We perform a comprehensive analysis of the spectral statistics of the molecular resonances in (166)Er and (168)Er observed in recent ultracold collision experiments [Frisch et al., Nature (London) 507, 475 (2014)] with the aim of determining the chaoticity of this system. We calculate different independent statistical properties to check their degree of agreement with random matrix theory (RMT), and analyze if they are consistent with the possibility of having missing resonances. The analysis of the short-range fluctuations as a function of the magnetic field points to a steady increase of chaoticity until B∼30 G. The repulsion parameter decreases for higher magnetic fields, an effect that can be interpreted as due to missing resonances. The analysis of long-range fluctuations allows us to be more quantitative and estimate a 20%-25% fraction of missing levels. Finally, a study of the distribution of resonance widths provides additional evidence supporting missing resonances of small width compared with the experimental magnetic field resolution. We conclude that further measurements with increased resolution will be necessary to give a final answer to the problem of missing resonances and the agreement with RMT.
We perform a comprehensive analysis of the spectral statistics of the molecular resonances in (166)Er and (168)Er observed in recent ultracold collision experiments [Frisch et al., Nature (London) 507, 475 (2014)] with the aim of determining the chaoticity of this system. We calculate different independent statistical properties to check their degree of agreement with random matrix theory (RMT), and analyze if they are consistent with the possibility of having missing resonances. The analysis of the short-range fluctuations as a function of the magnetic field points to a steady increase of chaoticity until B∼30 G. The repulsion parameter decreases for higher magnetic fields, an effect that can be interpreted as due to missing resonances. The analysis of long-range fluctuations allows us to be more quantitative and estimate a 20%-25% fraction of missing levels. Finally, a study of the distribution of resonance widths provides additional evidence supporting missing resonances of small width compared with the experimental magnetic field resolution. We conclude that further measurements with increased resolution will be necessary to give a final answer to the problem of missing resonances and the agreement with RMT.
We show that for ultracold magnetic lanthanide atoms chaotic scattering emerges due to a combination of anisotropic interaction potentials and Zeeman coupling under an external magnetic field. This scattering is studied in a collaborative experimental and theoretical effort for both dysprosium and erbium. We present extensive atom-loss measurements of their dense magnetic Feshbach-resonance spectra, analyze their statistical properties, and compare to predictions from a random-matrix-theory-inspired model. Furthermore, theoretical coupled-channels simulations of the anisotropic molecular Hamiltonian at zero magnetic field show that weakly bound, near threshold diatomic levels form overlapping, uncoupled chaotic series that when combined are randomly distributed. The Zeeman interaction shifts and couples these levels, leading to a Feshbach spectrum of zero-energy bound states with nearest-neighbor spacings that changes from randomly to chaotically distributed for increasing magnetic field. Finally, we show that the extreme temperature sensitivity of a small, but sizable fraction of the resonances in the Dy and Er atom-loss spectra is due to resonant nonzero partial-wave collisions. Our threshold analysis for these resonances indicates a large collision-energy dependence of the three-body recombination rate.
Abstract : We explored Feshbach resonances in the collision between ultracold highly-magnetic dysprosium and erbium atoms. The resonance density is orders of magnitude larger than seen in any other previously studied atomic system. Moreover, we showed that these resonance can only exist because of the anisotropic nature of the atom-atom potentials. Analysis of nearest-neighbor spacings between Feshbach resonances shows a chaotic distribution that one would expect from random-matrix theory. We explained these statistics as originating from the large strength of the anisotropy. We demonstrated that the vibrational motion of BaCl+ molecules is quenched by collisions with ultracold calcium atoms at a rate comparable to the Langevin rate. This is over four orders of magnitude more efficient than traditional sympathetic cooling schemes. In addition, we calculated the electronic structure of BaCl+ and other molecular ions. Based on these results we found unusually-large rates for cold charge-transfer reactions between neutral and ionic atoms.
Abstract We investigate ultracold magnetic-field-assisted collisions in the so far unexplored ErYb system. The nonsphericity of the Er atom leads to weakly anisotropic interactions that provide the mechanism for Feshbach resonances to emerge. The resonances are moderately sparsely distributed with a density of 0.1–0.3 G−1 and exhibit chaotic statistics characterized by a Brody parameter η ≈ 0.5–0.7. The chaotic behaviour of Feshbach resonances is accompanied by strong mixing of magnetic and rotational quantum numbers in near-threshold bound states. We predict the existence of broad resonances at fields < 300 G that may be useful for the precise control of scattering properties and magnetoassociation of ErYb molecules. The high number of bosonic Er–Yb isotopic combinations gives many opportunities for mass scaling of interactions. Uniquely, two isotopic combinations have nearly identical reduced masses (differing by less than 10−5 relative) that we expect to have strikingly similar Feshbach resonance spectra, which would make it possible to experimentally measure their sensitivity to hypothetical variations of proton-to-electron mass ratio.
A key goal of quantum chaos is to establish a relationship between widely observed universal spectral fluctuations of clean quantum systems and random matrix theory (RMT).Most prominent features of such RMT behavior with respect to a random spectrum, both encompassed in spectral pair correlation function, are statistical suppression of small level spacings (correlation hole) and enhanced stiffness of the spectrum at large spectral ranges.For single particle systems with fully chaotic classical counterparts, the problem has been partly solved by Berry [Proc.R. Soc.London, A400, 229 (1985)] within the so-called diagonal approximation of semiclassical periodic-orbit sums, while the derivation of the full RMT spectral form factor K(t) (Fourier transform of spectral pair correlation function), from semiclassics has been completed by Müller et al. [Phys.Rev. Lett.93, 014103 (2004)].In recent years, the questions of long-time dynamics at high energies, for which the full many-body energy spectrum becomes relevant, are coming at the forefront even for simple many-body quantum systems, such as locally interacting spin chains.Such systems display two universal types of behaviour which are termed as the 'many-body localized phase' and 'ergodic phase'.In the ergodic phase, the spectral fluctuations are excellently described by RMT, even for very simple interactions and in the absence of any external source of disorder.Here we provide a clear theoretical explanation for these observations.We compute K(t) in the leading two orders in t and show its agreement with RMT for non-integrable, time-reversal invariant many-body systems without classical counterparts, a generic example of which are Ising spin 1/2 models in a periodically kicking transverse field.In particular, we relate K(t) to partition functions of a class of twisted classical Ising models on a ring of size t, hence the leading order RMT behavior K(t)2t is a consequence of translation and reflection symmetry of the Ising partition function.
A key goal of quantum chaos is to establish a relationship between widely observed universal spectral fluctuations of clean quantum systems and random matrix theory (RMT). Most prominent features of such RMT behavior with respect to a random spectrum, both encompassed in the spectral pair correlation function, are statistical suppression of small level spacings (correlation hole) and enhanced stiffness of the spectrum at large spectral ranges. For single-particle systems with fully chaotic classical counterparts, the problem has been partly solved by Berry [Proc. R. Soc. A 400, 229 (1985)] within the so-called diagonal approximation of semiclassical periodic-orbit sums, while the derivation of the full RMT spectral form factor K(t) (Fourier transform of the spectral pair correlation function) from semiclassics has been completed by Müller et al. [Phys. Rev. Lett. 93, 014103 (2004)]. In recent years, the questions of long-time dynamics at high energies, for which the full many-body energy spectrum becomes relevant, are coming to the forefront even for simple many-body quantum systems, such as locally interacting spin chains. Such systems display two universal types of behaviour which are termed the "many-body localized phase" and "ergodic phase." In the ergodic phase, the spectral fluctuations are excellently described by RMT, even for very simple interactions and in the absence of any external source of disorder. Here we provide a clear theoretical explanation for these observations. We compute K(t) in the leading two orders in t and show its agreement with RMT for nonintegrable, time-reversal invariant many-body systems without classical counterparts, a generic example of which are Ising spin-1/2 models in a periodically kicking transverse field. In particular, we relate K(t) to partition functions of a class of twisted classical Ising models on a ring of size t; hence, the leading-order RMT behavior K(t)≃2t is a consequence of translation and reflection symmetry of the Ising partition function.Received 5 February 2018Revised 12 April 2018DOI:https://doi.org/10.1103/PhysRevX.8.021062Published by the American Physical Society under the terms of the Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI.Published by the American Physical SocietyPhysics Subject Headings (PhySH)Research AreasQuantum chaosQuantum statistical mechanicsStatistical PhysicsNonlinear DynamicsCondensed Matter, Materials & Applied Physics
We calculate near-threshold bound states and Feshbach resonance positions for atom--rigid-rotor models of the highly anisotropic systems Li+CaH and Li+CaF. We perform statistical analysis on the resonance positions to compare with the predictions of random matrix theory. For Li+CaH with total angular momentum J=0 we find fully chaotic behavior in both the nearest-neighbor spacing distribution and the level number variance. However, for J>0 we find different behavior due to the presence of a nearly conserved quantum number. Li+CaF (J=0) also shows apparently reduced levels of chaotic behavior despite its stronger effective coupling. This may indicate the development of another good quantum number relating to a bending motion of the complex. However, continuously varying the rotational constant over a wide range shows unexpected structure in the degree of chaotic behavior, including a dramatic reduction around the rotational constant of CaF. This demonstrates the complexity of the relationship between coupling and chaotic behavior.