A quantum phase transition may occur in the ground state of a system at zero temperature when a controlling field or interaction is varied. The resulting quantum fluctuations which trigger the transition produce scaling behaviour of various observables, governed by universal critical exponents. A particularly interesting class of such transitions appear in systems with quantum impurities where a non-extensive term in the free energy becomes singular at the critical point. Curiously, the notion of a conventional order parameter that exhibits scaling at the critical point is generically missing in these systems. Here we explore the possibility to use the Schmidt gap, which is an observable obtained from the entanglement spectrum, as an order parameter. A case study of the two-impurity Kondo model confirms that the Schmidt gap faithfully captures the scaling behaviour by correctly predicting the critical exponent of the dynamically generated length scale at the critical point.
A quantum phase transition may occur in the ground state of a system at zero temperature when a controlling field or interaction is varied. The resulting quantum fluctuations which trigger the transition produce scaling behaviour of various observables, governed by universal critical exponents. A particularly interesting class of such transitions appear in systems with quantum impurities where a non-extensive term in the free energy becomes singular at the critical point. Curiously, the notion of a conventional order parameter that exhibits scaling at the critical point is generically missing in these systems. Here we explore the possibility to use the Schmidt gap, which is an observable obtained from the entanglement spectrum, as an order parameter. A case study of the two-impurity Kondo model confirms that the Schmidt gap faithfully captures the scaling behaviour by correctly predicting the critical exponent of the dynamically generated length scale at the critical point.
The emerging field of quantum thermodynamics is contributing important results and insights into archetypal many-body problems, including quantum phase transitions. Still, the question whether out-of-equilibrium quantities, such as fluctuations of work, exhibit critical scaling after a sudden quench in a closed system has remained elusive. Here, we take a novel approach to the problem by studying a quench across an impurity quantum critical point. By performing density matrix renormalization group computations on the two-impurity Kondo model, we are able to establish that the irreversible work produced in a quench exhibits finite-size scaling at quantum criticality. This scaling faithfully predicts the equilibrium critical exponents for the crossover length and the order parameter of the model, and, moreover, implies an exponent for the rescaled irreversible work. By connecting the irreversible work to the two-impurity spin correlation function, our findings can be tested experimentally.
A multichannel Kondo model, where two or more equivalent but independent channels of electrons compete to screen a spin-21 impurity, shows overcompensation of the impurity spin, leading to the non-Fermi-liquid behavior in various thermodynamic and transport properties. However, when the channel symmetry is broken, an impurity quantum phase transition can occur at zero temperature. Identification of an order parameter describing the impurity quantum phase transition is very difficult since it is beyond the conventional Landau-Ginzburg-Wilson theory. By employing the natural orbitals renormalization group method, we study both two-channel and three-channel Kondo models, from the perspective of spin correlation between the impurity and electrons in electronic channels. Here we demonstrate that by introducing the spin-correlation ratio as an order parameter we can characterize impurity quantum phase transitions driven by channel asymmetry. In particular, the universal critical exponents $\ensuremath{\beta}$ of the spin-correlation ratio and $\ensuremath{\nu}$ of the correlation length are explicitly determined by finite-size-scaling analysis, namely, $\ensuremath{\beta}=0.10(1)$ and $\ensuremath{\nu}=2.0(1)$, and $\ensuremath{\beta}=0.10(1)$ and $\ensuremath{\nu}=2.5(1)$ for the two-channel and three-channel Kondo models, respectively.
The study of entanglement spectra is a powerful tool to detect or elucidate universal behavior in quantum many-body systems. We investigate the scaling of the entanglement (or Schmidt) gap δξ , i.e., the lowest-laying gap of the entanglement spectrum, at a two-dimensional quantum critical point. We focus on the paradigmatic quantum spherical model, which exhibits a second-order transition and is mappable to free bosons with an additional external constraint. We analytically show that the Schmidt gap vanishes at the critical point, although only logarithmically. For a system on a torus and the half-system bipartition, the entanglement gap vanishes as π2/ ln(L), with L the linear system size. The entanglement gap is nonzero in the paramagnetic phase and exhibits a faster decay in the ordered phase. The rescaled gap δξ ln(L) exhibits a crossing for different system sizes at the transition, although logarithmic corrections prevent a precise verification of the finite-size scaling. Interestingly, the change of the entanglement gap across the phase diagram is reflected in the zero-mode eigenvector of the spin-spin correlator. At the transition quantum fluctuations give rise to a nontrivial structure of the eigenvector, whereas in the ordered phase it is flat. We also show that the vanishing of the entanglement gap at criticality can be qualitatively but not quantitatively captured by neglecting the structure of the zero-mode eigenvector.
We investigate the entanglement spectrum near criticality in finite quantum spin chains. Using finite size scaling we show that when approaching a quantum phase transition, the Schmidt gap, i.e., the difference between the two largest eigenvalues of the reduced density matrix λ(1), λ(2), signals the critical point and scales with universal critical exponents related to the relevant operators of the corresponding perturbed conformal field theory describing the critical point. Such scaling behavior allows us to identify explicitly the Schmidt gap as a local order parameter.
Two electronic channels competing to screen a single impurity spin, as in the two-channel Kondo model, are expected to generate a ground state with a nontrivial entanglement structure. We exploit a spin-chain representation of the two-channel Kondo model to probe the ground-state block entropy, negativity, tangle, and Schmidt gap, using a density matrix renormalization group approach. In the presence of symmetric coupling to the two channels, we confirm field-theory predictions for the boundary entropy difference ln(gUV/gIR)=ln(2)/2 between the ultraviolet and infrared limits and the leading ln(x)/x impurity correction to the block entropy. The impurity entanglement Simp is shown to scale with the characteristic length ${\ensuremath{\xi}}_{2\text{CK}}$. We show that both the Schmidt gap and the entanglement of the impurity with one of the channels---as measured by the negativity---faithfully serve as order parameters for the impurity quantum phase transition appearing as a function of channel asymmetry, allowing for explicit determination of critical exponents, $\ensuremath{\nu}\ensuremath{\approx}2$ and $\ensuremath{\beta}\ensuremath{\approx}0.2$. Remarkably, we find the emergence of tripartite entanglement only in the vicinity of the critical channel-symmetric point.
Quantum Phase Transitions Quantum phase transitions, in contrast to temperature-driven critical phenomena, occur due to a competition between different parameters describing the basic interactions of the system. Their specific feature is the quantum character of the critical fluctuations. This implies, through the uncertainty principle, that energy fluctuations and time are coupled. Then at zero temperature time plays a crucial and fundamental role, the static properties being entangled with the dynamics (Continentino, 1994a; Sondhi et al ., 1997; Sachdev, 1999). In this book we are mainly interested in quantum phase transitions that occur in electronic many-body systems and how scaling concepts can be useful to understand their properties close to these transitions (Continentino, 1994a). Even though a similar approach has been used in the case of interacting bosons (Fisher et al ., 1989) the fermionic problem has its own idiosyncrasies and difficulties. For example, there is no natural order parameter associated with the localisation transition in the electronic case, while bosons at zero temperature are either localised or superfluid so that the superfluid order parameter can be used to distinguish between both phases. If the results of the study of quantum phase transitions were restricted to zero temperature, this would be an interesting but purely academic area of research. What is really exciting about this subject is the effect of quantum critical points (QCP) in the finite temperature phase diagram of actual physical systems, even far away from the QCP (Freitas, 2015). As we will show, there is a special line in this phase diagram, the quantum critical trajectory , where the temperature dependence of the thermodynamic and transport properties is governed by the quantum critical exponents, i.e. those associated with the QCP. This and the observed crossover effects induced by temperature in the non-critical side of the phase diagram of a material with a QCP are sufficient to make the study of quantum phase transitions an inevitable subject. We start this chapter by introducing the scaling theory of quantum critical phenomena, since scaling concepts are used throughout this book.