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arXiv:1309.5745

Quantum beats of the rigid rotor

K. Kowalski, Jakub Rembieliński

Published Sep 23, 2013• 0 citations
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Abstract

The dynamics is investigated of a free particle on a sphere (rigid rotor or rotator) that is initially in a coherent state. The instability of coherent states with respect to the free evolution leads to nontrivial time-development of averages of observables representing the position of a particle on a sphere that can be interpreted as quantum beats.

DOI
10.48550/arxiv.1309.5745

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•Nov 7, 2018•3 citations
The dynamics is investigated of a free particle on a sphere (rigid rotor or rotator) that is initially in a coherent state. The instability of coherent states with respect to the free evolution leads to nontrivial time-development of averages of observables representing the position of a particle on a sphere that can be interpreted as quantum beats.
The coherent states for a particle on a sphere are introduced. These states are labelled by points of the classical phase space, i.e. the position on the sphere and the angular momentum of a particle. As with the coherent states for a particle on a circle discussed in Kowalski et al ( 1996 J. Phys. A: Math. Gen. 29 4149 ), we deal with a deformation of the classical phase space related to quantum fluctuations. The expectation values of the position and the angular momentum in the coherent states are regarded as the best possible approximation of the classical phase space. The correctness of the introduced coherent states is illustrated by an example of the rotator.
Physical consequences of the theorem of equivalence among harmonic oscillators of different frequencies, including a free particle as a special case, are explored. A new pictorial way of understanding time-dependent coherent states and squeezed states are presented and contrasted with the standard view. Three-dimensional spherical analogues of squeezed coherent states are constructed. It is also shown as a corollary of the theorem that a free wave packet which coincides initially with any one of the eigenfunctions of a harmonic oscillator maintains its shape, that is, the probability density of position does not change apart from a time-dependent scaling of spatial coordinates. Most of the results are derived without use of any sophisticated techniques but with the knowledge of free wave packets alone.
We study, analytically as well as numerically, the dynamics that arises from the interaction of a polar polarizable rigid rotor with single unipolar electromagnetic pulses of varying length, Δτ, with respect to the rotational period of the rotor, τr. In the sudden, non-adiabatic limit, Δτ ≪ τr, we derive analytic expressions for the rotor’s wavefunctions, kinetic energies, and field-free evolution of orientation and alignment. We verify the analytic results by solving the corresponding time-dependent Schrödinger equation numerically and extend the temporal range of the interactions considered all the way to the adiabatic limit, Δτ > τr, where general analytic solutions beyond the field-free case are no longer available. The effects of the orienting and aligning interactions as well as of their combination on the post-pulse populations of the rotational states are visualized as functions of the orienting and aligning kick strengths in terms of population quilts. Quantum carpets that encapsulate the evolution of the rotational wavepackets provide the space-time portraits of the resulting dynamics. The population quilts and quantum carpets reveal that purely orienting, purely aligning, or even-break combined interactions each exhibit sui generis dynamics. In the intermediate temporal regime, we find that the wavepackets as functions of the orienting and aligning kick strengths show resonances that correspond to diminished kinetic energies at particular values of the pulse duration.