Bipartite Lieb-Mattis ferrimagnetism and the symmetry-protected Haldane phase are paradigmatic mechanisms in quasi-one-dimensional quantum magnets. Both emerge, in distinct regimes, in a mixed-spin
1-
21-
21 Heisenberg trimer chain with antiferromagnetic backbone exchange
J and a side spin-
21 coupled to each backbone spin by an exchange
Jt of either sign. Using the density matrix renormalization group, we compute magnetization curves and the entanglement spectrum and entropy. For
Jt>0 a robust ferrimagnetic plateau forms at magnetization per unit cell
m=1, whose multiplet entropy reflects how the conserved magnetization splits between the halves. For
Jt<0 an
m=0 plateau opens and grows with
∣Jt∣, while the
m=1 plateau closes. As
Jt→−∞ the chain maps onto a spin-
1 Heisenberg chain with coupling
J/2: the
m=0 width
Δh≃0.196 matches half the Haldane gap. Exponentially localized spin-
21 edge states and the even-fold degeneracy of the entanglement spectrum confirm the Haldane character of the
m=0 phase.
Bipartite Lieb-Mattis ferrimagnetism and the symmetry-protected Haldane phase are paradigmatic mechanisms in quasi-one-dimensional quantum magnets. Both emerge, in distinct regimes, in a mixed-spin
1-
21-
21 Heisenberg trimer chain with antiferromagnetic backbone exchange
J and a side spin-
21 coupled to each backbone spin by an exchange
Jt of either sign. Using the density matrix renormalization group, we compute magnetization curves and the entanglement spectrum and entropy. For
Jt>0 a robust ferrimagnetic plateau forms at magnetization per unit cell
m=1, whose multiplet entropy reflects how the conserved magnetization splits between the halves. For
Jt<0 an
m=0 plateau opens and grows with
∣Jt∣, while the
m=1 plateau closes. As
Jt→−∞ the chain maps onto a spin-
1 Heisenberg chain with coupling
J/2: the
m=0 width
Δh≃0.196 matches half the Haldane gap. Exponentially localized spin-
21 edge states and the even-fold degeneracy of the entanglement spectrum confirm the Haldane character of the
m=0 phase.
We consider a class of geometrically frustrated Heisenberg spin systems which admit exact ground states. The systems consist of suitably coupled antiferromagnetic spin trimers with integer spin quantum numbers s and their ground state Φ will be the product state of the local singlet ground states of the trimers. We provide linear equations for the inter-trimer coupling constants which are equivalent to Φ being an eigenstate of the corresponding Heisenberg Hamiltonian and sufficient conditions for Φ being a ground state. The classical case s → ∞ can be completely analyzed. For the quantum case we consider a couple of examples, where the critical values of the inter-trimer couplings are numerically determined. These examples include chains of corner sharing tetrahedra as well as certain spin tubes. Φ is proven to be gapped in the case of trimer chains. This follows from a more general theorem on quantum chains with product ground states.