Recent examples have shown that zero private capacity need not imply antidegradability and that two channels with zero private capacity can nevertheless transmit private information together. Existing entropic channel orders compare what a receiver and its environment can learn and thereby bound capacities. We connect these orders to the recent constructions through binary estimation, whose minimum mean-square error is governed by measured
χ2 divergence. A new integral representation shows how measured
χ2 on a qubit extension recovers quantum
χ2. It lets us pass from complete measured-
χ2 ordering to complete quantum-
χ2, relative-entropy, and less-noisy ordering. Zhu and Wang used a signed lift to show that their qutrit channel has zero private capacity. We show that Hermitian-smoothed measured-
χ2 ordering characterizes when such lifts exist, even with a quantum reference. Environmental dominance in binary estimation at every blocklength yields a finite-code reliability--secrecy bound. These results explain why complete comparison prevents activation with antidegradable helpers whereas regularized comparison alone does not. Building on that qutrit example, we establish this stability for a range of noisy Werner--Holevo channels, determine sharp private-capacity and antidegradability thresholds, and compute exact complementary capacities in a nondegradable range. By contrast, we extend Pauli half-erasure activation to all
1/2≤p<1 and establish the same range for a new four-level family. Reference-assisted measured-
χ2 witnesses show why these activating constructions lack complete comparison.
Two classes of quantum channels, which we call more capable and less noisy, are introduced. The more capable class consists of channels such that the quantum capacities of the complementary channels to the environments are zero. The less noisy class consists of channels such that the private capacities of the complementary channels to the environment are zero. For the more capable class, it is clarified that the private capacity and quantum capacity coincide. For the less noisy class, it is clarified that the private capacity and quantum capacity can be single letter characterized.