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arXiv:1412.6991 · New Journal of Physics

Functional integral approach to time-dependent heat exchange in open quantum systems: general method and applications

Matteo Carrega, Paolo Solinas, Alessandro Braggio, Maura Sassetti, U Weiss

Published Apr 29, 2015• 62 citations
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Abstract

We establish the path integral approach for the time-dependent heat exchange of an externally driven quantum system coupled to a thermal reservoir. We derive the relevant influence functional and present an exact formal expression for the moment generating functional which carries all statistical properties of the heat exchange process for general linear dissipation. The method is applied to the time-dependent average heat transfer in the dissipative two-state system (TSS). We show that the heat can be written as a convolution integral which involves the population and coherence correlation functions of the TSS and additional correlations due to a polarization of the reservoir. The corresponding expression can be solved in the weak-damping limit both for white noise and for quantum mechanical coloured noise. The implications of pure quantum effects are discussed. Altogether a complete description of the dynamics of the average heat transfer ranging from the classical regime down to zero temperature is achieved.

DOI
10.1088/1367-2630/17/4/045030

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We establish the path integral approach for the time-dependent heat exchange of an externally driven quantum system coupled to a thermal reservoir. We derive the relevant influence functional and present an exact formal expression for the moment generating functional which carries all statistical properties of the heat exchange process for general linear dissipation. The method is applied to the time-dependent average heat transfer in the dissipative two-state system (TSS). We show that the heat can be written as a convolution integral which involves the population and coherence correlation functions of the TSS and additional correlations due to a polarization of the reservoir. The corresponding expression can be solved in the weak-damping limit both for white noise and for quantum mechanical coloured noise. The implications of pure quantum effects are discussed. Altogether a complete description of the dynamics of the average heat transfer ranging from the classical regime down to zero temperature is achieved.
The time-dependent energy transfer in a driven quantum system strongly coupled to a heat bath is studied within an influence functional approach. Exact formal expressions for the statistics of energy dissipation into the different channels are derived. The general method is applied to the driven dissipative two-state system. It is shown that the energy flows obey a balance relation, and that, for strong coupling, the interaction may constitute the major dissipative channel. Results in analytic form are presented for the particular value K=1/2 of strong Ohmic dissipation. The energy flows show interesting behaviors including driving-induced coherences and quantum stochastic resonances. It is found that the general characteristics persists for K near 1/2.
We analyze the heat exchange distribution of open quantum systems undergoing a thermal relaxation process with a time-dependent effective temperature. We show that such processes arise, for example, if the dynamics maximizes the entropy production. Using a two-point measurement scheme, we find an expression for the heat moment generating function that depends solely on the system's partition function and on the thermalization function (i.e., the law of cooling) describing the effective temperature. Applications include the relaxation of free bosonic and fermionic modes, for which closed-form expressions for the time-dependent heat distribution function are derived. Multiple free modes with arbitrary dispersion relations are also briefly discussed. In the semiclassical limit our formula agrees with previous results of the literature for the heat distribution of an optically trapped nanoscopic particle far from equilibrium.
Heat exchanged between an open quantum system and its environment exhibits fluctuations that carry crucial signatures of the underlying dynamics. Within the well-established two-point measurement scheme, we identify a “heat operator,” whose moments with respect to the vacuum state of a thermofield-doubled Hilbert space correspond to the stochastic moments of the heat exchanged with a bath. This recasts heat statistics as a unitary time evolution problem, which we solve by combining chain-mapped reservoirs with tensor-network propagation. In a multibath setup, all total and bath-resolved heat moments then follow from a single pure state evolution. We employ this approach to compute transient and steady-state heat fluctuations in Ohmic spin-boson models in and out of equilibrium, accessing the challenging low-temperature and long memory time regimes of the environment. In the nonequilibrium case, we show a crossover in the Fano factor from super-Poissonian to nearly Poissonian statistics under strong coupling asymmetry, corresponding to thermal rectification behavior. The method applies to noninteracting (bosonic or fermionic) nonequilibrium environments with arbitrary spectral densities, offering a powerful, nonperturbative framework for understanding heat transfer in open quantum systems.
As the dimensions of physical systems approach the nanoscale, the laws of thermodynamics must be reconsidered due to the increased importance of fluctuations and quantum effects. While the statistical mechanics of small classical systems is relatively well understood, the quantum case still poses challenges. Here, we set up a formalism that allows us to calculate the full probability distribution of energy exchanges between a periodically driven quantum system and a thermalized heat reservoir. The formalism combines Floquet theory with a generalized master equation approach. For a driven two-level system and in the long-time limit, we obtain a universal expression for the distribution, providing clear physical insight into the exchanged energy quanta. We illustrate our approach in two analytically solvable cases and discuss the differences in the corresponding distributions. Our predictions could be directly tested in a variety of systems, including optical cavities and solid-state devices.
We present a numerically exact method to compute the full counting statistics of heat transfer in non-Markovian open quantum systems, which is based on the time-evolving matrix product operator algorithm.This approach is applied to the paradigmatic spin-boson model in order to calculate the mean and fluctuations of the heat transferred to the environment during thermal equilibration.We show that system-reservoir correlations make a significant contribution to the heat statistics at low temperature and present a variational theory that quantitatively explains our numerical results.We also demonstrate a fluctuation-dissipation relation connecting the mean and variance of the heat distribution at high temperature.Our results reveal that system-bath interactions make a significant contribution to heat transfer even when the dynamics of the open system is effectively Markovian.The method presented here provides a flexible and general tool to predict the fluctuations of heat transfer in open quantum systems in nonperturbative regimes.
The modelling of quantum heat transfer processes at the nanoscale is crucial for the development of energy harvesting and molecular electronic devices. Herein, we adopt a mixed quantum-classical description of a device, in which the open subsystem of interest is treated quantum mechanically and the surrounding heat baths are treated in a classical-like fashion. By introducing such a mixed quantum-classical description of the composite system, one is able to study the heat transfer between the subsystem and bath from a closed system point of view, thereby avoiding simplifying assumptions related to the bath time scale and subsystem-bath coupling strength. In particular, we adopt the full counting statistics approach to derive a general expression for the moment generating function of heat in systems whose dynamics are described by the quantum-classical Liouville equation (QCLE). From this expression, one can deduce expressions for the dynamics of the average heat and heat current, which may be evaluated using numerical simulations. Due to the approximate nature of the QCLE, we also find that the steady state fluctuation symmetry holds up to order ℏ for systems whose subsystem-bath couplings and baths go beyond bilinear and harmonic, respectively. To demonstrate the approach, we consider the nonequilibrium spin boson model and simulate its time-dependent average heat and heat current under various conditions.