While long spin coherence times and efficient single-qubit quantum control have been implemented successfully in nitrogen-vacancy (NV) centers in diamond, the controlled coupling of remote NV spin qubits remains challenging. Here, we propose and analyze a controlled-phase (cphase) gate for the spins of two NV centers embedded in a common optical cavity and driven by two off-resonant lasers. In combination with previously demonstrated single-qubit gates, cphase allows for arbitrary quantum computations. The coupling of the NV spin to the cavity mode is based upon Raman transitions via the NV excited states and can be controlled with the laser intensities and relative phase. We find characteristic laser frequencies at which the scattering amplitude of a laser photon into the cavity mode is strongly dependent on the NV center spin. A scattered photon can be reabsorbed by another selectively driven NV center and can generate a conditional phase (cphase) gate. Gate times around 200 ns are within reach, nearly two orders of magnitude shorter than typical NV spin coherence times of around 10 $\ensuremath{\mu}\mathrm{s}$. The separation between the two interacting NV centers is limited only by the extension of the cavity.
While long spin coherence times and efficient single-qubit quantum control have been implemented successfully in nitrogen-vacancy (NV) centers in diamond, the controlled coupling of remote NV spin qubits remains challenging. Here, we propose and analyze a controlled-phase (cphase) gate for the spins of two NV centers embedded in a common optical cavity and driven by two off-resonant lasers. In combination with previously demonstrated single-qubit gates, cphase allows for arbitrary quantum computations. The coupling of the NV spin to the cavity mode is based upon Raman transitions via the NV excited states and can be controlled with the laser intensities and relative phase. We find characteristic laser frequencies at which the scattering amplitude of a laser photon into the cavity mode is strongly dependent on the NV center spin. A scattered photon can be reabsorbed by another selectively driven NV center and can generate a conditional phase (cphase) gate. Gate times around 200 ns are within reach, nearly two orders of magnitude shorter than typical NV spin coherence times of around 10 \ensuremathμs. The separation between the two interacting NV centers is limited only by the extension of the cavity.
Defect centers in diamond are exceptional solid-state quantum systems that can have exceedingly long electron and nuclear spin coherence times. So far, single-qubit gates for the nitrogen nuclear spin, a two-qubit gate with a nitrogen-vacancy (NV) center electron spin, and entanglement between nearby nitrogen nuclear spins have been demonstrated. Here, we develop a scheme to implement a universal two-qubit gate between two distant nitrogen nuclear spins. Virtual excitation of an NV center that is embedded in an optical cavity can scatter a laser photon into the cavity mode; we show that this process depends on the nuclear spin state of the nitrogen atom. If two NV centers are simultaneously coupled to a common cavity mode and individually excited, virtual cavity photon exchange can mediate an effective interaction between the nuclear spin qubits, conditioned on the spin state of both nuclei, which implements a universal controlled-Z gate. We predict operation times below $10\phantom{\rule{0.16em}{0ex}}\ensuremath{\mu}\mathrm{s}$, which is four orders of magnitude faster than the decoherence time of nuclear spin qubits in diamond.
We propose efficient schemes for universal quantum gates with the photon polarization states and electron spin states of nitrogen-vacancy (NV) centers in diamond embedded in optical microcavity. A hybrid polarization-spin controlled-NOT gate and a two-qubit controlled phase gate between NV centers in separated cavities are demonstrated in the weak-coupling regime without complex devices or interaction. The gates presented here are deterministic and can be applied directly to a variety of quantum information processing tasks. The feasibility analyses show that our schemes can be accomplished with high fidelity under current technologies and have wide potential applications in quantum communication and computation fields.
The nitrogen-vacancy (NV) center in diamond has garnered great interest over the past decade as its electronic spin shows promise as a quantum bit (qubit) and nanoscale sensor. Consisting of a substitutional nitrogen adjacent to a vacant site within the carbon lattice of diamond, this defect exhibits millisecond-long spin coherence times extending beyond room temperature, spin-dependent optical addressability, coupling to intrinsic and nearby nuclear spins, and it can be controlled and manipulated through electrical, magnetic, and optical means. In particular, at cryogenic temperatures (T < 25 K), the NV center's excited state becomes sharp and optically resolvable, providing a solid-state quantum optical testbed. In this thesis, I describe several experiments that explore this quantum optical interface to facilitate the development of a photonic network of single spins linked and controlled by light. We begin by exploring how electric fields tune the orbital levels within the NV center through the DC Stark effect, finding a surprising photo-induced field that aids in the ability to tune multiple NV centers' optical transitions to degeneracy. We then develop techniques to fully control the spin state of the NV center by coupling through a lambda system, an energy configuration consisting of two lower levels coupled to one of higher energy. When a lambda system is optically driven, the spin becomes trapped in a dark state, or the eigenstate of the system that is not coupled to the light fields through destructive interference, forming the basis for the various types of control demonstrated. We demonstrate arbitrary-basis initialization and readout of the spin state through coherent population trapping, as well as the ability to rotate about any arbitrary basis through stimulated Raman transitions. Combining these techniques, we measure the NV center's spin coherence through a completely optical measurement. We then extend these lambda system techniques to adiabatically move the dark state in trajectories around the Bloch sphere. Such trajectories accumulate a quantum mechanical phase that depends only on the geometry of the path enclosed, not on the energetics or time of the interaction. We characterize the interaction, measure this phase, known as Berry phase, and explore the limits of its control and resilience to noise. Finally, we demonstrate another all-optical control technique that uses strong ultrafast pulses of light to transfer the spin between the ground and excited states, deriving spin manipulation from the excited state dynamics. This technique also provides time-resolved spectroscopy of the excited state and its various decay and decoherence mechanisms. These experiments advance the progress toward the development of photonic networks coupling and controlling defects through light-matter interactions.
The implementation of a high-fidelity two-qubit quantum logic gate remains an outstanding challenge for isolated solid-state qubits such as nitrogen-vacancy (NV) centers in diamond. In this work, we show that by driving pairs of NV centers to undergo photon scattering processes that flip their qubit states simultaneously, we can achieve a unitary two-qubit gate conditioned upon a single photon-detection event. Further, by exploiting quantum interference between the optical transitions of the NV centers' electronic states, we realize the existence of two special drive frequencies: a ``magic'' point where the spin-preserving elastic scattering rates are suppressed and a ``balanced'' point where the state-flipping scattering rates are equal. We analyzed four different gate operation schemes that utilize these two special drive frequencies, and various combinations of polarizations in the drive and collection paths. Our theoretical and numerical calculations show that the gate fidelity can be as high as 98%. The proposed unitary gate, combined with available single-qubit unitary operations, forms a universal gate set for quantum computing.
An efficient interface between a spin qubit and single photons is a key enabling system for quantum science and technology. We report on a coherently controlled diamond nitrogen-vacancy center electron spin qubit that is optically interfaced with an open microcavity. Through Purcell enhancement and an asymmetric cavity design, we achieve efficient collection of resonant photons, while on-chip microwave lines allow for spin qubit control at a 10 MHz Rabi frequency. With the microcavity tuned to resonance with the nitrogen-vacancy center’s optical transition, we use excited state lifetime measurements to determine a Purcell factor of 7.3 ± 1.6. Upon pulsed resonant excitation, we find a coherent photon detection probability of 0.5% per pulse. Although this result is limited by the finite excitation probability, it already presents an order of magnitude improvement over the solid immersion lens devices used in previous quantum network demonstrations. Furthermore, we use resonant optical pulses to initialize and read out the electron spin. By combining the efficient interface with spin qubit control, we generate two-qubit and three-qubit spin-photon states and measure heralded Z-basis correlations between the photonic time-bin qubits and the spin qubit. Current applications of NV centers in diamond as spin-photon interfaces for quantum networks are limited by low coherent photon emission. Here, the authors integrate a coherently controlled NV spin qubit with an open microcavity to achieve Purcell-enhanced emission and demonstrate spin-photon state generation.
Nitrogen-vacancy (NV) centers in nanodiamond offer a promising platform for quantum information processing due to their room-temperature spin coherence and optical addressability. However, scalable quantum processors remain limited by the challenge of achieving strong, controllable interactions between distant NV spins. Here, we propose a scalable architecture utilizing optically levitated nanodiamond arrays, where torsional vibrations mediate the coherent coupling between the embedded NV centers. By optimizing the shape of ellipsoidal nanoparticles, we achieve a light-induced coupling strength exceeding 119 kHz between torsional modes of the distant levitated nanodiamonds, which are two orders of magnitude larger than the typical decoherence rates in this system. This strong interaction, combined with magnetic-field-enabled spin-torsion coupling, establishes an effective interaction between the spatially separated NV centers in the distant nanodiamonds. Numerical simulations confirm that dynamic decoupling can suppress both thermal noise and spin dephasing, enabling two-qubit gates with fidelity exceeding 99%. This work provides a foundation for reconfigurable quantum hybrid systems, with potential applications in rotational sensing and programmable quantum processing.