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arXiv:1609.01620 · Physical review. E

Entropy production and thermalization in the one-atom maser

E. Solano‐Carrillo

Published Dec 12, 2016• 1 citation
arXivHTMLPDF

Abstract

In the configuration in which two-level atoms with an initial thermal distribution of their states are sent in succession to a cavity sustaining a single mode of electromagnetic radiation, one atom leaving the cavity as the next one enters it (as in the one-atom maser), Jaynes and Cummings showed that the steady state of the field, when many atoms have traversed the cavity, is thermal with a temperature different than that of the atoms in the off-resonant situation. Having an interaction between two subsystems which maintains them at different temperatures was then understood as leading to an apparent violation of energy conservation. Here we show, by calculating the quantum entropy production in the system, that this difference of temperatures is consistent with having the subsystems adiabatically insulated from each other as the steady state is approached. At resonance the insulation is removed and equilibration of the temperatures is achieved.

DOI
10.1103/physreve.94.062116

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In the configuration in which two-level atoms with an initial thermal distribution of their states are sent in succession to a cavity sustaining a single mode of electromagnetic radiation, one atom leaving the cavity as the next one enters it (as in the one-atom maser), Jaynes and Cummings showed that the steady state of the field, when many atoms have traversed the cavity, is thermal with a temperature different than that of the atoms in the off-resonant situation. Having an interaction between two subsystems which maintains them at different temperatures was then understood as leading to an apparent violation of energy conservation. Here we show, by calculating the quantum entropy production in the system, that this difference of temperatures is consistent with having the subsystems adiabatically insulated from each other as the steady state is approached. At resonance the insulation is removed and equilibration of the temperatures is achieved.
In this thesis we develop an approach to nonequilibrium quantum-statistical mechanics which is based on the consideration of the thermodynamic entropy as being a quantum observable with an associated hermitian operator and with its own equation of motion, from which the rate of entropy production can be studied. The relationship of this quantum observable---the expectation value of which is proved to obey the laws of thermodynamics and is thus called the thermodynamic entropy---with heat dissipation in quantum many-body systems is investigated in detail. After showing how the classical theory of nonequilibrium thermodynamics is obtained from our entropy-production formalism in the limit of very weakly coupled subsystems of a larger isolated quantum system, the solution of the equation of motion for the thermodynamic entropy operator is formally obtained and applied to the case of electrons interacting with phonons and being driven by an external electric field, arriving at an explicit expression for the Joule heat without any a priori consideration of the rate of change of the energy of the system. Finally, the formalism is applied to solve a puzzle introduced with the most basic model for atom-light interactions: the Jaynes-Cummings model. Without using the correct thermodynamic arguments implied by our entropy-production theory, this model leads to the conclusion that a stream of two-level atoms sent to a cavity filled with monochromatic photons---in the so called one-atom maser configuration---thermalize, under off-resonant conditions, to a temperature different from that of the photons, casting doubts on the validity of the principle of conservation of energy.
We study the relaxation properties of the quantized electromagnetic field in a cavity under repeated interactions with single two-level atoms, so-called one-atom maser. We improve the ergodic results obtained in [BP] and prove that, whenever the atoms are initially distributed according to the canonical ensemble at temparature T>0, all the invariant states are mixing. Under some non-resonance condition this invariant state is known to be thermal equilibirum at some renormalized temperature T* and we prove that the mixing is then arbitrarily slow, in other words that there is no lower bound on the relaxation speed.
. In this paper experiments performed with the one-atom maser are reviewed. Furthermore, possible experiments to test basic quantum physics are discussed. Introduction, the One-Atom-Maser The most promising avenue to study the generation process of radiation in lasers and masers is to drive a maser consisting of a single mode cavity by single atoms. This system, at first glance, seems to be another example of a Gedanken-experiment treated in the pioneering work of Jaynes and Cummings (1963), but such a one-atom maser (Meschede, Walther and Müller, 1985) really exists and can in addition be used to study the basic principles of radiation-atom interaction. The advantages of the system are: it is the first maser which sustains oscillations with less than one atom on the average in the cavity, this setup allows to study in detail the conditions necessary to obtain nonclassical radiation, especially radiation with sub-Poissonian photon statistics in a maser system directly in a Poissonian pumping process, and it is possible to study a variety of phenomena of a quantum field including the quantum measurement process. What are the tools that make this device work: It was the enormous progress in constructing superconducting cavities together with the laser preparation of highly excited atoms – Rydberg atoms – that have made the realization of such a one-atom maser possible.
We consider a two-level atom interacting with a single mode of the electromagnetic field in a cavity within the Jaynes-Cummings model. Initially, the atom is thermal while the cavity is in a coherent state. The atom interacts with the cavity field for a fixed time. After removing the atom from the cavity and applying a laser pulse the atom will be in a thermal state again. Depending on the interaction time with the cavity field the final temperature can be varied over a large range. We discuss how this method can be used to cool the internal degrees of freedom of atoms and create heat baths suitable for studying thermodynamics at the nanoscale.
Introduction In 1963, E. T. Jaynes and F. W. Cummings published a paper entitled “Comparison of Quantum and Semiclassical Radiation Theories, with Application to the Beam Maser.” This paper was written at a time when the quantum theory of the laser had not yet been worked out, and represented an attempt at discussing the new behaviour that could be expected from treating the field quantum mechanically instead of classically. Jaynes and Cummings began by considering the interaction between a single two-level molecule and a single field mode, a simple situation which has become known as the Jaynes-Cummings model. Treating then the maser medium as a beam of two-level systems initially in a mixture of their upper and lower states characterized by a temperature T , they found that the field mode reached a thermal equilibrium with temperature T f = Ω T /ω, where ω is the transition frequency of the two-level systems and Ω is the field mode frequency, provided that T > 0. For T < 0, the steady state field was found to contain an infinite amount of energy, an unphysical result resulting from the neglect of losses in the model. Jaynes and Cummings then proceeded to develop an alternative semi-classical theory of the beam maser, introducing their famous neo-classical theory of spontaneous emission. An important follow-up paper was published by F. W. Cummings, who studied the long-time behavior of a two-level system interacting with a quantized single-mode field initially in a coherent state.
There are only fistful of systems in physics that can be described by an exact theory from first principles and, at the same time, can be investigated under experimental conditions approaching the idealized theoretical ones. The one-atom-maser or micromaser provides such an example, making a detailed study of the fundamental properties of the atom-field interaction possible. The situation realized in a micromaser is very close to the ideal case of a single two-level atom interacting with a single quantized mode of a cavity field. In the micromaser the atoms have a dual purpose of both pumping the field and also probing it via measurements of the outgoing atoms. Any other means of measuring the field inside the resonator has the detrimental effect of lowering its Q-factor and thereby the photon storage time. The long photon storage time of the resonator allows for the decay of the field to be negligible during the passage of an atom and its interaction with the field. The behavior of atoms in a cavity is governed by the oscillatory exchange of energy between the atoms and the field, which is called Rabi oscillation. For cavity fields in the vacuum and few photon number states (Fock states), Rabi oscillations have been measured in the past. To prevent thermal effects from polluting the pure number states these experiments were performed at low temperatures (below 1 K). However, the observed resolution of the Rabi oscillations measurements was quite disappointing (only about 2% of the predicted theoretical value) and precluded more ambitious experiments like atom-atom correlations or time resolved investigations of the maser field dynamics. The observed contrast of Rabi oscillations can be considered as a figure of merit for the experimental resolution of quantum features of a maser field. Therefore, a high resolution in the measurements of Rabi oscillations is crucial. This thesis describes the methods and improvements applied to enhance the resolution of Rabi oscillations by a factor of 8. The following upgrades and developments proved to be crucial in this work: 1) The base temperature of the cryogenic system was lowered to 0.3 K, i.e. one third of the original value. At the same time, the time during which the system remains at the base temperature was improved by almost of an order of magnitude (to more than 12 h). 2) For the promotion of the atoms to the Rydberg regime new three-step diode laser setup was constructed. The excitation efficiency compared to the old dye laser was increased by two orders. Using top-of-fringe stabilization with new spectroscopic methods, specially designed error detection and feedback schemes as well as state-of-the-art PID regulators the continuous locking of lasers is about 8 h (compared to about 20 min with the old dye laser system). 3) The flexibility of using the three step excitation allows to excite different maser states and for the first time to investigate pure maser transition. 4) Various improvements on the atomic oven and the channeltron detection unit led to the reliable and stable production and detection of the atomic beam. Observed distribution of the atomic beam statistics reaches to within 6% the Poisson limit which is expected in the absence of experimental imperfections. 5) New developed techniques in magnetic field compensation allow to perform such measurements with two orders of magnitude better accuracy compared to the previous experiments. To demonstrate the new capabilities of the apparatus and to apply its improved resolution of quantum fields we performed a previously impossible in-depth analysis of mean photon number and the atomic inversion produced by a micromaser for various detunings between the cavity- and atomic resonance frequency.