In quantum mechanics, many observables for a quantum system are represented as self-adjoint linear operators (possibly unbounded) on a complex Hilbert space
H. In this paper, we introduce a binary relation
⊥ on
S(H) of all self-adjoint linear operators (including unbounded) on
H. We obtain that
A⊥B implies that
A,B are affiliated with some abelian von Neumann algebra at the same time. Depending on
⊥,S(H) can be constructed to be a generalized orthoalgebra. Then we present the orthoalgebra order
⪯ and the traditional order
≤ on
S(H) and give some properties about these two orders. We prove that for
A,B∈S(H),
A⪯B if and only if
A has a value in
Δ implies that
B has a value in
Δ for every Borel set
Δ not containing
0. Moreover, we study the existence of the infimum
A∧B and supremum
A∨B for
A,B∈S(H) with respect to
⪯. Finally, we prove that
Q∧P=0 where
Q and
P are the significant quantum observables corresponding to the position and momentum.}