New quantum fluctuation relations are presented. In contrast with the standard approach, where the initial state of the driven system is described by the (micro) canonical density matrix, here we assume that it is described by a (micro) canonical distribution of wave functions, as originally proposed by Schrödinger. While the standard fluctuation relations are based on von Neumann measurement postulate, these new fluctuation relations do not involve any quantum collapse, but involve instead a notion of work as the change in expectation of the Hamiltonian.
Previously derived expressions for the characteristic function of work performed on a quantum system by a classical external force are generalized to arbitrary initial states of the considered system and to Hamiltonians with degenerate spectra. In the particular case of microcanonical initial states, explicit expressions for the characteristic function and the corresponding probability density of work are formulated. Their classical limit as well as their relations to the corresponding canonical expressions are discussed. A fluctuation theorem is derived that expresses the ratio of probabilities of work for a process and its time reversal to the ratio of densities of states of the microcanonical equilibrium systems with corresponding initial and final Hamiltonians. From this Crooks-type fluctuation theorem a relation between entropies of different systems can be derived which does not involve the time-reversed process. This entropy-from-work theorem provides an experimentally accessible way to measure entropies.
The recent remarkable developments in quantum optics, mesoscopic and cold atom physics have given reality to wave functions. It is then interesting to explore the consequences of assuming ensembles over the wave functions simply related to the canonical density matrix. In this note we analyze a previously introduced distribution over wave functions which naturally arises considering the Schrödinger equation as an infinite dimensional dynamical system. In particular, we discuss the low temperature fluctuations of the quantum expectations of coordinates and momenta for a particle in a double well potential. Our results may be of interest in the study of chiral molecules.
Quantum mechanics is reformulated using Hartle's definition of the state of an individual physical system and a variant of von Neumann's propositional calculus. An elementary set of quantum postulates lead inductively to the familiar formulas of quantum theory, including the canonical commutation relation and Schrödinger's equation. The expected value of the frequency of events for an ideal ensemble is equal to the expected value of a state operator for an individual system, producing a binomial probability distribution for the determination of indefinite experimental propositions.
The quantum measurement problems are revisited from a new perspective. One of the main ideas of this work is that the basic entities of our world are various types of particles, elementary or composite. It follows that each elementary process, hence each measurement process at its core, is a space–time, pointlike, event. Another key idea is that, when a microsystem [Formula: see text] gets into contact with the experimental device, factorization of [Formula: see text] rapidly fails and entangled mixed states appear. The wave functions for the microsystem-apparatus coupled systems for different measurement outcomes then lack overlapping space–time support. It means that the aftermath of each measurement is a single term in the sum: a “wave function collapse.” Our discussion leading to a diagonal density matrix, [Formula: see text] shows how the information encoded in the wave function [Formula: see text] gets transcribed, via entanglement with the experimental device and environment, into the relative frequencies [Formula: see text] for various experimental results [Formula: see text]. These results represent the first, significant steps towards filling in the logical gaps in the standard interpretation based on Born’s rule, and replacing it with a more natural one. Accepting objective reality of quantum fluctuations, independent of any experiments, and independently of human presence, one renounces the idea that in a fundamental, complete theory of Nature the result of each single experiment must necessarily be predictable. A few well-known puzzles such as the Schrödinger cat conundrum and the Einstein–Podolsky–Rosen (EPR) paradox are briefly reviewed: they can all be naturally explained away.
The probability operator is derived from first principles for an equilibrium quantum system. It is also shown that the superposition states collapse into a mixture of states giving the conventional von Neumann trace form for the quantum average. The mechanism for the collapse is found to be quite general: it results from the conservation law for a conserved, exchangeable variable (such as energy) and the entanglement of the total system wave function that necessarily follows. The relevance of the present results to the einselection mechanism for decoherence, to the quantum measurement problem, and to the classical nature of the macroscopic world are discussed.
The quantum measurement problems are discussed from a new perspective.
One of the main ideas of this work is that the basic entities of our world are various types of particles, elementary or composite. It follows that each elementary process, hence each measurement process at its core, is a spacetime, pointlike, event. Another key idea is that, when a microsystem
ψ gets into contact with the experimental device, factorization of
ψ rapidly fails and entangled mixed states appear. The wave functions for the microsystem-apparatus coupled systems for different measurement outcomes then lack overlapping spacetime support. It means that the aftermath of each measurement is a single term in the sum: a ``wave-function collapse.
Our discussion leading to a diagonal density matrix,
ρ=diag(∣c1∣2,…,∣cn∣2,…) shows how the information encoded in the wave function
∣ψ⟩=∑ncn∣n⟩ gets transcribed, via entanglement with the experimental device and environment, into the relative frequencies
Pn=∣cn∣2 for various experimental results
F=fn.
These results represent the first, significant steps towards filling in the logical gaps in the standard interpretation based on Born's rule, and replacing it with a more natural one. Accepting objective reality of quantum fluctuations, independent of any experiments, and independently of human presence, one renounces the idea that in a fundamental, complete theory of Nature the result of each single experiment must necessarily be predictable.
A few well-known puzzles such as the Schr\odinger cat conundrum and the EPR paradox are briefly reviewed: they can all be naturally explained away.