How much work can be extracted from a heat bath using a thermal machine? The study of this question has a very long history in statistical physics in the weak-coupling limit, when applied to macroscopic systems. However, the assumption that thermal heat baths remain uncorrelated with associated physical systems is less reasonable on the nano-scale and in the quantum setting. In this work, we establish a framework of work extraction in the presence of quantum correlations. We show in a mathematically rigorous and quantitative fashion that quantum correlations and entanglement emerge as limitations to work extraction compared to what would be allowed by the second law of thermodynamics. At the heart of the approach are operations that capture the naturally non-equilibrium dynamics encountered when putting physical systems into contact with each other. We discuss various limits that relate to known results and put our work into the context of approaches to finite-time quantum thermodynamics.
How much work can be extracted from a heat bath using a thermal machine? The study of this question has a very long history in statistical physics in the weak-coupling limit, when applied to macroscopic systems. However, the assumption that thermal heat baths remain uncorrelated with associated physical systems is less reasonable on the nano-scale and in the quantum setting. In this work, we establish a framework of work extraction in the presence of quantum correlations. We show in a mathematically rigorous and quantitative fashion that quantum correlations and entanglement emerge as limitations to work extraction compared to what would be allowed by the second law of thermodynamics. At the heart of the approach are operations that capture the naturally non-equilibrium dynamics encountered when putting physical systems into contact with each other. We discuss various limits that relate to known results and put our work into the context of approaches to finite-time quantum thermodynamics.
How much work can be extracted from a heat bath using a thermal machine operating at the quantum level? In this work, we establish a framework of work extraction in the presence of quantum correlations as they naturally emerge in quantum thermodynamics beyond the weak-coupling regime. Quantum correlations and entanglement, as they are ubiquitously encountered when putting systems into contact with a bath, emerge as a limitation to work extraction, rather than as an advantage. We bring together concepts of quantum thermodynamics with those of non-equilibrium dynamics, in a rigorous but physically motivated approach. We discuss various limits that relate to known results and put our work into context of approaches to finite-time quantum thermodynamics.
The laws of thermodynamics strongly restrict the performance of thermal machines. Standard thermodynamics, initially developed for uncorrelated macroscopic systems, does not hold for microscopic systems correlated with their environments. We here derive an exact formula for the efficiency of any cyclically driven quantum engine by using generalized laws of quantum thermodynamics that account for all possible correlations between all involved parties, including initial correlations. Furthermore, we demonstrate the existence of two basic modes of engine operation: the usual thermal case, where heat is converted into work, and an athermal regime, where work is extracted from entropic resources, such as system-bath correlations. In the latter regime, the efficiency is not bounded by the usual Carnot formula. Our results provide a unified formalism to determine the efficiency of correlated microscopic quantum machines.
Thermodynamics at the nanoscale is known to differ significantly from its familiar macroscopic counterpart: The possibility of state transitions is not determined by free energy alone but by an infinite family of free-energy-like quantities; strong fluctuations (possibly of quantum origin) allow one to extract less work reliably than what is expected from computing the free-energy difference.However, these known results rely crucially on the assumption that the thermal machine is not only exactly preserved in every cycle but also kept uncorrelated from the quantum systems on which it acts.Here, we lift this restriction: We allow the machine to become correlated with the microscopic systems on which it acts while still exactly preserving its own state.Surprisingly, we show that this possibility restores the second law in its original form: Free energy alone determines the possible state transitions, and the corresponding amount of work can be invested or extracted from single systems exactly and without any fluctuations.At the same time, the work reservoir remains uncorrelated from all other systems and parts of the machine.Thus, microscopic machines can increase their efficiency via clever "correlation engineering" in a perfectly cyclic manner, which is achieved by a catalytic system that can sometimes be as small as a single qubit (though some setups require very large catalysts).Our results also solve some open mathematical problems on majorization which may lead to further applications in entanglement theory.
The stationary state of a quantum particle strongly coupled to a quantum thermal bath is known to be non-Gibbsian, due to entanglement with the bath. For harmonic potentials, where the system can be described by effective temperatures, thermodynamic relations are shown to take a generalized Gibbsian form that may violate the Clausius inequality. For the weakly anharmonic case, a Fokker-Planck-type description is constructed. It is shown that then work can be extracted from the bath by cyclic variation of a parameter. These apparent violations of the second law are the consequence of quantum coherence in the presence of the slightly off-equilibrium nature of the bath.
Thermodynamics typically concerns the physical behaviour of macroscopic systems comprised of many particles. However, recent theoretical progress has extended the theory to both the classical-stochastic and quantum regimes, where systems are comprised of just a small number of particles. In this thesis I investigate a range of situations in which new thermodynamic phenomena emerge due to the reduced size of the systems involved. One central assumption in macroscopic thermodynamics is the weak coupling approximation, which posits that the equilibrium properties of a system are not influenced by the interactions with its surrounding environment. However, for microscopic systems this assumption can break down, and I derive new fluctuation relations that provide a refined form of the second law of thermodynamics in this strong-coupling regime, taking into account corrections stemming from these interactions. In this work I provide a characterisation of stochastic heat and entropy production for small scale classical systems that are defined regardless of the strength of interaction. I then show that these definitions lead to a consistent thermodynamic framework valid beyond the usual weak-coupling regime. The thesis also concerns the effect of interactions on the equilibrium properties of strongly-coupled quantum systems, and I investigate how these interactions can influence the resulting temperature fluctuations in this regime. Using tools from quantum estimation theory, I derive an uncertainty relation between energy and temperature valid at all coupling strengths and system sizes. The relation reveals how quantum energy coherences contribute to statistical fluctuations in the estimated temperature of small- scale systems. Finally, I investigate how quantum fluctuations influence the statistics of work extracted from slowly-driven quantum systems. I prove that, unlike in classical systems, the work dissipated by a general quantum system is no longer proportional to its statistical fluctuations. This result reveals new subtleties involved in designing optimal quantum thermodynamic processes.
In recent years we have witnessed a concentrated effort to make sense of thermodynamics for small-scale systems. One of the main difficulties is to capture a suitable notion of work that models realistically the purpose of quantum machines, in an analogous way to the role played, for macroscopic machines, by the energy stored in the idealisation of a lifted weight. Despite several attempts to resolve this issue by putting forward specific models, these are far from realistically capturing the transitions that a quantum machine is expected to perform. In this work, we adopt a novel strategy by considering arbitrary kinds of systems that one can attach to a quantum thermal machine and defining work quantifiers . These are functions that measure the value of a transition and generalise the concept of work beyond those models familiar from phenomenological thermodynamics. We do so by imposing simple operational axioms that any reasonable work quantifier must fulfil and by deriving from them stringent mathematical condition with a clear physical interpretation. Our approach allows us to derive much of the structure of the theory of thermodynamics without taking the definition of work as a primitive. We can derive, for any work quantifier , a quantitative second law in the sense of bounding the work that can be performed using some non-equilibrium resource by the work that is needed to create it. We also discuss in detail the role of reversibility and correlations in connection with the second law. Furthermore, we recover the usual identification of work with energy in degrees of freedom with vanishing entropy as a particular case of our formalism. Our mathematical results can be formulated abstractly and are general enough to carry over to other resource theories than quantum thermodynamics.