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arXiv:1507.01389 · Physical Review B

Delta chain with anisotropic ferromagnetic and antiferromagnetic interactions

Д. В. Дмитриев, V. Ya. Krivnov

Published Nov 20, 2015• 25 citations
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Abstract

We consider analytically and numerically an anisotropic $\text{spin}\ensuremath{-}\frac{1}{2}$ delta chain (sawtooth chain) with nearest-neighbor ferromagnetic and next-nearest-neighbor antiferromagnetic interactions. For certain values of the interactions a lowest one-particle band becomes flat and there is a class of localized-magnon eigenstates which form a ground state with a macroscopic degeneracy. In this case the model depends on a single parameter which can be chosen as the anisotropy of the exchange interactions. When this parameter changes from zero to infinity the model interpolates between the one-dimensional isotropic ferromagnet and the frustrated Ising model on the delta chain. It is shown that the low-temperature thermodynamic properties in these limiting cases are governed by the specific structure of the excitation spectrum. In particular, the specific heat has one or infinite number of low-temperature maxima for the small or the large anisotropy parameter, correspondingly. Qualitative features of such behavior survive when the interaction parameters deviate from the relations providing the local magnon ground state.

DOI
10.1103/physrevb.92.184422

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We consider analytically and numerically an anisotropic spin\ensuremath−12\text{spin}\ensuremath{-}\frac{1}{2}spin\ensuremath−21​ delta chain (sawtooth chain) with nearest-neighbor ferromagnetic and next-nearest-neighbor antiferromagnetic interactions. For certain values of the interactions a lowest one-particle band becomes flat and there is a class of localized-magnon eigenstates which form a ground state with a macroscopic degeneracy. In this case the model depends on a single parameter which can be chosen as the anisotropy of the exchange interactions. When this parameter changes from zero to infinity the model interpolates between the one-dimensional isotropic ferromagnet and the frustrated Ising model on the delta chain. It is shown that the low-temperature thermodynamic properties in these limiting cases are governed by the specific structure of the excitation spectrum. In particular, the specific heat has one or infinite number of low-temperature maxima for the small or the large anisotropy parameter, correspondingly. Qualitative features of such behavior survive when the interaction parameters deviate from the relations providing the local magnon ground state.
We investigate the spin-1/2 Heisenberg model on the delta chain (sawtooth chain) with ferromagnetic nearest-neighbor and antiferromagnetic next-neighbor interactions. For a special ratio between these interactions there is a class of exact ground states formed by localized magnons and the ground state is macroscopically degenerate. The degree of this degeneration is found analytically. It is shown that the residual entropy per spin is s0=12ln2{s}_{0}=\frac{1}{2}ln\phantom{\rule{0.16em}{0ex}}2s0​=21​ln2. An important feature of this model is a sharp decrease of the gaps for excited states with an increase of the number of magnons. These excitations give an essential contribution to the low-temperature thermodynamics. The corresponding thermodynamic quantities are calculated using full exact diagonalization of finite chains up to N=22N=22N=22. The behavior of the considered model is compared with that of the delta chain with both antiferromagnetic interactions.
We investigate spin-12anisotropic model of a linear chain of triangles with competing ferro- and antiferromagnetic interactions and ferromagneic Heisenberg interactions between triangles. For a certain ratio between interactions the one-magnon excitation band is dispersionless leading to an existence of localized-magnon states which form macroscopically degenerated ground states. The spectrum of excitations has a specific structure depending on the value of the triangle-triangle interaction. Such specific structure determines the low-temperature thermodynamics and, in particular, the temperature dependence of a specific heat. In the limit of strong anisotropy of interactions the spectrum has a multi-scale structure which consists of subsets rank-ordered on small parameter. Each subset is responsible for the appearance of the peak in the temperature dependence of the specific heat.
We consider analytically and numerically an anisotropic spin-[Formula: see text] delta-chain (sawtooth chain) in which exchange interactions between apical and basal spins are ferromagnetic and those between basal spins are antiferromagnetic. In the limit of strong anisotropy of exchange interactions this model can be considered as the Ising delta chain with macroscopic degenerate ground state perturbed by transverse quantum fluctuations. These perturbations lift the ground state degeneracy and the model reduces to the basal XXZ spin chain in the magnetic field induced by static apical spins. We show that the ground state of such a model is ferrimagnetic. The excitations of the model are formed by ferrimagnetic domains separated by domain walls with a finite energy. At low temperatures the system is effectively divided into two independent subsystems, the apical subsystem described by the Ising spin-[Formula: see text] chain and the basal subsystem described by the XXZ chain with infinite zz interactions.
We consider a spin-[Formula: see text] kagome-like chain with competing ferro- and antiferromagnetic anisotropic exchange interactions. The ground state phase diagram of this model consists of the ferromagnetic and ferrimagnetic phases. We study the ground state and the low-temperature properties on the phase boundary between these phases. The ground state on this phase boundary is macroscopically degenerate and consists of localized magnon states. We calculate the ground state degeneracy and corresponding residual entropy. The spontaneous magnetization has a jump on the phase boundary confirming the first-order type of the phase transition. In the limit of a strong anisotropy, the spectrum of the low-energy excitations has multi-scale structure governing the peculiar features of the specific heat behavior.
Abstract We consider the strongly anisotropic spin-1/2 XXZ model on the sawtooth-chain lattice with ferromagnetic longitudinal interaction Jzz = ΔJ and aniferromagnetic transversal interaction Jxx = Jyy = J > 0. At Δ = −1∕2 the lowest one-magnon excitation band is dispersionless (flat) leading to a massively degenerate set of ground states. Interestingly, this model admits a three-coloring representation of the ground-state manifold [H.J. Changlani et al., Phys. Rev. Lett. 120, 117202 (2018)]. We characterize this ground-state manifold and elaborate the low-temperature thermodynamics of the system. We illustrate the manifestation of the flat-band physics of the anisotropic model by comparison with two isotropic flat-band Heisenberg sawtooth chains. Our analytical consideration is complemented by exact diagonalization and finite-temperature Lanczos method calculations. Graphical abstract
Background. Low-dimensional quantum magnets based on geometrically frustrated lattices are of considerable interest last time. As a typical example of such systems is the delta-chain which is a linear chain of triangles with spins on vertices. The delta-chain with AF exchange interactions is well studied and has a number of unusual properties. However, the same model with competing ferro (F)-and antiferromagnetic (AF) interactions is less studied. The purpose of this work is the study of the anisotropic F-AF delta-chain on the critical line separating different ground state phases, the calculation of the ground state degeneracy, residual entropy etc. Materials and methods. The study of this model is both analytically and numerically. It is proposed a method of construction of exact ground state wave functions and accounting of the number of ground ststes states in each spin sector. The analytical results are confirmed by numerical calculations of finite chains. Results. It is shown that the ground state manifold of the F-AF delta-chain on the critical line consists of localized magnons. Together with isolated magnons there are bound magnon complexes which give dominated contribution in ground state manifold in the thermodynamic limit. Conclusions. Spin systems with macroscopically degenerated ground state and with residual entropy demonstrate significant magnetocaloric effect. Taking into account great progress in a synthesis of frustrated magnets, it can be expected that real compounds of the FAF delta-chain type with parameters close to critical ones will be obtained and these compounds will be used for the construction of effective magnetocooling devices.