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arXiv:1302.6679 · Physica B Condensed Matter

Electron pairing and evidence of a BCS–BEC crossover in d-wave superconductors

Subrat Kumar Das, Ayan Khan, Saurabh Basu

Published Oct 29, 2012• 1 citation
arXivHTMLPDF
DOI
10.1016/j.physb.2012.10.017

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The condensation of paired fermions into superfluid states changes progressively depending on the coupling strength. At the midpoint of the crossover between Bardeen-Cooper-Schrieffer (BCS) weak-coupling and Bose-Einstein condensate (BEC) strong-coupling limits, paired fermions condensate most robustly, thereby leading to the emergence of a pseudogap due to enhanced pairing fluctuations. In the case of electrons in solids, excessively strong interactions often induce competing electronic orders instead of strong-coupling superconductivity, and experimental comprehension of the pseudogap remains incomplete. In this study, we provide experimental evidence demonstrating the opening of a pseudogap, marking the incipient stage of the BCS-BEC crossover in the organic system $\ensuremath{\kappa}\text{\ensuremath{-}}(\mathrm{BEDT}\text{\ensuremath{-}}{\mathrm{TTF})}_{2}X$. By controlling electron correlations, we investigate the thermodynamic properties of the BCS-BEC crossover and pseudogap phase. Since the superconductivity of $\ensuremath{\kappa}\text{\ensuremath{-}}{(\text{BEDT}\text{\ensuremath{-}}\mathrm{TTF})}_{2}X$ arises from a simple Fermi liquid that does not exhibit any other electronic orders, our study sheds light on the inherent nature of the BCS-BEC crossover.
Physical properties of two-dimensional (2D) superconductors is an active area of long time researches in which many, even principle, questions are still open. One of them is a possibility of a smooth crossover of the system from the standard Bardeen–Cooper–Schrieffer (BCS) regime of strongly overlapping Cooper pairs to the regime of Bose–Einstein condensation (BEC) of almost non-overlapping local pairs. The adequate to the real process description of this transition which can happen either by changing the doping or temperature would lead to a better understanding of the superconducting properties of materials. Though the crossover is not observed in one of the most important layered systems—namely, cuprate superconductors—we demonstrate that in systems with stronger electron-electron attraction it is possible. In particular, in the d-wave channel at sufficiently high doping the crossover can take place with growth of temperature two times, i.e., as BEC→BCS, and followed by reverse BCS→BEC condensation. The physical mechanisms of such transitions and possibility to detect them experimentally in real systems are discussed.