In the previous companion paper, we proposed a subclass of wavefunctions to describe macroscopic solids that resolved and extended the theory quantum measurement and gave a more specific treatment of quasiparticles. Here we extend these notions to thermalization of solids and gases and to gas state hydrodynamics. This gives a modification of the thermodynamic limit to justify the canonical averages for "typical wavefunctions" without the use of ensembles. The energetic cost of vorticity is contrasted in the classical and ultracold gas limits. From this perspective, we then examine the applicability of thermo and hydro to ultracold gases and compare with the implications of pure state evolution. We illustrate how the proposed quantum limits on viscosity could be reinterpreted in terms of Schrödinger induced evolution of the one-body density function but some history dependent measurable properties should still persist.
In the previous companion paper, we proposed a subclass of wavefunctions to describe macroscopic solids that resolved and extended the theory quantum measurement and gave a more specific treatment of quasiparticles. Here we extend these notions to thermalization of solids and gases and to gas state hydrodynamics. This gives a modification of the thermodynamic limit to justify the canonical averages for "typical wavefunctions" without the use of ensembles. The energetic cost of vorticity is contrasted in the classical and ultracold gas limits. From this perspective, we then examine the applicability of thermo and hydro to ultracold gases and compare with the implications of pure state evolution. We illustrate how the proposed quantum limits on viscosity could be reinterpreted in terms of Schrödinger induced evolution of the one-body density function but some history dependent measurable properties should still persist.
Previous approaches of emergent thermalization for condensed matter based on typical wavefunctions are extended to generate an intrinsically quantum theory of gases. Gases are fundamentally quantum objects at all temperatures, by virtue of rapid delocalization of their constituents. When there is a sufficiently broad spread in the energy of eigenstates, a well-defined temperature is shown to arise by photon production when the samples are optically thick. This produces a highly accurate approximation to the Planck distribution so that thermalization arises from the initial data as a consequence of purely quantum and unitary dynamics. These results are used as a foil for some common hydrodynamic theory of ultracold gases. It is suggested here that strong history dependence typically remains in these gases and so limits the validity of thermodynamics in their description. These problems are even more profound in the extension of hydrodynamics to such gases when they are optically thin, even when their internal energy is not low. We investigate rotation of elliptically trapped gases and consistency problems with deriving a local hydrodynamic approach. The presence of vorticity that is "hidden" from order parameter approaches is discussed along with some buoyancy intrinsically associated with vorticity that gives essential quantum corrections to gases in the regimes where standard perturbation approaches to the Boltzmann equations are known to fail to converge. These results suggest that studying of trapped gases in the far from ultracold regions may yield interesting results not described by classical hydrodynamics.
Descriptions of molecular systems usually refer to two distinct theoretical frameworks. On the one hand the quantum pure state, i.e., the wavefunction, of an isolated system is determined to calculate molecular properties and their time evolution according to the unitary Schrödinger equation. On the other hand a mixed state, i.e., a statistical density matrix, is the standard formalism to account for thermal equilibrium, as postulated in the microcanonical quantum statistics. In the present paper an alternative treatment relying on a statistical analysis of the possible wavefunctions of an isolated system is presented. In analogy with the classical ergodic theory, the time evolution of the wavefunction determines the probability distribution in the phase space pertaining to an isolated system. However, this alone cannot account for a well defined thermodynamical description of the system in the macroscopic limit, unless a suitable probability distribution for the quantum constants of motion is introduced. We present a workable formalism assuring the emergence of typical values of thermodynamic functions, such as the internal energy and the entropy, in the large size limit of the system. This allows the identification of macroscopic properties independently of the specific realization of the quantum state. A description of material systems in agreement with equilibrium thermodynamics is then derived without constraints on the physical constituents and interactions of the system. Furthermore, the canonical statistics is recovered in all generality for the reduced density matrix of a subsystem.
Hydrodynamics of gases in the classical domain are examined from the perspective that the gas has a well-defined wavefunction description at all times. Specifically, the internal energy and volume exclusion of decorrelated vortex structures are included so that quantum corrections and modifications to Navier-Stokes behavior can be derived. This leads to a small deviation in rigid body rotation for a cylindrically bound gas and the internal energy changes associated with vorticity give deviations in the Reynolds' transport theorem. Some macroscopic observable features arising from this include variations in the specific heat, an anisotropic correction to thermal conductivity and a variation in optical scattering as a function of the declination from the axis of local vorticity. The improvements in magneto-optical traps suggests some interesting experiments to be done in higher temperature regimes where they are not usually employed. It is argued that the finite lifetime of observed vortices in ultracold bosonic gases is only apparent and these volume excluding structures persist in generating angular momentum and pressure in the cloud in a non-imageable form.
Since the systems described by quantum fields are by definition extended, it is natural to think that in some limit they may reasonably well be approximated as fluids. This means that the state of the system is parameterized by a few locally well-defined fields such as temperature or energy density, obeying a set of hyperbolic equations of motion. A concrete example is the extensive use of fluid models to describe high-energy collisions [BelLan56, CarDuo73, CoFrSc74, Bjo83, CarZac83]. Our earlier derivation of quantum kinetic theory suggests a way to put this insight on a formal basis. Within its range of validity, the Boltzmann equation will drive the one-particle distribution function towards local thermal equilibrium. On scales much larger than the local thermalization scale, we expect to see hydrodynamical behavior [BeCoPa02]. This is, after all, the usual way of deriving hydrodynamics from kinetic theory [Hua87]. Beware, notwithstanding, that even at the level of classical kinetic theory there are still open questions regarding the cross-over from the kinetic to the hydro regime [KarGor02, KarGor03]. If we understand hydrodynamics as stated in the first paragraph of this chapter, then a system defined in terms of a quantum field may not have a hydrodynamic limit. This has been shown in [Elz02] for the case of a free Fermi field.
We provide a pure state formulation for hydrodynamics of isolated quantum many-body systems. A pure state describing quantum systems in local thermal equilibrium is constructed, which we call a local thermal pure quantum ($\ensuremath{\ell}\mathrm{TPQ}$) state. We show that the thermodynamic functional and the expectation values of local operators (including a real-time correlation function) calculated from the $\ensuremath{\ell}\mathrm{TPQ}$ state converge to those from a local Gibbs ensemble in the large fluid-cell limit. As a numerical demonstration, we investigate a one-dimensional spin chain and observe the hydrodynamic relaxation obeying Fourier's law. We further prove the second law of thermodynamics and the quantum fluctuation theorem, which are also validated numerically. The $\ensuremath{\ell}\mathrm{TPQ}$ formulation gives a useful theoretical basis to describe the emergent hydrodynamic behavior of quantum many-body systems furnished with a numerical efficiency applicable to both the nonrelativistic and relativistic regimes.
The project concerns the interplay among quantum mechanics, statistical mechanics and thermodynamics, in isolated quantum systems. The underlying goal is to improve our understanding of the concept of thermal equilibrium in quantum systems. First, I investigated the role played by observables and measurements in the emergence of thermal behaviour. This led to a new notion of thermal equilibrium which is specific for a given observable, rather than for the whole state of the system. The equilibrium picture that emerges is a generalization of statistical mechanics in which we are not interested in the state of the system but only in the outcome of the measurement process. I investigated how this picture relates to one of the most promising approaches for the emergence of thermal behaviour in isolated quantum systems: the Eigenstate Thermalization Hypothesis. Then, I applied the results to study some equilibrium properties of many-body localised systems. Despite the localization phenomenon, which prevents thermalization of subsystems, I was able to show that we can still use the predictions of statistical mechanics to describe the equilibrium of some observables. Moreover, the intuition developed in the process led me to propose an experimentally accessible way to unravel the interacting nature of many-body localised systems. Second, I exploited the "Concentration of Measure" phenomenon to study the macroscopic properties of the basis states of Loop Quantum Gravity. These techniques were previously used to explain why the thermal behaviour in quantum systems is such an ubiquitous phenomenon, at the macroscopic scale. I focused on the local properties, their thermodynamic behaviour and interplay with the semiclassical limit. This was motivated by the necessity to understand, from a quantum gravity perspective, how and why a classical horizon exhibits thermal properties.