In its simplest form, decoherence occurs when a quantum state is entangled with a second state, but the results of measurements made on the second state are not accessible. As the second state has effectively ``measured'' the first, in this paper we argue that the quantum Fisher information is the relevant metric for predicting and quantifying this kind of decoherence. The quantum Fisher information is usually used to determine an upper bound on how precisely measurements on a state can be used to estimate a classical parameter, and as such it is an important resource. Quantum-enhanced metrology aims to create nonclassical states with large quantum Fisher information and utilize them in precision measurements. In the process of doing this it is possible for states to undergo decoherence; for instance atom-light interactions used to create coherent superpositions of atomic states may result in atom-light entanglement. Highly nonclassical states, such as spin-cat states (Schr\"odinger cat states constructed from superpositions of collective spins) are shown to be highly susceptible to this kind of decoherence. We also investigate the required field occupation of the second state, such that this decoherence is negligible.
In its simplest form, decoherence occurs when a quantum state is entangled with a second state, but the results of measurements made on the second state are not accessible. As the second state has effectively ``measured'' the first, in this paper we argue that the quantum Fisher information is the relevant metric for predicting and quantifying this kind of decoherence. The quantum Fisher information is usually used to determine an upper bound on how precisely measurements on a state can be used to estimate a classical parameter, and as such it is an important resource. Quantum-enhanced metrology aims to create nonclassical states with large quantum Fisher information and utilize them in precision measurements. In the process of doing this it is possible for states to undergo decoherence; for instance atom-light interactions used to create coherent superpositions of atomic states may result in atom-light entanglement. Highly nonclassical states, such as spin-cat states (Schr"odinger cat states constructed from superpositions of collective spins) are shown to be highly susceptible to this kind of decoherence. We also investigate the required field occupation of the second state, such that this decoherence is negligible.
In optical interferometry path-entangled states such as NOON states have shown to give quantum-enhanced precision measurements, but these states are notoriously fragile to particle losses, which typically collapse the quantum state and destroy the phase information. A class of inherently robust states that show the potential for great improvements over the alternatives are the entangled coherent states (ECSs). We show that these states allow substantial improvements over unentangled `classical' states and highly-entangled NOON states for a wide range of loss values. We then describe a measurement scheme that can be used to measure these states with a precision close to the theoretical bound given by the quantum Fisher information. \nWe then look at the quantum mechanisms that lead to precise measurements. In optical interferometry multi-mode entanglement is often assumed to be the driving force behind quantum enhanced measurements. Recent work has shown this assumption to be false, and here we show that when photon losses occur multi-mode entanglement is actually detrimental to obtaining quantum enhanced measurements. We specifically apply this idea to a superposition of coherent states, demonstrating that these states show a robustness to loss that allows them to significantly outperform their competitors in realistic systems. A practically viable measurement scheme is then presented that allows measurements close to the theoretical bound, even with loss. \nIn this thesis we also consider superpositions of spin coherent states and their application to quantum metrology. Compared to optical states, spin systems have a distinctly different process of decoherence known as non-Markovian dephasing, which has shown to give greatly improved robustness to loss. We see that spin cat states give an enhanced scaling over the shot noise limit, even with dephasing, whilst being realisable with current technology.
Quantum metrology faces major challenges in noisy environments, where decoherence rapidly degrades useful quantum resources. We investigate the dynamics of the precision limits given by the quantum Fisher information (QFI) for phase estimation under spatially correlated dephasing. We characterize the dynamics of the QFI by the sensitivity and degradation indicators that can be obtained as analytical expressions derived using perturbative theory treatment. These short-time and weak-noise formulas yield analytic insight into how collective-spin moments govern both (i) the noiseless sensitivity and (ii) the leading noise-induced degradation of metrological usefulness. We identify a trade-off that is intrinsic to our commuting encoding-noise structure. We analyze the QFI dynamics for the Gaussian spin state (GSS) superpositions, encompassing spin coherent state (SCS), Dicke state superpositions, spin-squeezed states, and GHZ-like states. Predictions from indicators of the QFI dynamics are compared to both the quantum Cramér--Rao bound and the measurement-specific sensitivity bounds for an optimal parameter and interrogation time under a finite total time resource. When possible, we analytically derive the measurement-specific sensitivity bounds for spin-projection and parity-based measurements.
The generation of entanglement in atomic systems plays a central topic in the fields of quantum information storage and processing. Moreover, a special category of entangled states of multi-atom ensembles, spin squeezed states, have been proven to lead to considerable improvement in the sensitivity of precision measurements compared to systems involving uncorrelated atoms. A treatment of entanglement in open systems is, however, incomplete without a precise description of the process of decoherence which necessarily accompanies it. The theory of entanglement and decoherence are the two main topics of this thesis. Methods are described for the generation of strong correlations in large atomic ensembles using either cavity quantum electrodynamics or measurement outcome conditioned quantum dynamics. Moreover, the description of loss of entanglement resulting from the coupling to a noise reservoir (electromagnetic vacuum) is explored. A spin squeezing parameter is used throughout this thesis as both a measure of entanglement strength and as an indication of the sensitivity improvement above the so-called standard quantum limit (sensitivity obtained with uncorrelated particles) in metrology. The first scheme considered consists of a single mode cavity field interacting with a collection of atoms for which spin squeezing is produced in both resonant and off-resonant regimes. In the resonant case, transfer of squeezing from a field state to the atoms is analyzed, while in the off-resonant regime squeezing is produced via an effective nonlinear interaction (one-axis twisting Hamiltonian). A second, more experimentally realistic case, is one involving the interaction of free space atoms with laser pulses; a projective measurement of a source field originating from atomic fluctuations provides a means of preparing atomic collective states such as spin squeezed and Schrodinger cat states. A new unravelling is proposed, that employs the detection of photon number in a single output channel and is capable of producing mesoscopic Schrodinger cat states in a single step. As a first step to understanding the role of cooperative decoherence, of importance in the case of dense pencil-shaped atomic ensembles, the collective spin decoherence of a two multilevel atom system is derived. This calculation is also relevant to entanglement loss for two qubits manipulated using with reading/writing pulses. Finally, a scheme is proposed in which arbitrarily strong entanglement can be produced in a four-wave mixing setup, where the preparation of the atoms in a dark state limits the decoherence to negligible values.
Quantum metrology aims to yield higher measurement precisions via quantum techniques such as entanglement. It is of great importance for both fundamental sciences and practical technologies, from testing equivalence principle to designing high-precision atomic clocks. However, due to environment effects, highly entangled states become fragile and the achieved precisions may even be worse than the standard quantum limit (SQL). Here we present a high-precision measurement scheme via spin cat states (a kind of non-Gaussian entangled states in superposition of two quasi-orthogonal spin coherent states) under dissipation. In comparison to maximally entangled states, spin cat states with modest entanglement are more robust against losses and their achievable precisions may still beat the SQL. Even if the detector is imperfect, the achieved precisions of the parity measurement are higher than the ones of the population measurement. Our scheme provides a realizable way to achieve high-precision measurements via dissipative quantum systems of Bose atoms.
Quantum-enhanced sensing is commonly benchmarked using the quantum Fisher information (QFI), often interpreted as a direct indicator of achievable precision. However, such an interpreta- tion is only justified within a fully specified inference framework that consistently incorporates state preparation, measurement design, resource accounting, estimator construction, prior information, and finite data effects. Here we develop an operational, end-to-end framework for quantum sensing under finite resources and identify general principles required for meaningful performance assess- ment. A central conceptual point is that the relevant unit of estimation is not a single detection event, but the complete data set required to construct a consistent estimator. Rather than relying on abstract statistical formalism, we analyze a set of paradigmatic and experimentally relevant ex- amples that expose common pitfalls in widely discussed quantum sensing strategies. These include quantum interferometry, sensing with squeezed states, and criticality-inspired protocols. Our results clarify when large Fisher information or nonclassical resources translate into genuine metrological advantage, and when they do not. They further provide a practical methodology for designing and evaluating quantum sensing protocols under realistic experimental constraints.
A usual assumption in quantum estimation is that the unknown parameter labels the possible states of the system, while it influences neither the sample space of outcomes nor the measurement aimed at extracting information on the parameter itself. This assumption is crucial to prove the quantum Cram\'er-Rao theorem and to introduce the quantum Fisher information as an upper bound to the Fisher information of any possible measurement. However, there are relevant estimation problems where this assumption does not hold and an alternative approach should be developed to find the genuine ultimate bound to precision of quantum measurements. We investigate physical situations where there is an intrinsic dependence of the measurement strategy on the parameter and find that quantum-enhanced measurements may be more precise than previously thought.