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arXiv:1509.07091 · Physical Review A

Measurements of the ground-state polarizabilities of Cs, Rb, and K using atom interferometry

Maxwell D. Gregoire, Ivan Hromada, William F. Holmgren, Raisa Trubko, Alexander D. Cronin

Published Nov 20, 2015• 78 citations
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Abstract

We measured the ground-state static electric-dipole polarizabilities of Cs, Rb, and K atoms using a three-nanograting Mach-Zehnder atom beam interferometer. Our measurements provide benchmark tests for atomic structure calculations and thus test the underlying theory used to interpret atomic parity-nonconservation experiments. We measured ${\ensuremath{\alpha}}_{\mathrm{Cs}}=4\ensuremath{\pi}{\ensuremath{\epsilon}}_{0}\ifmmode\times\else\texttimes\fi{}59.39(9)\phantom{\rule{0.16em}{0ex}}{\AA{}}^{3},{\ensuremath{\alpha}}_{\mathrm{Rb}}=4\ensuremath{\pi}{\ensuremath{\epsilon}}_{0}\ifmmode\times\else\texttimes\fi{}47.39(8)\phantom{\rule{0.16em}{0ex}}{\AA{}}^{3}$, and ${\ensuremath{\alpha}}_{\mathrm{K}}=4\ensuremath{\pi}{\ensuremath{\epsilon}}_{0}\ifmmode\times\else\texttimes\fi{}42.93(7)\phantom{\rule{0.16em}{0ex}}{\AA{}}^{3}$. In atomic units, these measurements are ${\ensuremath{\alpha}}_{\mathrm{Cs}}=401.2(7),{\ensuremath{\alpha}}_{\mathrm{Rb}}=320.1(6)$, and ${\ensuremath{\alpha}}_{\mathrm{K}}=290.0(5)$. We report ratios of polarizabilities ${\ensuremath{\alpha}}_{\mathrm{Cs}}/{\ensuremath{\alpha}}_{\mathrm{Rb}}=1.2532(10),{\ensuremath{\alpha}}_{\mathrm{Cs}}/{\ensuremath{\alpha}}_{\mathrm{K}}=1.3834(9)$, and ${\ensuremath{\alpha}}_{\mathrm{Rb}}/{\ensuremath{\alpha}}_{\mathrm{K}}=1.1040(9)$ with smaller fractional uncertainty because the systematic errors for individual measurements are largely correlated. Since Cs atom beams have short de Broglie wavelengths, we developed measurement methods that do not require resolved atom diffraction. Specifically, we used phase choppers to measure atomic beam velocity distributions, and we used electric field gradients to give the atom interference pattern a phase shift that depends on atomic polarizability.

DOI
10.1103/physreva.92.052513

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We measured the ground-state static electric-dipole polarizabilities of Cs, Rb, and K atoms using a three-nanograting Mach-Zehnder atom beam interferometer. Our measurements provide benchmark tests for atomic structure calculations and thus test the underlying theory used to interpret atomic parity-nonconservation experiments. We measured \ensuremathαCs=4\ensuremathπ\ensuremathϵ0\ifmmode×\else\texttimes\fi59.39(9)A˚3,\ensuremathαRb=4\ensuremathπ\ensuremathϵ0\ifmmode×\else\texttimes\fi47.39(8)A˚3{\ensuremath{\alpha}}_{\mathrm{Cs}}=4\ensuremath{\pi}{\ensuremath{\epsilon}}_{0}\ifmmode\times\else\texttimes\fi{}59.39(9)\phantom{\rule{0.16em}{0ex}}{\AA{}}^{3},{\ensuremath{\alpha}}_{\mathrm{Rb}}=4\ensuremath{\pi}{\ensuremath{\epsilon}}_{0}\ifmmode\times\else\texttimes\fi{}47.39(8)\phantom{\rule{0.16em}{0ex}}{\AA{}}^{3}\ensuremathαCs​=4\ensuremathπ\ensuremathϵ0​\ifmmode×\else\texttimes\fi59.39(9)A˚3,\ensuremathαRb​=4\ensuremathπ\ensuremathϵ0​\ifmmode×\else\texttimes\fi47.39(8)A˚3, and \ensuremathαK=4\ensuremathπ\ensuremathϵ0\ifmmode×\else\texttimes\fi42.93(7)A˚3{\ensuremath{\alpha}}_{\mathrm{K}}=4\ensuremath{\pi}{\ensuremath{\epsilon}}_{0}\ifmmode\times\else\texttimes\fi{}42.93(7)\phantom{\rule{0.16em}{0ex}}{\AA{}}^{3}\ensuremathαK​=4\ensuremathπ\ensuremathϵ0​\ifmmode×\else\texttimes\fi42.93(7)A˚3. In atomic units, these measurements are \ensuremathαCs=401.2(7),\ensuremathαRb=320.1(6){\ensuremath{\alpha}}_{\mathrm{Cs}}=401.2(7),{\ensuremath{\alpha}}_{\mathrm{Rb}}=320.1(6)\ensuremathαCs​=401.2(7),\ensuremathαRb​=320.1(6), and \ensuremathαK=290.0(5){\ensuremath{\alpha}}_{\mathrm{K}}=290.0(5)\ensuremathαK​=290.0(5). We report ratios of polarizabilities \ensuremathαCs/\ensuremathαRb=1.2532(10),\ensuremathαCs/\ensuremathαK=1.3834(9){\ensuremath{\alpha}}_{\mathrm{Cs}}/{\ensuremath{\alpha}}_{\mathrm{Rb}}=1.2532(10),{\ensuremath{\alpha}}_{\mathrm{Cs}}/{\ensuremath{\alpha}}_{\mathrm{K}}=1.3834(9)\ensuremathαCs​/\ensuremathαRb​=1.2532(10),\ensuremathαCs​/\ensuremathαK​=1.3834(9), and \ensuremathαRb/\ensuremathαK=1.1040(9){\ensuremath{\alpha}}_{\mathrm{Rb}}/{\ensuremath{\alpha}}_{\mathrm{K}}=1.1040(9)\ensuremathαRb​/\ensuremathαK​=1.1040(9) with smaller fractional uncertainty because the systematic errors for individual measurements are largely correlated. Since Cs atom beams have short de Broglie wavelengths, we developed measurement methods that do not require resolved atom diffraction. Specifically, we used phase choppers to measure atomic beam velocity distributions, and we used electric field gradients to give the atom interference pattern a phase shift that depends on atomic polarizability.
We measured the ground-state electric-dipole polarizability of sodium, potassium, and rubidium using a Mach-Zehnder atom interferometer with an electric-field gradient. We find ${\ensuremath{\alpha}}_{\mathrm{Na}}=24.11(2){}_{\mathrm{stat}}(18){}_{\mathrm{sys}}\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}24}{\mathrm{cm}}^{3}$, ${\ensuremath{\alpha}}_{\mathrm{K}}=43.06(14)(33)$, and ${\ensuremath{\alpha}}_{\mathrm{Rb}}=47.24(12)(42)$. Since these measurements were all performed in the same apparatus and subject to the same systematic errors, we can present polarizability ratios with 0.30.3%0.3 uncertainty. We find ${\ensuremath{\alpha}}_{\mathrm{Rb}}/{\ensuremath{\alpha}}_{\mathrm{Na}}=1.959(5)$, ${\ensuremath{\alpha}}_{\mathrm{K}}/{\ensuremath{\alpha}}_{\mathrm{Na}}=1.786(6)$, and ${\ensuremath{\alpha}}_{\mathrm{Rb}}/{\ensuremath{\alpha}}_{\mathrm{K}}=1.097(5)$. We combine our ratio measurements with the higher-precision measurement of sodium polarizability by Ekstrom et al. [Phys. Rev. A 51, 3883 (1995)] to find ${\ensuremath{\alpha}}_{\mathrm{K}}=43.06(21)$ and ${\ensuremath{\alpha}}_{\mathrm{Rb}}=47.24(21)$.
I used a Mach-Zehnder atom interferometer to measure the static electric-dipole polarizabilities of K, Rb, and Cs atoms with 0.11\% uncertainty. Static polarizability measurements serve as benchmark tests for 𝑎𝑏 𝑖𝑛𝑖𝑡𝑖𝑜 atomic structure calculations. Calculating atomic properties such as polarizabilities, van der Waals coefficients, state lifetimes, or oscillator strengths involves accurately calculating the valence electrons' electric-dipole transition matrix elements. Additionally, testing Cs atomic structure calculations helps interpret the results of parity non-conservation experiments, which in turn places constraints on beyond-the-standard-model physics. I discuss improvements to our experiment that allowed us to measure static polarizabilities with 0.11% uncertainty, and we present our results in the context of recent 𝑎𝑏 𝑖𝑛𝑖𝑡𝑖𝑜 and semi-empirical static polarizabilities and recent, high-precision measurements of excited state lifetimes and van der Waals C₆ coefficients. I also used our interferometer to develop a new technique for inertial sensing. High precision, portable, atom-interferometer gyroscopes and accelerometers are desirable for self-contained inertial navigation and in the future may be used for tests of General Relativity and searches for gravitational waves using satellite-mounted inertial sensors. Satellite-mounted atom interferometers are challenging to build because of size, weight, power, and reliability constraints. Atom interferometers that use nanogratings to diffract atoms are attractive for satellite-mounted inertial sensing applications because nanogratings weigh approximately nothing and require no power. We developed a new 𝑖𝑛 𝑠𝑖𝑡𝑢 measurement technique using our nanograting atom interferometer, and we used it to measure inertial forces for the benefit of our static polarizability measurements. I also review how to calculate the sensitivity of a nanograting atom interferometer, and I employed these calculations in order to design a portable, nanograting atom interferometer inertial sensor.
We present revised measurements of the static electric dipole polarizabilities of K, Rb, and Cs based on atom interferometer experiments presented in [Phys. Rev. A 2015, 92, 052513] but now re-analyzed with new calibrations for the magnitude and geometry of the applied electric field gradient. The resulting polarizability values did not change, but the uncertainties were significantly reduced. Then we interpret several measurements of alkali metal atomic polarizabilities in terms of atomic oscillator strengths fikf_{ik}fik​, Einstein coefficients AikA_{ik}Aik​, state lifetimes τkτ_{k}τk​, transition dipole matrix elements DikD_{ik}Dik​, line strengths SikS_{ik}Sik​, and van der Waals C6C_6C6​ coefficients. Finally, we combine atom interferometer measurements of polarizabilities with independent measurements of lifetimes and C6C_6C6​ values in order to quantify the residual contribution to polarizability due to all atomic transitions other than the principal nsnsns-npJnp_JnpJ​ transitions for alkali metal atoms.
We present revised measurements of the static electric dipole polarizabilities of K, Rb, and Cs based on atom interferometer experiments presented in [Phys. Rev. A 2015, 92, 052513] but now re-analyzed with new calibrations for the magnitude and geometry of the applied electric field gradient. The resulting polarizability values did not change, but the uncertainties were significantly reduced. Then, we interpret several measurements of alkali metal atomic polarizabilities in terms of atomic oscillator strengths fik, Einstein coefficients Aik, state lifetimes τk, transition dipole matrix elements Dik, line strengths Sik, and van der Waals C6 coefficients. Finally, we combine atom interferometer measurements of polarizabilities with independent measurements of lifetimes and C6 values in order to quantify the residual contribution to polarizability due to all atomic transitions other than the principal ns-npJ transitions for alkali metal atoms.
The electric dipole polarizability of the alkali-metal atoms Na, K, Rb, and Cs are determined by measuring the deflection of a velocity-selected beam by an inhomogeneous electric field. It is shown experimentally that scattering of slower beam atoms by background gas in the apparatus is an important systematic error in measurements of this kind if a beam-velocity selector is not used, and that this scattering is responsible for the discrepancies between different, earlier beam-deflection measurements of polarizability. The polarizability values obtained in this work are $\ensuremath{\alpha}(\mathrm{Na})=24.4\ifmmode\pm\else\textpm\fi{}1.7$ A˚3{\mathrm{\AA{}}}^{3}A˚3, $\ensuremath{\alpha}(\mathrm{K})=45.2\ifmmode\pm\else\textpm\fi{}3.2$ A˚3{\mathrm{\AA{}}}^{3}A˚3, $\ensuremath{\alpha}(\mathrm{Rb})=48.7\ifmmode\pm\else\textpm\fi{}3.4$ A˚3{\mathrm{\AA{}}}^{3}A˚3, and $\ensuremath{\alpha}(\mathrm{Cs})=63.3\ifmmode\pm\else\textpm\fi{}4.6$ A˚3{\mathrm{\AA{}}}^{3}A˚3.
Atomic polarizability plays an essential role in topics ranging from van der Waals interactions, state lifetimes, and indices of refraction, to next generation atomic clocks and atomic parity non-conservation experiments. Polarizability measurements, such as the ones described in this thesis, provide valuable input to these subjects and serve as benchmark tests for sophisticated atomic structure calculations. We measured the static polarizability of potassium and rubidium with record precision and 0.5% uncertainty using a Mach-Zehnder atom interferometer with an electric-field gradient. To support future precision measurements of polarizability, we developed a new atom beam velocity measurement technique called phase choppers. Using phase choppers, we demonstrated measurements of mean atom beam velocity with an uncertainty of 0.1%. We also developed a new way to probe atomic structure: a measurement of a zero-crossing of the dynamic polarizability of potassium, known as a magic-zero wavelength. We measured the first magic-zero wavelength of potassium with 1.5 pm uncertainty and established a new benchmark measurement for the ratio of the D1 and D2 line strengths. Finally, we propose the use of a resonant photoionization detector for measurements of strontium polarizability, and the use of contrast interferometry for measurements of alkali dimer tensor polarizabilities.