Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:1411.4805 · Physical Review E

Fluctuations of work in nearly adiabatically driven open quantum systems

Samu Suomela, Juha Salmilehto, Ivan G. Savenko, Tapio Ala-Nissilä, Mikko Möttönen

Published Feb 19, 2015• 21 citations
arXivHTMLPDF

Abstract

We extend the quantum jump method to nearly adiabatically driven open quantum systems in a way that allows for an accurate account of the external driving in the system-environment interaction. Using this framework, we construct the corresponding trajectory-dependent work performed on the system and derive the integral fluctuation theorem and the Jarzynski equality for nearly adiabatic driving. We show that such identities hold as long as the stochastic dynamics and work variable are consistently defined. We numerically study the emerging work statistics for a two-level quantum system and find that the conventional diabatic approximation is unable to capture some prominent features arising from driving, such as the continuity of the probability density of work. Our results reveal the necessity of using accurate expressions for the drive-dressed heat exchange in future experiments probing jump time distributions.

DOI
10.1103/physreve.91.022126

Related papers

Work statistics in open quantum systems

Samu Suomela

Rapid progress in the fabrication and manipulation of micro and nanoscale devices has made it necessary to extend the concepts of thermodynamics to small systems and finally to quantum systems. In such systems the extensive thermodynamic quantities, such as entropy, heat, and work, are not described by their average values alone but by distributions. \n \nRemarkably, it has been shown that the stochastic thermodynamic variables often obey fluctuation relations which usually appear in the form of relations between exponential averages. While the two-measurement protocol of thermodynamic variables, especially work, is now well studied in closed quantum systems, there have been conceptual and experimental problems in open quantum systems. \n \nIn this thesis, we theoretically study work statistics and fluctuation relations in open quantum systems. To calculate the work statistics, we use the quantum jump method and direct master equation calculations. We show that work definitions equivalent in closed systems can lead to mutually different results in the case of open quantum systems due to a different order of approximations. Moreover, we show that the fluctuation relations can be extended to nearly adiabatically driven systems by using the adiabatic renormalization procedure. \n \nLast, we focus on how a finite size of the environment affects the dynamics and work statistics of open quantum systems. This is important from the experimental point of view because a finite-size environment allows the detection of heat exchange between the system and the environment. We derive a master equation that takes into account these effects and develop a stochastic model that unravels the master equation. We explicitly show that the finite size of the environment influences the dynamics and the work statistics. We also show that the common fluctuation relations are still valid.

•Jan 1, 2017•0 citations

Fluctuation theorems for thermally isolated driven quantum systems: nonadiabaticity, excess work and strong inequalities

J. V. M. Steimetz, M. Campisi, M. V. S. Bonança

We expand on the ideas developed by C. Jarzynski in Physica A 552, 122077 (2020), where an integral fluctuation theorem was derived with the aim of obtaining thermodynamic inequalities stronger than those implied by the Jarzynski equality. Restricting ourselves to the quantum setting, we derive the corresponding detailed fluctuation theorem and additional detailed and integral fluctuation theorems; we also provide a clear physical interpretation of the stochastic quantities defined in the previous reference. Furthermore, we show that their averages are given by the nonadiabaticity parameter (i.e., the relative entropy between the final state after a finite-time driving protocol and the corresponding adiabatically evolved state) and the excess work (also known as inner friction). We elaborate on the inequalities derived from the fluctuation theorems and discuss their connection to irreversibility and formulations of the Second Law.

cond-mat.stat-mechCross-listedarXiv:2607.09615•Jul 13, 2026•0 citations

Operational Work Fluctuation Theorem for Open Quantum Systems

Konstantin Beyer, Walter T. Strunz

The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasistatic process. This fluctuation theorem bears experimental relevance, as it enables the determination of the free energy difference through the measurement of externally applied work in a nonequilibrium process. In the quantum case, the Jarzynski equality only holds if the measurement procedure of the stochastic work is drastically changed: it is replaced by a so-called two-point measurement scheme that requires the knowledge of the initial and final Hamiltonian and therefore lacks the predictive power for the free energy difference that the classical Jarzynski equation is known for. Here, we propose a quantum fluctuation theorem that is valid for externally measurable quantum work determined during the driving protocol. In contrast to the two-point measurement case, the theorem also applies to open quantum systems and the scenario can be realized without knowing the system Hamiltonian. Our fluctuation theorem comes in the form of an inequality and therefore only yields bounds to the true free energy difference. The inequality is saturated in the quasiclassical case of vanishing energy coherences at the beginning and at the end of the protocol. Thus, there is a clear quantum disadvantage.

arXiv:2408.13417•Physical Review Letters•Apr 9, 2025•2 citations

Fluctuation theorems in driven open quantum systems

Peter Talkner, Michele Campisi, Peter Hänggi

The characteristic function for the joint measurement of the changes of two or more commuting observables upon an external forcing of a quantum system is derived. In particular, the statistics of the internal energy, the exchanged heat and the work of a quantum system that weakly couples to its environment are determined in terms of the energy changes of the system and the environment due to the action of a classical, external force on the system. If the system and the environment initially are in a canonical equilibrium, the work performed on the system is shown to satisfy the Tasaki–Crooks theorem and the Jarzynski equality.

arXiv:0811.0973•Journal of Statistical Mechanics Theory and Experiment•Feb 9, 2009•121 citations

Perturbative analysis of quantum fluctuation theorems in a driven open system

Yi Peng, Heng Fan

We give a perturbative analysis of Crooks relation and Jarzynski equality in an arbitrary driven quantum system weakly coupled to a heat bath. Invoking no efficient Hamiltonian nor any restriction on the form of the coupling, we derive the first-order correction to Crooks relation and Jarzynski equality in terms of the interacting Hamiltonian. A Crooks type of relation about energy increment in the system and nonvanishing heat expenditure to the heat bath up to the second order of interaction would be given by the way. Our results tell us that deviation of the quantum fluctuation relations is mainly caused by energy trapped interaction rather than the heat flow to (or from) heat bath. We also show a way of defining work in weak coupling regime which is consistent to the work definition in closed systems and thus deepen our understanding of work in quantum realm.

arXiv:1708.08214•Aug 28, 2017•0 citations

Autonomization of Quantum Systems and the Emergence of the Work Operator

Carlo Cepollaro, Danial Chughtai, Alberto Spalvieri +2 more

Estimation of work at the quantum scale remains a central challenge in quantum thermodynamics. Canonical approaches have a fundamental drawback: they assume classical control of the quantum system, as implicit in a time-dependent Hamiltonian. Yet the energetic cost of implementing this control is omitted and can exceed the system's energy scale by orders of magnitude, calling into question the operational significance of work values. We address this by autonomizing the controlled energy transfer, embedding the driven dynamics into an energy-conserving evolution on a larger quantum system. Work is then unambiguously identified with the energy transferred between the two systems, singling out a unique observable on the driven system: the work operator. We show that the quantum work operator evades a no-go theorem by deriving a quantum fluctuation theorem that recovers the Jarzynski equality in classical scenarios. We incorporate imperfect control and quantify corrections to work statistics. Extending the framework to open quantum systems, we obtain an operatorial first law in which work, heat, and internal-energy changes are represented by distinct operators on the reduced system. Together, these results settle the long-standing debate over whether work is a quantum observable: it is, once the controlling system is included in the description rather than treated as external.

quant-pharXiv:2607.20602•Jul 24, 2026•0 citations
We extend the quantum jump method to nearly adiabatically driven open quantum systems in a way that allows for an accurate account of the external driving in the system-environment interaction. Using this framework, we construct the corresponding trajectory-dependent work performed on the system and derive the integral fluctuation theorem and the Jarzynski equality for nearly adiabatic driving. We show that such identities hold as long as the stochastic dynamics and work variable are consistently defined. We numerically study the emerging work statistics for a two-level quantum system and find that the conventional diabatic approximation is unable to capture some prominent features arising from driving, such as the continuity of the probability density of work. Our results reveal the necessity of using accurate expressions for the drive-dressed heat exchange in future experiments probing jump time distributions.
Rapid progress in the fabrication and manipulation of micro and nanoscale devices has made it necessary to extend the concepts of thermodynamics to small systems and finally to quantum systems. In such systems the extensive thermodynamic quantities, such as entropy, heat, and work, are not described by their average values alone but by distributions. \n \nRemarkably, it has been shown that the stochastic thermodynamic variables often obey fluctuation relations which usually appear in the form of relations between exponential averages. While the two-measurement protocol of thermodynamic variables, especially work, is now well studied in closed quantum systems, there have been conceptual and experimental problems in open quantum systems. \n \nIn this thesis, we theoretically study work statistics and fluctuation relations in open quantum systems. To calculate the work statistics, we use the quantum jump method and direct master equation calculations. We show that work definitions equivalent in closed systems can lead to mutually different results in the case of open quantum systems due to a different order of approximations. Moreover, we show that the fluctuation relations can be extended to nearly adiabatically driven systems by using the adiabatic renormalization procedure. \n \nLast, we focus on how a finite size of the environment affects the dynamics and work statistics of open quantum systems. This is important from the experimental point of view because a finite-size environment allows the detection of heat exchange between the system and the environment. We derive a master equation that takes into account these effects and develop a stochastic model that unravels the master equation. We explicitly show that the finite size of the environment influences the dynamics and the work statistics. We also show that the common fluctuation relations are still valid.
We expand on the ideas developed by C. Jarzynski in Physica A 552, 122077 (2020), where an integral fluctuation theorem was derived with the aim of obtaining thermodynamic inequalities stronger than those implied by the Jarzynski equality. Restricting ourselves to the quantum setting, we derive the corresponding detailed fluctuation theorem and additional detailed and integral fluctuation theorems; we also provide a clear physical interpretation of the stochastic quantities defined in the previous reference. Furthermore, we show that their averages are given by the nonadiabaticity parameter (i.e., the relative entropy between the final state after a finite-time driving protocol and the corresponding adiabatically evolved state) and the excess work (also known as inner friction). We elaborate on the inequalities derived from the fluctuation theorems and discuss their connection to irreversibility and formulations of the Second Law.
The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasistatic process. This fluctuation theorem bears experimental relevance, as it enables the determination of the free energy difference through the measurement of externally applied work in a nonequilibrium process. In the quantum case, the Jarzynski equality only holds if the measurement procedure of the stochastic work is drastically changed: it is replaced by a so-called two-point measurement scheme that requires the knowledge of the initial and final Hamiltonian and therefore lacks the predictive power for the free energy difference that the classical Jarzynski equation is known for. Here, we propose a quantum fluctuation theorem that is valid for externally measurable quantum work determined during the driving protocol. In contrast to the two-point measurement case, the theorem also applies to open quantum systems and the scenario can be realized without knowing the system Hamiltonian. Our fluctuation theorem comes in the form of an inequality and therefore only yields bounds to the true free energy difference. The inequality is saturated in the quasiclassical case of vanishing energy coherences at the beginning and at the end of the protocol. Thus, there is a clear quantum disadvantage.
The characteristic function for the joint measurement of the changes of two or more commuting observables upon an external forcing of a quantum system is derived. In particular, the statistics of the internal energy, the exchanged heat and the work of a quantum system that weakly couples to its environment are determined in terms of the energy changes of the system and the environment due to the action of a classical, external force on the system. If the system and the environment initially are in a canonical equilibrium, the work performed on the system is shown to satisfy the Tasaki–Crooks theorem and the Jarzynski equality.
We give a perturbative analysis of Crooks relation and Jarzynski equality in an arbitrary driven quantum system weakly coupled to a heat bath. Invoking no efficient Hamiltonian nor any restriction on the form of the coupling, we derive the first-order correction to Crooks relation and Jarzynski equality in terms of the interacting Hamiltonian. A Crooks type of relation about energy increment in the system and nonvanishing heat expenditure to the heat bath up to the second order of interaction would be given by the way. Our results tell us that deviation of the quantum fluctuation relations is mainly caused by energy trapped interaction rather than the heat flow to (or from) heat bath. We also show a way of defining work in weak coupling regime which is consistent to the work definition in closed systems and thus deepen our understanding of work in quantum realm.
Estimation of work at the quantum scale remains a central challenge in quantum thermodynamics. Canonical approaches have a fundamental drawback: they assume classical control of the quantum system, as implicit in a time-dependent Hamiltonian. Yet the energetic cost of implementing this control is omitted and can exceed the system's energy scale by orders of magnitude, calling into question the operational significance of work values. We address this by autonomizing the controlled energy transfer, embedding the driven dynamics into an energy-conserving evolution on a larger quantum system. Work is then unambiguously identified with the energy transferred between the two systems, singling out a unique observable on the driven system: the work operator. We show that the quantum work operator evades a no-go theorem by deriving a quantum fluctuation theorem that recovers the Jarzynski equality in classical scenarios. We incorporate imperfect control and quantify corrections to work statistics. Extending the framework to open quantum systems, we obtain an operatorial first law in which work, heat, and internal-energy changes are represented by distinct operators on the reduced system. Together, these results settle the long-standing debate over whether work is a quantum observable: it is, once the controlling system is included in the description rather than treated as external.