We establish a generic method to analyze the time evolution of open quantum many-body systems. Our approach is based on a variational integration of the quantum master equation describing the dynamics and naturally connects to a variational principle for its nonequilibrium steady state. We successfully apply our variational method to study dissipative Rydberg gases, finding very good quantitative agreement with small-scale simulations of the full quantum master equation. We observe that correlations related to non-Markovian behavior play a significant role during the relaxation dynamics towards the steady state. We further quantify this non-Markovianity and find it to be closely connected to an information-theoretical measure of quantum and classical correlations.
We establish a generic method to analyze the time evolution of open quantum many-body systems. Our approach is based on a variational integration of the quantum master equation describing the dynamics and naturally connects to a variational principle for its nonequilibrium steady state. We successfully apply our variational method to study dissipative Rydberg gases, finding very good quantitative agreement with small-scale simulations of the full quantum master equation. We observe that correlations related to non-Markovian behavior play a significant role during the relaxation dynamics towards the steady state. We further quantify this non-Markovianity and find it to be closely connected to an information-theoretical measure of quantum and classical correlations.
We present a novel generic framework to approximate the nonequilibrium steady states of dissipative quantum many-body systems. It is based on the variational minimization of a suitable norm of the quantum master equation describing the dynamics. We show how to apply this approach to different classes of variational quantum states and demonstrate its successful application to a dissipative extension of the Ising model, which is of importance to ongoing experiments on ultracold Rydberg atoms, as well as to a driven-dissipative variant of the Bose-Hubbard model. Finally, we identify several advantages of the variational approach over previously employed mean-field-like methods.
Numerous variational methods have been proposed for solving quantum many-body systems, but they often face exponentially increasing computational complexity as the Hilbert space dimension grows. To address this, we introduce a novel approach using quantum neural networks to simulate the dissipative dynamics of many-body open quantum systems. This method combines neural-network quantum state representation with the time-dependent variational principle, both implemented via quantum algorithms. This results in accurate open quantum dynamics described by the Lindblad quantum master equation, exemplified by the spin-boson and transverse field Ising models. Our approach avoids the computational expense of classical algorithms and demonstrates the potential advantages of quantum computing for many-body simulations. To reduce measurement errors, we introduce a projection reset procedure, which could benefit other quantum simulations. In addition, our approach can be extended to simulate non-Markovian quantum dynamics.
The theory of open quantum systems represents one of the major developments of quantum mechanics over the last 50 years. Its central object of study is constituted by quantum systems that cannot be regarded as fully isolated, but instead interact with additional degrees of freedom, giving rise to irreversible phenomena such as dissipation and decoherence. The tools provided by this framework are nowadays of paramount importance across many active areas of research, including quantum computation, thermodynamics, metrology and biology. In this thesis, we investigate three main topics within the field. The first contribution concerns the microscopic derivation of the evolution equations, socalled quantum master equations, for open systems which are also subject to external driving fields. Standard techniques developed for time-independent Hamiltonians encounter several difficulties in the time-dependent case, largely restricting their applicability to specific instances, such as periodic or adiabatic drivings. In contrast, a core result of the derivation presented in the thesis is that, when the environment is sufficiently Markovian (essentially, memoryless), the non-adiabatic contributions to the driving field can be neglected in a controlled fashion, yielding an accurate master equation with time-dependent generator, capable of correctly reproducing the open dynamics even for strong drivings. This result is further supported by benchmarks against numerically exact simulations. The second contribution addresses the long-time behavior of general types of (Markovian) quantum master equations, including those of the form introduced above. While this problem has been extensively analyzed in the time-independent setting, virtually no results are known for time-dependent generators. In particular, we establish the foundations of a general theory of relaxation, that is, convergence towards an asymptotic trajectory in the long-time limit, independently of the initial state. The main results include a theorem guaranteeing sufficient conditions for relaxation and the derivation of a rate function governing the convergence to the asymptotic trajectory. The analysis is further extended to a simple non-Markovian case. Moreover, we treat in detail the specific master equation derived in the first part, connecting the aforementioned relaxation property directly to the underlying microscopic dynamics. The third contribution investigates chirality-induced spin selectivity (CISS) effects from the perspective of open quantum systems. Although the majority of theoretical studies aiming to model CISS are based on a coherent description of the spin dynamics, such effects have been observed also for electrons subject to incoherent transport across molecular networks. In this regard, we provide a rigorous ab initio derivation of the microscopic Hamiltonian describing the electronic transport, incorporating electron spin effects and contributions stemming from the nuclear vibrations. Within this result, we critically revise a master equation approach aiming to explain the origin of CISS effects observed in photosynthetic complexes. Taken together, these contributions offer fresh insights and original results on the interplay between driving fields and dissipation, relaxation phenomena, and electronic spin transport in the presence of incoherent dynamics. More broadly, these results provide new theoretical tools with several potential applications in quantum technologies, from modeling of control pulses in noisy environments to quantum reservoir engineering, and contribute to a deeper understanding of the role of quantum effects in biological systems.
A central aim of physics is to describe the dynamics of physical sys-tems. Schrödinger’s equation does this for isolated quantum systems. Describing the time evolution of a quantum system that interacts with its environment, in its most general form, has proved to be difficult because the dynamics is dependent on the state of the environment and the corre-lations with it. For discrete processes, such as quantum gates or chemical reactions, quantum process tomography provides the complete descrip-tion of the dynamics, provided that the initial states of the system and the environment are independent of each other. However, many physical systems are correlated with the environment at the beginning of the ex-periment. Here, we give a prescription of quantum process tomography that yields the complete description of the dynamics of the system even when the initial correlations are present. Surprisingly, our method also gives quantitative expressions for the initial correlation. There is a rich history to the studies of decoherence of quantum systems due to the interactions with the surrounding degrees of freedom. When the dynamics of the system (S) is Markovian it can be described by a master equation [1, 2, 3]. Nowadays many researchers are interested in systems that are non-Markovian, as there is mounting evidence that some natural systems of importance may be non-Markovian [4] and such features may allow to manipulate and control quantum systems in desired ways. There is also a great deal of interest in systems that are initially correlated with their environments (E) because non-Markovianity and initial system-environment (SE) correlations are intimately related [5, 6, 7]. 1 ar
We propose a protocol to simulate the evolution of a non-Markovian open quantum system by considering a collisional process with a many-body system, which plays the role of an environment. As a result of our protocol, the environment spatial correlations are mapped into the time correlations of a noise that drives the dynamics of the open system. Considering the weak coupling limit, the open system can also be considered as a probe of the environment properties. In this regard, when preparing the environment in its ground state, a measurement of the dynamics of the open system allows to determine the length of the environment spatial correlations and therefore its critical properties. To illustrate our proposal we simulate the full system dynamics with matrix-product-states and compare this to the reduced dynamics obtained with an approximated variational master equation.
The basic features of the dynamics of open quantum systems, such as the dissipation of energy, the decay of coherences, the relaxation to an equilibrium or non-equilibrium stationary state, and the transport of excitations in complex structures are of central importance in many applications of quantum mechanics. The theoretical description, analysis and control of non-Markovian quantum processes play an important role in this context. While in a Markovian process an open system irretrievably loses information to its surroundings, non-Markovian processes feature a flow of information from the environment back to the open system, which implies the presence of memory effects and represents the key property of non-Markovian quantum behavior. Here, we review recent ideas developing a general mathematical definition for non-Markoviantiy in the quantum regime and a measure for the degree of memory effects in the dynamics of open systems which are based on the exchange of information between system and environment. We further study the dynamical effects induced by the presence of system-environment correlations in the total initial state and design suitable methods to detect such correlations through local measurements on the open system.