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arXiv:1310.0109 · Journal of the Physical Society of Japan

Resonating-Valence-Bond Liquid in Low Dimensions

Fusayoshi J. Ohkawa

Published Nov 11, 2014• 0 citations
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Abstract

The Hubbard model in $D$ dimensions, with the on-site repulsion $U$ and the transfer integral between nearest neighbors $-t/\sqrt{D}$, is studied on the basis of the Kondo-lattice theory. If $U/|t| \gg 1$, $|n - 1| \lesssim |t|/(DU)$, where $n$ is the number of electrons per unit cell, and $D$ is so small that $|J|/D \gg k_{\rm B}T_c$, where $J = -4t^2/U$ and $T_c$ is $0 {\rm K}$ for $D = 1$ and is the highest critical temperature among possible ones for $D \ge 2$, a low-$T$ phase where $T_c < T \ll |J|/(k_{\rm B}D)$ is a frustrated electron liquid. Since the liquid is stabilized by the Kondo effect in conjunction with the resonating-valence-bond (RVB) mechanism, it is simply the RVB electron liquid; in one dimension, it is also the Tomonaga-Luttinger liquid. The Kondo energy of the RVB liquid is $k_{\rm B}T_{\rm K} = O(|J|/D)$; its effective Fermi energy is $O(k_{\rm B}T_{\rm K})$. A midband appears on the chemical potential between the upper and lower Hubbard bands; the Hubbard gap is a pseudogap. As regards the density of states per unit cell of the midband, its bandwidth is $O(k_{\rm B}T_{\rm K})$ or $O(|J|/D)$, its peak height is $O(1/U)$, and its spectral weight is $O[t^2/(DU^2)]$. Since the midband almost disappears in the Heisenberg limit, the RVB electron liquid in the Heisenberg limit is simply the RVB spin liquid. The RVB electron and spin liquids adiabatically continue to each other. Since local moments form in a high-$T$ phase where $T \gtrsim T_{\rm K}$, the high-$T$ phase is simply the Mott insulator.

DOI
10.7566/jpsj.83.124703

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The Hubbard model in DDD dimensions, with the on-site repulsion UUU and the transfer integral between nearest neighbors −t/D-t/\sqrt{D}−t/D​, is studied on the basis of the Kondo-lattice theory. If U/∣t∣≫1U/|t| \gg 1U/∣t∣≫1, ∣n−1∣≲∣t∣/(DU)|n - 1| \lesssim |t|/(DU)∣n−1∣≲∣t∣/(DU), where nnn is the number of electrons per unit cell, and DDD is so small that ∣J∣/D≫kBTc|J|/D \gg k_{\rm B}T_c∣J∣/D≫kB​Tc​, where J=−4t2/UJ = -4t^2/UJ=−4t2/U and TcT_cTc​ is 0K0 {\rm K}0K for D=1D = 1D=1 and is the highest critical temperature among possible ones for D≥2D \ge 2D≥2, a low-TTT phase where Tc<T≪∣J∣/(kBD)T_c < T \ll |J|/(k_{\rm B}D)Tc​<T≪∣J∣/(kB​D) is a frustrated electron liquid. Since the liquid is stabilized by the Kondo effect in conjunction with the resonating-valence-bond (RVB) mechanism, it is simply the RVB electron liquid; in one dimension, it is also the Tomonaga-Luttinger liquid. The Kondo energy of the RVB liquid is kBTK=O(∣J∣/D)k_{\rm B}T_{\rm K} = O(|J|/D)kB​TK​=O(∣J∣/D); its effective Fermi energy is O(kBTK)O(k_{\rm B}T_{\rm K})O(kB​TK​). A midband appears on the chemical potential between the upper and lower Hubbard bands; the Hubbard gap is a pseudogap. As regards the density of states per unit cell of the midband, its bandwidth is O(kBTK)O(k_{\rm B}T_{\rm K})O(kB​TK​) or O(∣J∣/D)O(|J|/D)O(∣J∣/D), its peak height is O(1/U)O(1/U)O(1/U), and its spectral weight is O[t2/(DU2)]O[t^2/(DU^2)]O[t2/(DU2)]. Since the midband almost disappears in the Heisenberg limit, the RVB electron liquid in the Heisenberg limit is simply the RVB spin liquid. The RVB electron and spin liquids adiabatically continue to each other. Since local moments form in a high-TTT phase where T≳TKT \gtrsim T_{\rm K}T≳TK​, the high-TTT phase is simply the Mott insulator.
The Hubbard model in the strong-coupling regime is mainly studied by Kondo-lattice theory or 1/d expansion theory, with d the spatial dimensionality. In two dimensions and higher, the ground state within the Hilbert subspace with no order parameter is a normal Fermi liquid except for n=1 and U/W=+infinity, with n the electron density per unit cell, U the on-site repulsion, and W the bandwidth; the cooperation between the Kondo effect, which favors a local singlet on each unit cell, and a resonating-valence-bond effect, which favors a local singlet on each pair of nearest-neighbor unit cells, stabilizes the Fermi liquid, whose ground state is a singlet as a whole, in the strong-coupling regime. In the whole Hilbert space with no restriction, the normal Fermi liquid is unstable at least against a magnetic or superconducting state. This analysis confirms an early Fermi-liquid theory of high-temperature superconductivity, F. J. Ohkawa, Jpn. J. Appl. Phys. 26, L652 (1987). The ground state for n=1 and U/W=+infinity is a Mott insulator. Actual metal-insulator transitions cannot be explained within the Hubbard model. In order to explain them, the electron-phonon interaction, multi-band or multi-orbital effects, and effects of disorder should be considered beyond the Hubbard model. The crossover between local-moment magnetism and itinerant-electron magnetism corresponds to that between a localized spin and a normal Fermi liquid in the Kondo effect and it is simply a Mott metal-insulator crossover.
The Hubbard model in the strong-coupling regime is studied by the Kondo-lattice theory. If no symmetry is broken at a sufficiently low temperature in sufficiently low dimensions, an electron liquid is stabilized by the Fock-type exchange effect of the superexchange interaction. Since the stabilization mechanism is none other than the resonating-valence-bond (RVB) mechanism, the electron liquid is none other than an RVB electron liquid. The RVB electron liquid in the Hubbard model is adiabatically connected to the RVB spin liquid in the Heisenberg model.
The ground state of the Hubbard model is studied within the constrained Hilbert space where no order parameter exists.The self-energy of electrons is decomposed into the single-site and multisite self-energies.The calculation of the single-site self-energy is mapped to a problem of self-consistently determining and solving the Anderson model.When an electron reservoir is explicitly considered, it is proved that the single-site self-energy is that of a normal Fermi liquid even if the multisite self-energy is anomalous.Thus, the ground state is a normal Fermi liquid in the supreme single-site approximation (S 3 A).In the strong-coupling regime, the Fermi liquid is stabilized by the Kondo effect in the S 3 A and is further stabilized by the Fock-type term of the superexchange interaction or the resonating-valence-bond (RVB) mechanism beyond the S 3 A. The stabilized Fermi liquid is frustrated as much as an RVB spin liquid in the Heisenberg model.It is a relevant unperturbed state that can be used to study a normal or anomalous Fermi liquid and an ordered state in the whole Hilbert space by Kondo lattice theory.Even if higher-order multisite terms than the Fock-type term are considered, the ground state cannot be a Mott insulator.It can be merely a gapless semiconductor even if the multisite self-energy is so anomalous that it is divergent at the chemical potential.A Mott insulator is only possible as a high temperature phase.
The ground state of the Hubbard model is studied within the constrained Hilbert space where no order parameter exists. The self-energy of electrons is decomposed into the single-site and multisite self-energies. The calculation of the single-site self-energy is mapped to a problem of self-consistently determining and solving the Anderson model. When an electron reservoir is explicitly considered, it is proved that the single-site self-energy is that of a normal Fermi liquid even if the multisite self-energy is anomalous. Thus, the ground state is a normal Fermi liquid in the supreme single-site approximation (S3A). In the strong-coupling regime, the Fermi liquid is stabilized by the Kondo effect in the S3A and is further stabilized by the Fock-type term of the superexchange interaction or the resonating-valence-bond (RVB) mechanism beyond the S3A. The stabilized Fermi liquid is frustrated as much as an RVB spin liquid in the Heisenberg model. It is a relevant unperturbed state that can be used to study a normal or anomalous Fermi liquid and an ordered state in the whole Hilbert space by Kondo lattice theory. Even if higher-order multisite terms than the Fock-type term are considered, the ground state cannot be a Mott insulator. It can be merely a gapless semiconductor even if the multisite self-energy is so anomalous that it is divergent at the chemical potential. A Mott insulator is only possible as a high temperature phase.
Very soon after the discovery of the high-Tc cuprate superconductors Anderson proposed the key to understanding their highly unusual properties lay in the ansatz that they were hole doped spin liquids in which the spins are bound in singlet pairs resonating between different configurations. This RVB concept is generally formulated for a doped Mott insulator, i.e. for a system with a strong onsite Coulomb interaction. It is instructive to explore the approach from weak Coulomb interaction to see if similar behavior can also occur case. Quasi-one dimensional systems in the form of finite width ladders do indeed show such behavior with a continuous crossover from weak to strong interaction limits. In two dimensions functional renormalization group methods have recently been developed to treat weak to moderately strong interactions. These show that similar behavior can occur in the case that the Fermi energy lies near the logarithmically divergent van Hove singularity in the density of states when the band is nearly half-filled. These methods are limited to a description of the flow to strong coupling as the energy or temperature scale is lowered. The form of the strong coupling phase can be explored by numerical techniques. However a proper theory of this phase is lacking and even a consistent phenomenological description has not yet been achieved.
We use Monte Carlo simulations to study properties of Anderson's resonating-valence-bond (RVB) spin-liquid state on the square lattice (i.e., the equal superposition of all pairing of spins into nearest-neighbor singlet pairs) and compare with the classical dimer model (CDM). The latter system also corresponds to the ground state of the Rokhsar-Kivelson quantum dimer model at its critical point. We find that, although spin-spin correlations decay exponentially in the RVB, four-spin valence-bond-solid correlations are critical, qualitatively like the well-known dimer-dimer correlations of the CDM, but decaying more slowly (as $1/{r}^{\ensuremath{\alpha}}$ with $\ensuremath{\alpha}\ensuremath{\approx}1.20$, compared with $\ensuremath{\alpha}=2$ for the CDM). We also compute the distribution of monomer (defect) pair separations, which decay by a larger exponent in the RVB than in the CDM. We further study both models in their different winding-number sectors and evaluate the relative weights of different sectors. Like the CDM, all the observed RVB behaviors can be understood in the framework of a mapping to a ``height'' model characterized by a gradient-squared stiffness constant KKK. Four independent measurements consistently show a value ${K}_{\mathrm{RVB}}\ensuremath{\approx}1.6{K}_{\mathrm{CDM}}$, with the same kinds of numerical evaluations of KCDM{K}_{\mathrm{CDM}}KCDM​ giving results in agreement with the rigorously known value ${K}_{\mathrm{CDM}}=\ensuremath{\pi}/16$. The background of a nonzero winding-number gradient W/LW/LW/L introduces spatial anisotropies and an increase in the effective KKK, both of which can be understood as a consequence of anharmonic terms in the height-model free energy, which are of relevance to the recently proposed scenario of ``Cantor deconfinement'' in extended quantum dimer models. In addition to the standard case of short bonds only, we also studied ensembles in which fourth-neighbor (bipartite) bonds are allowed at a density controlled by a tunable fugacity, resulting (as expected) in a smooth reduction of KKK.