A central topic in the emerging field of quantum thermodynamics is the definition of thermodynamic work in the quantum regime. One widely used solution is to define work for a closed system undergoing non-equilibrium dynamics according to the two-point energy measurement scheme. However, due to the invasive nature of measurement the two-point quantum work probability distribution cannot describe the statistics of energy change from the perspective of the system alone. We here introduce the quantum histories framework as a method to characterise the thermodynamic properties of the unmeasured , closed dynamics. Constructing continuous power operator trajectories allows us to derive an alternative quantum work distribution for closed quantum dynamics that fulfils energy conservation and is time-reversal symmetric. This opens the possibility to compare the measured work with the unmeasured work, contrasting with the classical situation where measurement does not affect the work statistics. We find that the work distribution of the unmeasured dynamics leads to deviations from the classical Jarzynski equality and can have negative values highlighting distinctly non-classical features of quantum work.
A central topic in the emerging field of quantum thermodynamics is the definition of thermodynamic work in the quantum regime. One widely used solution is to define work for a closed system undergoing non-equilibrium dynamics according to the two-point energy measurement scheme. However, due to the invasive nature of measurement the two-point quantum work probability distribution cannot describe the statistics of energy change from the perspective of the system alone. We here introduce the quantum histories framework as a method to characterise the thermodynamic properties of the unmeasured , closed dynamics. Constructing continuous power operator trajectories allows us to derive an alternative quantum work distribution for closed quantum dynamics that fulfils energy conservation and is time-reversal symmetric. This opens the possibility to compare the measured work with the unmeasured work, contrasting with the classical situation where measurement does not affect the work statistics. We find that the work distribution of the unmeasured dynamics leads to deviations from the classical Jarzynski equality and can have negative values highlighting distinctly non-classical features of quantum work.
At non-zero temperature classical systems exhibit statistical fluctuations of thermodynamic quantities arising from the variation of the system's initial conditions and its interaction with the environment. The fluctuating work, for example, is characterised by the ensemble of system trajectories in phase space and, by including the probabilities for various trajectories to occur, a work distribution can be constructed. However, without phase space trajectories, the task of constructing a work probability distribution in the quantum regime has proven elusive. Here we use quantum trajectories in phase space and define fluctuating work as power integrated along the trajectories, in complete analogy to classical statistical physics. The resulting work probability distribution is valid for any quantum evolution, including cases with coherences in the energy basis. We demonstrate the quantum work probability distribution and its properties with an exactly solvable example of a driven quantum harmonic oscillator. An important feature of the work distribution is its dependence on the initial statistical mixture of pure states, which is reflected in higher moments of the work. The proposed approach introduces a fundamentally different perspective on quantum thermodynamics, allowing full thermodynamic characterisation of the dynamics of quantum systems, including the measurement process.
At nonzero temperature classical systems exhibit statistical fluctuations of thermodynamic quantities arising from the variation of the system's initial conditions and its interaction with the environment. The fluctuating work, for example, is characterized by the ensemble of system trajectories in phase space and, by including the probabilities for various trajectories to occur, a work distribution can be constructed. However, without phase-space trajectories, the task of constructing a work probability distribution in the quantum regime has proven elusive. Here we use quantum trajectories in phase space and define fluctuating work as power integrated along the trajectories, in complete analogy to classical statistical physics. The resulting work probability distribution is valid for any quantum evolution, including cases with coherences in the energy basis. We demonstrate the quantum work probability distribution and its properties with an exactly solvable example of a driven quantum harmonic oscillator. An important feature of the work distribution is its dependence on the initial statistical mixture of pure states, which is reflected in higher moments of the work. The proposed approach introduces a fundamentally different perspective on quantum thermodynamics, allowing full thermodynamic characterization of the dynamics of quantum systems, including the measurement process.
A central challenge in quantum thermodynamics is to access work fluctuations in coherent processes without distorting the energetics of the unmeasured evolution. In standard two-point schemes, the initial energy measurement dephases coherent inputs, causing the measured average work to differ from that of the unmeasured evolution. Here, we develop an operational scheme for accessing work statistics for closed quantum systems based on the abstract notion of variation in the Heisenberg picture Hamiltonian. This scheme preserves energetically relevant coherences, thereby faithfully reproducing unmeasured work, while still producing positive probabilities. We derive modified Jarzynski and Crooks relations, as well as a thermodynamic uncertainty relation, identifying coherence-induced correction terms. Furthermore, we show that this scheme can reliably quantify the performance of a coherent engine in situations where the two-point energy measurement would suppress work output. In addition, the scheme requires only a single measurement and can predict the work associated with a subsequent unitary transformation. We exploit this feature to construct a Maxwell-demon protocol that can outperform energy-based feedback engines for coherent work extraction. Our results establish this scheme as a framework for accessing coherent work fluctuations without erasing the coherence that drives quantum thermodynamic performance.
Abstract Work is a process-based quantity, and its measurement typically requires interaction with a measuring device multiple times. While classical systems allow for non-invasive and accurate measurements, quantum systems present unique challenges due to the influence of the measuring device on the final value of work. As recent studies have shown, among these challenges is the impossibility of formulating a universal definition of work that respects energy conservation for coherent quantum systems and is compatible with the Jarzynski equality—a fluctuation relation linking the equilibrium free energy difference to the non-equilibrium work. Here, we overcome this challenge by introducing a genuinely quantum, positive correction to the Jarzynski equality stemming from imposing energy conservation. When sufficiently large, this correction forces quantum work to violate the second law more often. Moreover, we construct modified two-point measurement (TPM) schemes for work, along with circuit implementations for them. These measurement schemes correctly certify energy conservation and remain consistent with our quantum-corrected fluctuation relation.
Estimation of work at the quantum scale remains a central challenge in quantum thermodynamics. Canonical approaches have a fundamental drawback: they assume classical control of the quantum system, as implicit in a time-dependent Hamiltonian. Yet the energetic cost of implementing this control is omitted and can exceed the system's energy scale by orders of magnitude, calling into question the operational significance of work values. We address this by autonomizing the controlled energy transfer, embedding the driven dynamics into an energy-conserving evolution on a larger quantum system. Work is then unambiguously identified with the energy transferred between the two systems, singling out a unique observable on the driven system: the work operator. We show that the quantum work operator evades a no-go theorem by deriving a quantum fluctuation theorem that recovers the Jarzynski equality in classical scenarios. We incorporate imperfect control and quantify corrections to work statistics. Extending the framework to open quantum systems, we obtain an operatorial first law in which work, heat, and internal-energy changes are represented by distinct operators on the reduced system. Together, these results settle the long-standing debate over whether work is a quantum observable: it is, once the controlling system is included in the description rather than treated as external.
We investigate quantum work statistics within the standard two-point measurement scheme in continuously monitored quantum systems, including the effects of generalized unitary evolution, possibly controlled by quantum circuit models, and multiple generalized measurements as well as postselection of trajectories. We derive an explicit expression for the work generating function that naturally incorporates non-Hermitian dynamics arising from quantum jump processes and reveals deviations from the standard Jarzynski equality due to measurement-induced asymmetries. We illustrate our theoretical framework by analyzing a one-dimensional transverse-field Ising model under local spin monitoring. In this model, increased measurement strength projects the system onto the no-click state, leading to a suppression of energy fluctuations and measurement-induced energy saturation, reminiscent of the quantum Zeno effect. Moreover, we find signatures of the measurement-induced transition observed in the no-click limit in the moments of the work distribution.