Thermodynamic entropy, as defined by Clausius, characterizes macroscopic observations of a system based on phenomenological quantities such as temperature and heat. In contrast, information-theoretic entropy, introduced by Shannon, is a measure of uncertainty. In this Letter, we connect these two notions of entropy, using an axiomatic framework for thermodynamics [E. H. Lieb and J. Yngvason Proc. R. Soc. 469, 20130408 (2013)]. In particular, we obtain a direct relation between the Clausius entropy and the Shannon entropy, or its generalization to quantum systems, the von Neumann entropy. More generally, we find that entropy measures relevant in nonequilibrium thermodynamics correspond to entropies used in one-shot information theory.
Thermodynamic entropy, as defined by Clausius, characterizes macroscopic observations of a system based on phenomenological quantities such as temperature and heat. In contrast, information-theoretic entropy, introduced by Shannon, is a measure of uncertainty. In this Letter, we connect these two notions of entropy, using an axiomatic framework for thermodynamics [E. H. Lieb and J. Yngvason Proc. R. Soc. 469, 20130408 (2013)]. In particular, we obtain a direct relation between the Clausius entropy and the Shannon entropy, or its generalization to quantum systems, the von Neumann entropy. More generally, we find that entropy measures relevant in nonequilibrium thermodynamics correspond to entropies used in one-shot information theory.
We investigate the concept of entropy in probabilistic theories more general than quantum mechanics, with particular reference to the notion of information causality (IC) recently proposed by Pawlowski et al (2009 arXiv:0905.2292). We consider two entropic quantities, which we term measurement and mixing entropy. In the context of classical and quantum theory, these coincide, being given by the Shannon and von Neumann entropies, respectively; in general, however, they are very different. In particular, while measurement entropy is easily seen to be concave, mixing entropy need not be. In fact, as we show, mixing entropy is not concave whenever the state space is a non-simplicial polytope. Thus, the condition that measurement and mixing entropies coincide is a strong constraint on possible theories. We call theories with this property monoentropic . Measurement entropy is subadditive, but not in general strongly subadditive. Equivalently, if we define the mutual information between two systems A and B by the usual formula I ( A : B )= H ( A )+ H ( B )- H ( AB ), where H denotes the measurement entropy and AB is a non-signaling composite of A and B , then it can happen that I ( A : BC )< I ( A : B ). This is relevant to IC in the sense of Pawlowski et al : we show that any monoentropic non-signaling theory in which measurement entropy is strongly subadditive, and also satisfies a version of the Holevo bound, is informationally causal, and on the other hand we observe that Popescu–Rohrlich boxes, which violate IC, also violate strong subadditivity. We also explore the interplay between measurement and mixing entropy and various natural conditions on theories that arise in quantum axiomatics.
The concept of entropy rst arose in the study of thermodynamics and statistical me- chanics. In information theory the so-called Shannon entropy plays a signi cant role, which measures how much information we gain, on average, when we learn the value of a random variable. An alternative interpretation is that the entropy of the random variable quanti es the amount of uncertainty about the random variable before we learn its value. The concept was introduced by Claude E. Shannon in his 1948 paper "A Mathematical Theory of Communication". In the rst part of the present work we consider this fundamental measure of information and show some of its properties, such as non-negativity. The relative entropy or the Kullback-Leibler divergence is a very useful measure of the distance between two prob- ability distributions. After introducing its de nition and other notions (joint entropy, conditional entropy or mutual information) we can prove additional assertions about the Shannon entropy and present statements about the relations between the above men- tioned quantities. In quantum information theory, there is a quantity, namely von Neumann entropy, which corresponds to Shannon entropy and originates from it. In the section Von Neu- mann entropy we will introduce this quantity which is a continuous functional on the states, or on their mathematical representatives, the density operators, and it ful ls in- equalities such as subadditivity and strong subaddititvity. Just as with the Shannon entropy, it is extremely useful to de ne a quantum version of the relative entropy, which is one of the most important numerical quantities appearing in quantum information theory. It is used as a measure of distinguishability between quantum states. Among others its properties are jointly convexity, monotonicity which are speci cally convenient. Transformations on structures which preserve operations, quantities or relations among elements appear in many areas of mathematics. These are the so-called preservers which show up also in physics and even in chemistry where they are usually called symmetries. Therefore, the study of preserver transformations is an important area of research. The third section of this work is based on a paper, in which Lajos Molnár described the structure every bijective map on the space of all density operators on a given Hilbert space, which preserves the relative entropy. This result is closely related to Wigner's famous theorem on the form of quantum mechanical symmetry transformations. The above theorem of Molnár can be extended into two directions. On the one hand, the result holds also in the case when the transformation under consideration acts on the space of all positive semide nite operators not only on density operators (i.e., we omit the condition of unit trace). On the other hand the statement remains valid even if we omit the strongly restrictive condition that the transformation is bijective. The second result is a joint work with Prof. Lajos Molnár which appeared in the journal Linear Algebra and Its Applications.
Quantum information-theoretic approach had been identified as a way to understand the foundations of quantum mechanics as early as 1950 due to Shannon. However, there hasn’t been enough advancement or rigorous development of the subject. In the following paper we try to find the relationship between a general quantum mechanical observable and von Neumann entropy. We find that the expectation values and the uncertainties of the observables have bounds which depend on the entropy. The results also show that von Neumann entropy is not just the uncertainty of the state but also encompasses the information about expectation values and uncertainties of any observable which depend on the observers choice for a particular measurement. Also a reverse uncertainty relation is derived for [Formula: see text] quantum mechanical observables.
We investigate fundamental connections between thermodynamics and quantum information theory. First, we show that the operational framework of thermal operations is nonequivalent to the framework of Gibbs-preserving maps, and we comment on this gap. We then introduce a fully information-theoretic framework generalizing the above by making further abstraction of physical quantities such as energy. It is technically convenient to work with and reproduces known results for finite-size quantum thermodynamics. With our framework we may determine the minimal work cost of implementing any logical process. In the case of information processing on memory registers with a degenerate Hamiltonian, the answer is given by the max-entropy, a measure of information known from quantum information theory. In the general case, we obtain a new information measure, the "coherent relative entropy", which generalizes both the conditional entropy and the relative entropy. It satisfies a collection of properties which justifies its interpretation as an entropy measure and which connects it to known quantities. We then present how, from our framework, macroscopic thermodynamics emerges by typicality, after singling out an appropriate class of thermodynamic states possessing some suitable reversibility property. A natural thermodynamic potential emerges, dictating possible state transformations, and whose differential describes the physics of the system. The textbook thermodynamics of a gas is recovered as well as the form of the second law relating thermodynamic entropy and heat exchange. Finally, noting that quantum states are relative to the observer, we see that the procedure above gives rise to a natural form of coarse-graining in quantum mechanics: Each observer can consistently apply the formalism of quantum information according to their own fundamental unit of information.
We derive the quantum Fisher information for entropy estimation in a Gibbs state and show that it equals the inverse of the heat capacity, which is dual to the temperature Fisher information given by the heat capacity divided by the square of the temperature. Their product is independent of the Hamiltonian and depends only on the temperature, leading to a metrological uncertainty relation between the variances of entropy and temperature estimators in which all system-specific quantities cancel. This relation arises from the dually-flat structure of the Gibbs exponential family expressed in thermodynamic coordinates, and holds for all standard thermodynamically conjugate pairs. We identify energy measurement as the optimal protocol for entropy estimation, analyse critical-point scaling where the entropy Fisher information vanishes, and connect it to the Ruppeiner metric in entropy coordinates. We lastly examine the distinguished role of the von Neumann entropy within the Rényi family. Generalisations to the grand canonical and generalised Gibbs ensembles are given.
The similarity between quantum mechanics and thermodynamics is discussed. It is found that if the Clausius equality is imposed on the Shannon entropy and the analog of the quantity of heat, then the value of the Shannon entropy comes to formally coincide with that of the von Neumann entropy of the canonical density matrix, and pure-state quantum mechanics apparently transmutes into quantum thermodynamics. The corresponding quantum Carnot cycle of a simple two-state model of a particle confined in a one-dimensional infinite potential well is studied, and its efficiency is shown to be identical to the classical one.