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arXiv:1612.08734 · Entropy

On Quantum Collapse as a Basis for the Second Law of Thermodynamics

Ruth E. Kastner

Published Mar 9, 2017• 28 citations
arXivHTMLPDF

Abstract

It is argued that if the non-unitary measurement transition, as codified by Von Neumann, is a real physical process, then the ‘probability assumption’ needed to derive the Second Law of Thermodynamics naturally enters at that point. The existence of a real, indeterministic physical process underlying the measurement transition would therefore provide an ontological basis for Boltzmann’s Stosszahlansatz and thereby explain the unidirectional increase of entropy against a backdrop of otherwise time-reversible laws. It is noted that the Transactional Interpretation (TI) of quantum mechanics provides such a physical account of the non-unitary measurement transition, and TI is brought to bear in finding a physically complete, non-ad hoc grounding for the Second Law.

DOI
10.3390/e19030106

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It is argued that if the non-unitary measurement transition, as codified by Von Neumann, is a real physical process, then the ‘probability assumption’ needed to derive the Second Law of Thermodynamics naturally enters at that point. The existence of a real, indeterministic physical process underlying the measurement transition would therefore provide an ontological basis for Boltzmann’s Stosszahlansatz and thereby explain the unidirectional increase of entropy against a backdrop of otherwise time-reversible laws. It is noted that the Transactional Interpretation (TI) of quantum mechanics provides such a physical account of the non-unitary measurement transition, and TI is brought to bear in finding a physically complete, non-ad hoc grounding for the Second Law.
Quantum mechanics is widely recognised as being incomplete. It is not consistent with the second law of thermodynamics and does not provide a scientifically credible physical account of the measurement process, the means by which coherence is broken and classically observable states are recorded. This has led to many ad hoc assumptions being used to account for various properties of quantum systems, among which is the coherence time of quantum devices that determines their ability to perform computations. Here, we show that all these properties can be accommodated naturally and consistently in the context of mixing quantum systems which exhibit continuous spectra, as arises in the thermodynamic limit in quantum statistical mechanics and quantum gravity. In particular, for isolated systems we show that the time-reversal symmetry associated with unitary time evolution of the quantum state gives rise to time-symmetry breaking and a semi-group evolution which attains thermodynamic equilibrium at long times. Moreover, the emergence of this non-unitary time-asymmetry leads to microcanonical equilibrium states in which all quantum coherence is lost and is accompanied by the transformation of pure states into mixtures, leading in turn to an increase in entropy. Inclusion of a macroscopic measurement apparatus shows how the outcome of a measurement corresponds to the von Neumann projection postulate, arising with probabilities in conformance with the Born rule. The mathematical structure of the theory which applies to quantum systems with continuous spectra is closely analogous to the classical ergodic theory of dynamical systems and the conditions under which they attain equilibrium states.
The quantum measurement problem, i.e., the apparent conflict between unitary quantum evolution and non-unitary, stochastic wave-function collapse, remains unresolved a century after the formulation of quantum mechanics. We first review the standard picture, from the Copenhagen prescription with its Heisenberg cut, through von Neumann's movable cut, to environment-induced decoherence, which explains the emergence of stable classical records but still presupposes the Born rule and therefore cannot by itself replace the measurement postulates. We then connect this problem to the Maximum Entropy Principle in two complementary ways. First, decoherence drives the measurement apparatus toward the least biased state compatible with the dynamically protected pointer distribution, so that the emergent collapse may be viewed as a thermodynamic relaxation toward constrained maximum entropy. Second, we propose a Timeless Histories formulation of quantum mechanics in which the primitive objects are ordered sequences of events rather than evolving wave functions. Their conditional probabilities are assigned, relative to specified refinements, by a single Born-Boltzmann rule that combines the quadratic structure of Born's rule with Boltzmann's counting of equally probable microstates. The textbook form of Born's rule, the projection postulate, density operators, and wave functions are then recovered as derived informational constructs, while collapse becomes Bayesian conditioning on recorded events. Time and space enter only subsequently through unitary translation symmetry. Since the probability rule is postulated without reference to any physical collapse or classical observer, the usual circularity of the decoherence program is avoided. Decoherence can then be invoked to explain the stability and approximate additivity of macroscopic records, i.e., the emergence of classicality.
Providing a comprehensive exposition of the transactional interpretation (TI) of quantum mechanics, this book sheds new light on long-standing problems in quantum theory such as the physical meaning of the 'Born Rule' for the probabilities of measurement results, and demonstrates the ability of TI to solve the measurement problem of quantum mechanics. It provides robust refutations of various objections and challenges to TI, such as Maudlin's inconsistency challenge, and explicitly extends TI into the relativistic domain, providing new insight into the basic compatibility of TI with relativity and the meaning of 'virtual particles.' It breaks new ground in approaches to interpreting quantum theory and presents a compelling new ontological picture of quantum reality. This substantially revised and updated second edition is ideal for researchers and graduate students interested in the philosophy of physics and the interpretation of quantum mechanics.
In 1957, Feyerabend delivered a paper titled ‘On the Quantum-Theory of Measurement’ at the Colston Research Symposium in Bristol to sketch a completion of von Neumann's measurement scheme without collapse, using only unitary quantum dynamics and well-motivated statistical assumptions about macroscopic quantum systems. Feyerabend's paper has been recognised as an early contribution to quantum measurement, anticipating certain aspects of decoherence. Our paper reassesses the physical and philosophical content of Feyerabend's contribution, detailing the technical steps as well as its overall philosophical motivations and consequences. Summarising our results, Feyerabend interpreted collapse as a positivist assumption in quantum mechanics leading to a strict distinction between the uninterpreted formalism of unitary evolution in quantum mechanics and the classically interpreted observational language describing post-measurement outcomes. Thus Feyerabend took the no-collapse completion of the von Neumann measurement scheme to show the dispensability of the positivist assumption, leading the way to a realistic interpretation of quantum theory. We note, however, that there are substantial problems with his account of measurement that bring into question its viability as a legitimate foil to the orthodox view. We further argue that his dissatisfaction with the von Neumann measurement scheme is indicative of early views on theoretical pluralism.
The measurement problem in quantum mechanics represents a disconnect between the Schr\"{o}dinger equation's unitary evolution and the non-unitary collapse of the wave function. This work resolves this issue by modeling measurement as a deterministic, thermodynamically driven process. We modify the Liouville-von Neumann equation by introducing a dual mechanism: a dephasing term that eliminates quantum coherence and a state-resolution dynamic that amplifies one outcome to certainty. An infinitesimal environmental perturbation breaks the initial symmetry, determining which outcome emerges. Numerical simulations of a qubit in superposition demonstrate that (1) coherence is conserved during unitary evolution, (2) a rapid phase transition occurs upon measurement, and (3) Born Rule statistics emerge from ensemble averaging over random environmental fluctuations. We conclude that quantum collapse need not be a separate postulate but can be modeled as a unified, deterministic dynamical law with testable experimental predictions.