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arXiv:1403.4744 · Physical Review E

Universal scaling effects of a temperature gradient at first-order transitions

Claudio Bonati, Massimo D’Elia, Ettore Vicari

Published Jun 25, 2014• 8 citations
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Abstract

We study the effects of smooth inhomogeneities at first-order transitions. We show that a temperature gradient at a thermally driven first-order transition gives rise to nontrivial universal scaling behaviors with respect to the length scale l_{t} of the variation of the local temperature T_{x}. We propose a scaling ansatz to describe the crossover region at the surface where T_{x}=T_{c}, where the typical discontinuities of a first-order transition are smoothed out. The predictions of this scaling theory are checked, and get strongly supported, by numerical results for the two-dimensional (2D) Potts models, for a sufficiently large number of states to have first-order transitions. Comparing with analogous results at the 2D Ising transition, we note that the scaling behaviors induced by a smooth inhomogeneity appear quite similar in first-order and continuous transitions.

DOI
10.1103/physreve.89.062132

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We study the effects of smooth inhomogeneities at first-order transitions. We show that a temperature gradient at a thermally driven first-order transition gives rise to nontrivial universal scaling behaviors with respect to the length scale l_{t} of the variation of the local temperature T_{x}. We propose a scaling ansatz to describe the crossover region at the surface where T_{x}=T_{c}, where the typical discontinuities of a first-order transition are smoothed out. The predictions of this scaling theory are checked, and get strongly supported, by numerical results for the two-dimensional (2D) Potts models, for a sufficiently large number of states to have first-order transitions. Comparing with analogous results at the 2D Ising transition, we note that the scaling behaviors induced by a smooth inhomogeneity appear quite similar in first-order and continuous transitions.
We investigate the effects of smooth inhomogeneities at first-order quantum transitions (FOQTs), such as those arising in the presence of a space-dependent external field, which smooths out the discontinuities of the low-energy properties at the transition. We argue that a universal scaling behavior emerges in the space transition region close to the point in which the external field takes the value for which the homogeneous system undergoes the FOQT. We verify the general theory in two model systems. We consider the quantum Ising chain in the ferromagnetic phase and the q-state Potts chain for q=10, investigating the scaling behavior which arises in the presence of an additional inhomogeneous parallel and transverse magnetic field, respectively. Numerical results are in full agreement with the general theory.
We study off-equilibrium behaviors at first-order transitions (FOTs) driven by a time dependence of the temperature across the transition point T(c), such as the linear behavior T(t)/T(c)=1±t/t(s) where t(s) is a time scale. In particular, we investigate the possibility of nontrivial off-equilibrium scaling behaviors in the regime of slow changes, corresponding to large t(s). We consider the two-dimensional Potts models, which provide an ideal theoretical laboratory to investigate issues related to FOTs driven by thermal fluctuations. We put forward general ansatzes for off-equilibrium scaling behaviors around the time t=0 corresponding to T(c). Then we present numerical results for the q=10 and 20 Potts models. We show that off-equilibrium scaling behaviors emerge at FOTs with relaxational dynamics, when appropriate boundary conditions are considered, such as mixed boundary conditions favoring different phases at the opposite sides of the system, which enforce an interface in the system.
Abstract Phase transitions, as one of the most intriguing phenomena in nature, are divided into first-order phase transitions (FOPTs) and continuous ones in current classification. While the latter shows striking phenomena of scaling and universality, the former has recently also been demonstrated to exhibit scaling and universal behavior within a mesoscopic, coarse-grained Landau–Ginzburg theory. Here we apply this theory to a microscopic model—the paradigmatic Ising model, which undergoes FOPTs between two ordered phases below its critical temperature—and unambiguously demonstrate universal scaling behavior in such FOPTs. These results open the door for extending the theory to other microscopic FOPT systems and experimentally testing them to systematically uncover their scaling and universal behavior.
We investigate finite-size effects at first-order quantum transitions. For this purpose we consider the one-dimensional q-state quantum Potts chain, in particular with q=10, which undergoes a first-order transition, separating the quantum disordered and ordered phases with a discontinuity in the energy density of the ground state. In agreement with the general theory, around the transition the low-energy properties show finite-size scaling with respect to appropriate scaling variables. Their size dependence is particularly sensitive to boundary conditions, which is a specific feature of first-order quantum transitions. Finally, we also discuss the finite-size behavior of the q-state Potts model (q≥2) at the first-order transitions driven by a parallel magnetic field, occurring in the ferromagnetic phase.
In systems displaying a bulk first-order transition the order parameter may vanish continuously at a free surface, a phenomenon which is called surface-induced disorder. In the presence of surface-induced disorder the correlation lengths, parallel and perpendicular to the surface, diverge at the bulk transition point. In this way the surface induces an anisotropic power-law singular behavior for some bulk quantities. For example, in a finite system of transverse linear size L, the response functions diverge as ${L}^{(d\ensuremath{-}1)z+1},$ where d is the dimension of the system and z is the anisotropy exponent. We present a general scaling picture for this anisotropic discontinuity fixed point. Our phenomenological results are confronted with analytical and numerical calculations on the two-dimensional q-state Potts model in the large-qqq limit. The scaling results are demonstrated to apply also for the same model with a layered, Fibonacci-type modulation of the couplings for which the anisotropy exponent is a continuous function of the strength of the quasiperiodic perturbation.
Systems with a bulk first-order transition can display diverging correlation lengths close to a surface. This surface induced disordering yields a special type of surface criticality. Using extensive numerical simulations we study surface quantities in the two-dimensional Potts model with a large number of states qqq which undergoes a discontinuous bulk transition. The surface critical exponents are thereby found to depend on the value of qqq, which is in contrast to prior claims that these exponents should be universal and independent of qqq. It follows that surface-induced disordering at first-order transitions is characterized by exponents that depend on the details of the model.