In recent years, ultracold atoms in optical lattices have proven their great value as quantum simulators for studying strongly correlated phases and complex phenomena in solid-state systems.Here, we reveal their potential as quantum simulators for molecular physics and propose a technique to image the threedimensional molecular orbitals with high resolution.The outstanding tunability of ultracold atoms in terms of potential and interaction offer fully adjustable model systems for gaining deep insight into the electronic structure of molecules.We study the orbitals of an artificial benzene molecule and discuss the effect of tunable interactions in its conjugated π electron system with special regard to localization and spin order.The dynamical time scales of ultracold atom simulators are on the order of milliseconds, which allows for the time-resolved monitoring of a broad range of dynamical processes.As an example, we compute the hole dynamics in the conjugated π system of the artificial benzene molecule.
In recent years, ultracold atoms in optical lattices have proven their great value as quantum simulators for studying strongly correlated phases and complex phenomena in solid-state systems.Here, we reveal their potential as quantum simulators for molecular physics and propose a technique to image the threedimensional molecular orbitals with high resolution.The outstanding tunability of ultracold atoms in terms of potential and interaction offer fully adjustable model systems for gaining deep insight into the electronic structure of molecules.We study the orbitals of an artificial benzene molecule and discuss the effect of tunable interactions in its conjugated π electron system with special regard to localization and spin order.The dynamical time scales of ultracold atom simulators are on the order of milliseconds, which allows for the time-resolved monitoring of a broad range of dynamical processes.As an example, we compute the hole dynamics in the conjugated π system of the artificial benzene molecule.
One of the most active areas in atomic, molecular and optical physics is the use of ultracold atomic gases in optical lattices to simulate the behaviour of electrons in condensed matter systems. The larger mass, longer length scale, and tuneable interactions in these systems allow the dynamics of atoms moving in these systems to be followed in real time, and resonant light scattering by the atoms allows this motion to be probed on a microscopic scale using site-resolved imaging. This book reviews the physics of Hubbard-type models for both bosons and fermions in an optical lattice, which give rise to a rich variety of insulating and conducting phases depending on the lattice properties and interparticle interactions. It also discusses the effect of disorder on the transport of atoms in these models, and the recently discovered phenomenon of many-body localization. It presents several examples of experiments using both density and momentum imaging and quantum gas microscopy to study the motion of atoms in optical lattices. These illustrate the power and flexibility of ultracold-lattice analogues for exploring exotic states of matter at an unprecedented level of precision.
One of the most active areas in atomic, molecular and optical physics is the use of ultracold atomic gases in optical lattices to simulate the behaviour of electrons in condensed matter systems. The larger mass, longer length scale, and tuneable interactions in these systems allow the dynamics of atoms moving in these systems to be followed in real time, and resonant light scattering by the atoms allows this motion to be probed on a microscopic scale using site-resolved imaging. This book reviews the physics of Hubbard-type models for both bosons and fermions in an optical lattice, which give rise to a rich variety of insulating and conducting phases depending on the lattice properties and interparticle interactions. It also discusses the effect of disorder on the transport of atoms in these models, and the recently discovered phenomenon of many-body localization. It presents several examples of experiments using both density and momentum imaging and quantum gas microscopy to study the motion of atoms in optical lattices. These illustrate the power and flexibility of ultracold-lattice analogues for exploring exotic states of matter at an unprecedented level of precision.
Optical lattices make it possible to trap and coherently control large ensembles of ultracold atoms. They provide the possibility to create lattice potentials that mimic the structure of solid-state systems, and to control these potentials dynamically. In this thesis, we study how dynamical manipulations of the lattice geometry can be used to perform different tasks, ranging from quantum information processing to the creation of diatomic molecules. We first examine the dynamical properties of ultracold atoms trapped in a lattice whose periodicity is dynamically doubled. We derive a model describing the dynamics of the atoms during this process, and compute the different interaction parameters of this model. We investigate different ways of using this lattice manipulation to optimise the initialisation time of a Mott-insulating state with one atom per site, and provide a scaling law related to the interaction parameters of the system. We go on to show that entangling operations between the spin of adjacent atoms are realisable with optical lattices forming arrays of double-well potentials. We study the creation of a lattice containing a spin-encoded Bell-pair in each double-well, and show that resilient, highly-entangled many-body states are realisable using lattice manipulations. We show that the creation of cluster-like states encoded on Bell-pairs can be achieved using these systems, and we provide measurement networks that allow the execution of quantum algorithms while maintaining intact the resilience of the system. Finally, we investigate the possibility to create a diatomic molecular state and simulate Fermi systems via the excitation to Rydberg levels of ground-state atoms trapped in optical lattices. We develop a method based on symbolical manipulations to compute the interaction parameters between highly-excited electrons, and evaluate them for different electronic configurations. We use these parameters to investigate the existence of diatomic molecular states with equilibrium distances comparable to typical lattice spacings. Considering the possibility to excite atoms trapped in an optical lattice to Rydberg levels such that the electronic cloud of neighbouring atoms overlap, we propose a model describing their interactions and compute its parameters. If such systems were realised, they would allow the simulation of Fermi systems at a temperature much below the Fermi temperature, thus enabling the observation of quantum phenomena hitherto inaccessible with current technology.
Ultracold atoms in optical lattices provide an extremely clean and controllable setting to explore quantum many-body phases of matter. Here we give a brief review of the strong-correlation physics that has been realized using such ultracold atoms in optical lattices ranging from the realization of Hubbard models to studies of quantum magnetism and the detection of single atoms with lattice site resolution. All this has opened up fundamentally new opportunities for the investigation of quantum many-body systems. Introduction Over the past years, ultracold atoms in optical lattices have emerged as versatile new systems to explore the physics of quantum many-body systems. On the one hand, they can be helpful in gaining a better understanding of known phases of matter and their dynamical behavior; on the other hand, they allow one to realize completely novel quantum systems that have not been studied before in nature [1, 2, 3]. Commonly, the approach of exploring quantum many-body systems in such a way is referred to as “quantum simulations.” Examples of some of the first strongly interacting many-body phases that have been realized both in lattices and in the continuum include the quantum phase transition from a superfluid to a Mott insulator [4, 5, 6], fermionic Mott insulators [7, 8], the achievement of a Tonks- Girardeau gas [9, 10], and the realization of the Bose-Einsten condensate (BEC)– Bardeen-Cooper-Schrieffer (BCS) crossover (see also Chapter 12) in Fermi gas mixture [11] using Feshbach resonances [12]. In almost all of these experiments, detection was limited to time-of-flight imaging or more refined derived techniques that mainly characterized the momentum distribution of the quantum gas [2]. For several years, researchers in the field have therefore aspired to employ in situ single-particle detection methods for the analysis of ultracold quantum gases. Only recently has it become possible to implement such imaging techniques, marking a milestone for the characterization and manipulation of ultracold quantum gases [13, 14, 15, 16, 17]. In our discussion, we will focus on one of the most successful of these techniques based on high-resolution fluorescence imaging. Despite being a rather new technique, such quantum gas microscopy has already proven to be an enabling technology for probing and manipulating quantum many-body systems. For the first time, controllable and strongly interacting many-body systems, as realized with ultracold atoms, could be observed on a local scale [17, 16].
Here, we propose a platform based on ultracold fermionic molecules trapped in optical lattices to simulate nonadiabatic effects, as they appear in certain molecular dynamical problems. The idea consists of a judicious choice of two rotational states as the simulated electronic or nuclear degrees of freedom, in which their dipolar interactions induce the required attractive or repulsive interactions between them. We benchmark our proposal by studying the scattering of an electron or a proton against a hydrogen atom, showing the effect of electronic exchange and inelastic ionization as the mass ratio between the simulated nuclei and electrons-a tunable experimental parameter in our simulator-becomes comparable. These benchmarks illustrate how the simulator can qualitatively emulate phenomena like those appearing in molecular dynamical problems even if the simulated interaction occurs in two dimensions with a dipolar scaling. Beyond the molecular implementation proposed here, our proposal can be readily extrapolated to other atomic platforms, e.g., based on fermionic Rydberg atoms.
Many outstanding problems in quantum physics, such as high-Tc superconductivity or quark confinement, are still - after decades of research - awaiting commonly accepted explanations. One reason is that such systems are often difficult to control, show an intermingling of several effects, or are not easily accessible to measurement. To arrive at a deeper understanding of the physics at work, researchers typically derive simplified models designed to capture the most striking phenomena of the system under consideration. However, due to the exponential complexity of Hilbert space, even some of the simplest of such models pose formidable challenges to analytical and numerical calculations. In 1982, Feynman proposed to solve such quantum models with experimental simulation on a physically distinct, specifically engineered quantum system [Int. J. Theor.Phys. 21, 467]. Designed to be governed by the same underlying equations as the original model, it is hoped that direct measurements on these so called quantum simulators (QSs) will allow to gather deep insights into outstanding problems of physics and beyond. In this thesis, we identify four requirements that a useful QS has to fulfill, relevance, control, reliability, and efficiency. Focusing on these, we review the state of the art of two popular approaches, digital QSs (i.e., special purpose quantum computers) and analog QSs (devices with always-on interactions). Further, focusing on possibilities to increase control over QSs, we discuss a scheme to engineer quantum correlations between mesoscopic numbers of spinful particles in optical lattices. This technique, based on quantum polarization spectroscopy, may be useful for state preparation and quantum information protocols. Additionally, employing several analytical and numerical methods for the calculation of many-body ground states, we demonstrate the variety of condensed-matter problems that can be attacked with QSs consisting of ultracold ions or neutral atoms in optical lattices. The chosen examples, some of which have already been realized in experiment, include such diverse settings as frustrated antiferromagnetism, quantum phase transitions in exotic lattice geometries, topological insulators, non-Abelian gauge-fields, orbital order of ultracold Fermions, and systems with long-range interactions. The experimental realization of all of these models requires techniques which go beyond standard optical lattices, e.g., time-periodic driving of lattices with exotic geometry, loading ultracold atoms into higher bands, or immersing trapped ions into an optical lattice. The chosen models, motivated by important open questions of quantum physics, pose difficult problems for classical computers, but they may be amenable in the near future to quantum simulation with ultracold atoms or ions. While the experimental control over relevant models has increased dramatically in the last years, the reliability and efficiency of QSs has received considerably less attention. As a second important part of this thesis, we emphasize the need to consider these aspects under realistic experimental conditions. We discuss specific situations where terms that have typically been neglected in the description of the QS introduce systematic errors and even lead to novel physics. Further, we characterize in a generic example the influence of quenched disorder on an analog QS. Its performance for simulating universal behavior near a quantum phase transition seems satisfactory for low disorder. Moreover, our results suggest a connection between the reliability and efficiency of a QS: it works less reliable exactly in those interesting regimes where classical calculations are less efficient. If QSs fulfill all of our four requirements, they may revolutionize our approach to quantum-mechanical problems, allowing to solve the behavior of complex Hamiltonians, and to design nano-scale materials and chemical compounds from the ground up.