We report an experimental observation of coherent population trapping in multilevel dark states prepared in the ground hyperfine states of
87Rb atoms confined in a room-temperature vapor cell. The dark states are created by a linearly polarized coupling laser that is tuned to the
87Rb D1 $F=2\ensuremath{\leftrightarrow}{F}^{\ensuremath{'}}=1$ or 2 transition and establishes \ensuremath{\Lambda}-type transition chains. The Doppler shift for the \ensuremath{\Lambda}-type transition chains is compensated by the left and right circularly polarized components of the coupling laser. The multilevel dark states that consist of three or two magnetic sublevels among the five degenerate magnetic sublevels in the
F=2 ground hyperfine state are probed by a weak probe laser scanned across the same
D1 transition and their existence is manifested by a strong dependence of the probe excitation on the probe polarization. Our experiment demonstrates the importance of coherent population trapping in a laser coupled degenerate multilevel open atomic system, which may play an important role in diverse physical phenomena such as atom cooling and trapping, optical pumping, and multiple laser excitation and ionization of atoms and molecules.
We study the response of an inhomogeneously broadened atomic three-level ladder system to a strong probe beam under conditions in which electromagnetically induced transparency would be induced on a weak probe beam. Theoretical analysis and experimental data show that saturation effects associated with the strong probe can substantially alter the behavior of the system and can result in enhanced probe absorption under exactly the same circumstances in which a weak probe would experience enhanced transparency. Strong probe effects are also shown to lead to a breakdown of the correspondence between population inversion and gain. A power-series solution of the density-matrix equations describing the ladder system provides a physical picture for strong probe effects in terms of interfering multiphoton transition pathways.