglement between subsystems A and B in a pure ground state of a whole system A + B can induce thermal equilibrium in subsystem A. Here, the whole system is bipartitoned with the entanglement cut that covers the entire volume of subsystem A. An effective temperature T A of subsystem A induced by quantum entanglement is not a parameter but can be determined from the entanglement von Neumann entropy S A and the total energy E A of subsystem A calculated for the ground state of the whole system.We show that temperature T A can be derived by minimizing the relative entropy for the reduced density matrix operator of subsystem A and the Gibbs state (i.e., thermodynamic density matrix operator) of subsystem A with respect to the coupling strength between subsystems A and B. Temperature T A is essentially identical to the thermodynamic temperature, for which the entropy and the internal energy evaluated using the canonical ensemble in statistical mechanics for the isolated subsystem A agree numerically with the entanglement entropy S A and the total energy E A of subsystem A. Fidelity calculations ascertain that the reduced density matrix operator of subsystem A for the pure but entangled ground state of the whole system A + B matches, within a maximally 1.5% error in the finite size clusters studied, the thermodynamic density matrix operator of subsystem A at temperature T A , despite that these density-matrix operators are different in general.We also find that temperature T A evaluated from the ground state of the whole system depends insignificantly on the system sizes, which is consistent with the fact that the thermodynamic temperature is an intensive quantity.We argue that quantum fluctuation in an entangled pure state can mimic thermal fluctuation in a subsystem.We also provide two simple but nontrivial analytical examples of free bosons and free fermions for which the two density-matrix operators are exactly the same if the effective temperature T A is adopted.We furthermore discuss implications and possible applications of our finding.
While the eigenstate entanglement entropy has been extensively studied for fermionic systems, much less is known about bosonic systems. Here, we study the entanglement entropy of mid-spectrum eigenstates of Bose-Hubbard models, focusing on weakly disordered models with and without particle-number conservation, and contrasting them with the translationally-invariant model. We analyze the volume-law and O(1) contributions to the entanglement entropy via the averages over mid-spectrum eigenstates and the corresponding distributions. We derive the volume-law coefficient of the entanglement entropy by generalizing the mean-field approach from [Phys. Rev. Lett. 119, 220603 (2017)] to many-body systems with a tunable local bosonic cutoff, which agrees with previous analytical and numerical results from [Phys. Rev. B 110, 235154 (2024)]. We show that the volume-law contribution to the entanglement entropy does not change upon breaking translational invariance via on-site disorder. We then numerically study the role of the subleading O(1) contribution to the entanglement entropy. We find that, in the particle-number conserving case, it exhibits a nontrivial dependence on the particle-number density and the local bosonic cutoff, while without particle-number conservation, results suggest the emergence of a universal O(1) contribution beyond the random pure state predictions.
For the typical quantum many-body systems that obey the eigenstate thermalization hypothesis (ETH), we argue that the entanglement entropy of (almost) all energy eigenstates is described by a single crossover function. The ETH implies that the crossover functions can be deduced from subsystem entropies of thermal ensembles and have universal properties. These functions capture the full crossover from the ground-state entanglement regime at low energies and small subsystem size (area or log-area law) to the extensive volume-law regime at high energies or large subsystem size. For critical one-dimensional systems, a universal scaling function follows from conformal field theory and can be adapted for nonlinear dispersions. We use it to also deduce the crossover scaling function for Fermi liquids in d>1 dimensions. The analytical results are complemented by numerics for large noninteracting systems of fermions in d≤3 dimensions and have also been confirmed for bosonic systems and nonintegrable spin chains.