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arXiv:1410.5592

Generalised Virial theorems in Classical and Quantum Physics

C V Sukumar

Published Oct 21, 2014• 0 citations
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Abstract

Generalisations of the virial theorm in Classical Mechanics and Quantum Mechanics are examined. It is shown that the generalised virial theorem in Quantum Mechanics leads to certain relations between matrix elements. The differences between the generalisations in Classical and Quantum Mechanics are identified. Some results arising from the radial Schrödinger equation in Quantum Mechanics are discussed. It is also shown that the generalisations of the virial theorem may be extended to arbitrary number of dimensions.

DOI
10.48550/arxiv.1410.5592

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Generalisations of the virial theorm in Classical Mechanics and Quantum Mechanics are examined. It is shown that the generalised virial theorem in Quantum Mechanics leads to certain relations between matrix elements. The differences between the generalisations in Classical and Quantum Mechanics are identified. Some results arising from the radial Schrödinger equation in Quantum Mechanics are discussed. It is also shown that the generalisations of the virial theorem may be extended to arbitrary number of dimensions.
The virial theorem, introduced by Clausius in the field of statistical mechanics and later applied in both classical mechanics and quantum mechanics, is studied by making use of symplectic formalism as an approach, in the case of both the Hamiltonian and Lagrangian systems. The possibility of establishing virial-like theorems from one-parameter groups of non-strictly canonical transformations is analysed; the case of systems with a position-dependent mass is also discussed. Using the modern symplectic approach to quantum mechanics, we arrive at the quantum virial theorem in full analogy with the classical case.
Heretofore, the hypervirial theorems recently introduced by Hirschfelder have only been applied to bound-state systems. In this paper it is shown that, with certain modifications, these theorems can also be applied to free systems, and, in particular, to scattering problems. The new form of the general hypervirial theorem is derived, and the theory is illustrated with the problem of a particle scattered by a central field. The ordinary virial theorem is deduced, together with other results of physical interest. Both classical and quantum-mechanical formalisms are considered, and in some cases the semiclassical approximation links corresponding results.
A method, similar to the one previously used by the author in his derivation of a generalized classical virial theorem (see ibid., vol.10, no.4, p.507 (1977)), is used to derive a generalized quantum virial equation. This equation is applicable to any part of a larger system of particles. Furthermore, by the introduction of a flux density operator, it is possible to express the quantum surface flux virial in two alternative forms, as easily interpreted as the classical form. As an intermediate result, an equation of continuity for a general one-particle observable is obtained. In an appendix, an equation of motion of the reduced density matrix of the first order is derived.