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arXiv:1305.6889 · Physical Review E

Molecules with an induced dipole moment in a stochastic electric field

Y. B. Band, Yehuda Ben‐Shimol

Published Oct 30, 2013• 4 citations
arXivHTMLPDF

Abstract

The mean-field dynamics of a molecule with an induced dipole moment (e.g., a homonuclear diatomic molecule) in a deterministic and a stochastic (fluctuating) electric field is solved to obtain the decoherence properties of the system. The average (over fluctuations) electric dipole moment and average angular momentum as a function of time for a Gaussian white noise electric field are determined via perturbative and nonperturbative solutions in the fluctuating field. In the perturbative solution, the components of the average electric dipole moment and the average angular momentum along the deterministic electric field direction do not decay to zero, despite fluctuations in all three components of the electric field. This is in contrast to the decay of the average over fluctuations of a magnetic moment in a Gaussian white noise magnetic field. In the nonperturbative solution, the component of the average electric dipole moment and the average angular momentum in the deterministic electric field direction also decay to zero.

DOI
10.1103/physreve.88.042149

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The mean-field dynamics of a molecule with an induced dipole moment (e.g., a homonuclear diatomic molecule) in a deterministic and a stochastic (fluctuating) electric field is solved to obtain the decoherence properties of the system. The average (over fluctuations) electric dipole moment and average angular momentum as a function of time for a Gaussian white noise electric field are determined via perturbative and nonperturbative solutions in the fluctuating field. In the perturbative solution, the components of the average electric dipole moment and the average angular momentum along the deterministic electric field direction do not decay to zero, despite fluctuations in all three components of the electric field. This is in contrast to the decay of the average over fluctuations of a magnetic moment in a Gaussian white noise magnetic field. In the nonperturbative solution, the component of the average electric dipole moment and the average angular momentum in the deterministic electric field direction also decay to zero.
The dynamics of a spin in the presence of a deterministic and a fluctuating magnetic field is solved for analytically to obtain the averaged value of the spin as a function of time for various kinds of fluctuations (noise). Specifically, analytic results are obtained for the time dependence of the expectation value of the spin, averaged over fluctuations, for Gaussian white noise, Gaussian colored noise, and non-Gaussian telegraph noise. Fluctuations cause the decay of the average spin vector (decoherence). For noise with a finite temporal correlation time, a deterministic component of the field can suppress the decoherence of the spin component along the field. Hence, decoherence can be manipulated by controlling the deterministic magnetic field. A simple universal physical picture emerges which explains the mechanism for the suppression of decay.
We investigate the influence of different electric moments on the shift and dephasing of molecules in a matter wave interferometer. Firstly, we provide a quantitative comparison of two molecules that are non-polar yet polarizable in their thermal ground state and that differ in their stiffness and response to thermal excitations . While C 25 H 20 is rather rigid, its larger derivative C 49 H 16 F 52 is additionally equipped with floppy side chains and vibrationally activated dipole moment variations. Secondly, we elucidate the role of a permanent electric dipole moment by contrasting the quantum interference pattern of a (nearly) non-polar and a polar porphyrin derivative. We find that a high molecular polarizability and even sizeable dipole moment fluctuations are still well compatible with high-contrast quantum interference fringes. The presence of permanent electric dipole moments, however, can lead to a dephasing and rapid degradation of the quantum fringe pattern already at moderate electric fields. This finding is of high relevance for coherence experiments with large organic molecules, which are generally equipped with strong electric moments.
In this paper, a coherent superposition of angular-momentum states created by absorption of polarized light by molecules is analyzed. Attention is paid to the time evolution of wave packets representing the spatial orientation of the internuclear axis of a diatomic molecule. Two examples are considered in detail. Molecules absorbing light in a permanent magnetic field experiencing the Zeeman effect and molecules absorbing light in a permanent electric field experiencing the quadratic Stark effect. In a magnetic field, we have a wave packet that evolves in time exactly as a classical dipole oscillator in a permanent magnetic field (classical-physics picture of the Zeeman effect). In the second case, we have a wave packet that goes through periodical changes of shape of the packet with revivals of the initial shape. This is pure quantum behavior. The classical motion of angular momentum in an electric field in the case of a quadratic Stark effect is known to be a periodic. Solutions obtained for wave packet evolution are briefly compared with Rydberg-state coherent wave packets and harmonic-oscillator wave packets. Zeeman and Stark effects in small molecules continuously attract the attention of researchers, theoreticians, as well as experimentalists. These investigations allow us to obtain a deeper understanding of the interaction of molecules with stationary external fields and also can be used as a practical tool to measure different molecular characteristics, such as permanent electric or magnetic dipole moments, intramolecular perturbations, etc. It is worthwhile analyzing these effects as an evolution of wave packets. All this motivates a comparison of the quantum and classical picture of Zeeman and Stark effects in molecules.PACS No.: 33.55.Be
The behaviour of the interaction of the induced electric dipole moment of an atom with a uniform magnetic field and a non-uniform electric field are investigated in a rotating reference frame. An interesting aspect of this interaction is that it gives rise to an analogue of a spinless particle subject to the doubly anharmonic oscillator. Then, it is shown that analytical solutions to the Schrödinger equation can be obtained. Another point raised is that the quantum effects on the induced electric dipole moment can be observed if the uniform magnetic field possesses a discrete set of values.
The effect of ambient magnetic fields on the dynamics of a single trapped ion is studied analytically. We consider two electronic states with energy separation stochastically varied by magnetic-field perturbations and coupled to the vibrational modes by a laser. For Gaussian white noise, a master equation is derived and solved. The results obtained reveal how the effective Rabi frequencies and the decay rates depend on the noise strength and on the number state index. The detection of features specific to magnetic-field noise in the evolution of states that can be prepared under standard experimental conditions is discussed. A comparison with the effects of laser intensity and phase fluctuations is presented. Implications for the realization of logic gates are analyzed.
The angular momentum induced in the bound motion of an electron by an external magnetic field B is evaluated classically and quantum mechanically. The quantum-mechanical model used is one in which the angular momentum is quenched when B=0 so that it is representative of a molecule rather than an atom. The current density and its associated magnetic moment are calculated and discussed. Two different methods are used to solve the first-order perturbation theory equation for the required eigenfunction.