We obtain exact analytic expressions for a class of functions expressed as integrals over the Haar measure of the unitary group in d dimensions. Based on these general mathematical results, we investigate generic dynamical properties of complex open quantum systems, employing arguments from ensemble theory. We further generalize these results to arbitrary eigenvalue distributions, allowing a detailed comparison of typical regular and chaotic systems with the help of concepts from random matrix theory. To illustrate the physical relevance and the general applicability of our results we present a series of examples related to the fields of open quantum systems and nonequilibrium quantum thermodynamics. These include the effect of initial correlations, the average quantum dynamical maps, the generic dynamics of system-environment pure state entanglement and, finally, the equilibration of generic open and closed quantum systems.
We obtain exact analytic expressions for a class of functions expressed as integrals over the Haar measure of the unitary group in d dimensions. Based on these general mathematical results, we investigate generic dynamical properties of complex open quantum systems, employing arguments from ensemble theory. We further generalize these results to arbitrary eigenvalue distributions, allowing a detailed comparison of typical regular and chaotic systems with the help of concepts from random matrix theory. To illustrate the physical relevance and the general applicability of our results we present a series of examples related to the fields of open quantum systems and nonequilibrium quantum thermodynamics. These include the effect of initial correlations, the average quantum dynamical maps, the generic dynamics of system-environment pure state entanglement and, finally, the equilibration of generic open and closed quantum systems.
The question of how statistical physics can be seen to emerge from unitary quantum dynamics goes back to Schrödinger and von Neumann, however has been reaffirmed as a topic of importance due to recent advances in experimental capabilities, allowing the observation of the unitary evolution of many-particle systems over long periods of time. Understanding why such a system evolves to the specific thermal equilibrium state, effectively described by a relevant thermodynamic ensemble, has thus seen significantly more interest in recent years. Furthermore, observations of the dynamics of such systems open questions on the route to equilibrium, and subsequent fluctuations. In this thesis I will develop an approach to this problem, taking as a starting point the non-integrability of the system under study, which leads to a generic model in terms of random matrix theory (RMT), and more generally, chaotic wavefunctions. In the formulation of these methods, special attention is paid to the form of local observables of quantum systems, and an approach to their description is developed in terms of correlation functions of chaotic wavefunctions. From this approach a key conjecture in the understanding of thermalization, the eigenstate thermalization hypothesis (ETH), is derived in full, and the dynamical behaviour of such observables is obtained analytically. Further, I will show that emergent classical behaviour can be observed in the form of a fluctuation-dissipation theorem (FDT) of Brownian processes. This is exploited to develop an experimental proposal to measure the ‘complexity’ of a quantum device, by experimentally obtaining its effective Hilbert space dimension in terms of a fully connected system. Finally, quantum jump trajectories, describing stroboscopic projective measurements of local observables are studied, and shown to display classical Brownian dynamics in the form of a Markov process. Throughout this thesis, exact diagonalization calculations of realistic quantum spin systems are used to confirm analytical results.
We study generic open quantum systems with Markovian dissipation, focusing on a class of stochastic Liouvillian operators of Lindblad form with independent random dissipation channels (jump operators) and a random Hamiltonian. We perform a thorough numerical study, focusing on global spectral features, the spectral gap, and the steady-state purity and statistics. We establish that all properties follow three different regimes as a function of the dissipation strength, whose boundaries depend on the particular observable. Within each regime, we determine the scaling exponents with the dissipation strength and system size. On the analytical side, we compute the average spectral gap at arbitrary dissipation and provide simple closed-form expressions for the asymptotic values at strong and weak dissipation strength. We also consider spectral correlations in generic complex spectra, such as that of the Liouvillian. We introduce and study, both analytically and numerically, the complex ratio of the nearest-neighbor spacing by next-to-nearest-neighbor spacing. Besides the usual level repulsion, we find that complex spacing ratios have a nontrivial angular dependence which offers a distinct signature of quantum chaos. It distinguishes integrable systems, which support the flat ratio distribution characteristic of Poisson statistics, and chaotic dissipative quantum systems, which conform to Random Matrix Theory statistics. We apply this new signature of quantum chaos to random Liouvillians and boundary-driven dissipative spin-chains. The results of this thesis can help understand the long-time dynamics, steady-state properties, and spectral correlations of generic dissipative systems.
Quantum chaos entails an entropic and computational obstruction to describing a system and thus is intrinsically difficult to characterize. An understanding of quantum chaos is fundamentally related to the mechanism of thermalization in many-body systems and the quantum nature of black holes. In this thesis we adopt the view that quantum information theory provides a powerful framework in which to elucidate chaos in strongly-interacting quantum systems. We first push towards a more precise understanding of chaotic dynamics by relating different diagnostics of chaos, studying the time-evolution of random matrix Hamiltonians, and quantifying random matrix behavior in physical systems. We derive relations between out-of-time ordered correlation functions, spectral quantities, and frame potentials to relate the scrambling of quantum information, decay of correlators, and Haar-randomness. We give analytic expressions for these quantities in random matrix theory to explore universal aspects of late-time dynamics. Motivated by our random matrix results, we define k-invariance in order to capture the onset of random matrix behavior in physical systems. We then refine our diagnostics in order to study chaotic systems with symmetry by considering Haar-randomness with respect to quotients of the unitary group, and in doing so we generalize our quantum information machinery. We further consider extended random matrix ensembles in the context of strongly-interacting quantum systems dual to black holes. Lastly, we study operator growth in classes of random quantum circuits.
Recently, the possibility of investigating single molecule, or single spin observables, as well as the necessity of a better understanding of the mechanisms underlying quantum dynamics in order to obtain nanoscale devices and nanostructered materials suitable for quantum computing tasks, have revived the interest in foundational aspects of quantum statistical mechanics. This thesis aims to give a contribution to this field by re-considering the statistical characterization of a quantum system at the light of some paradigmatic changes in our understanding of quantum theory which have taken place in the last two decades. In particular the impressive development of quantum information theory has changed the perceptions of quantum entanglement: for a long time it has been considered a somewhat paradoxical property of the matter at the atomic scale, but now it is regarded as an essential and ubiquitous phenomenon whose consequences are affecting the very macroscopic world that we experience. Still the decoherence program has brought out the importance of considering a quantum system together with its environment in order to clarify some key aspects of quantum dynamics. Thus, we start from the idea that quantum correlations are ubiquitous and somewhat uncontrollable in systems with many degrees of freedom which are typically considered in statistical mechanics. As a consequence we assume the standpoint that quantum statistical mechanics has not to be based on the underlying idea of a collection of many, independent quantum systems but rather it has to emerge at the level of a global wavefunction (pure state) which describes the system as well as its environment as a whole. In order to investigate the consequences of these assumptions we study the equilibrium distribution of an isolated quantum system. This is defined, in analogy with the ergodic foundations of classical statistical mechanics, on the basis of the time evolution of the quantum state. Then, we study the emergence of thermodynamic properties in a quantum system by studying the probability distribution of some function of interests, as the entropy and the equilibrium state of a subsystem, on Ensembles of Pure States. Such a probability distribution is derived from the geometry of the Hilbert space, and the theoretical tools suitable for its characterization are developed. On the one hand we perform a numerical sampling of the ensemble distributions by employing Monte Carlo techniques, on the other hand simpler analytical approximation of the geometrical distributions are derived by means of a maximum entropy principle. Model systems composed of an ensemble of spins are chosen to illustrate the salient features which emerge from the developed theoretical framework: the main point is that the Ensemble Distributions of “thermodynamic observables” (entropy or equilibrium state of a subsystem) are sharply peaked around a typical value. From the analysis it emerges that each of the overwhelming majority of the wavefunctions which has appreciable weight in the considered ensemble, is characterized by the same value of the “macroscopic” functions. This is a striking evidence of the “typicality” of these properties. In the essence, our impossibility to know the state of the system in detail does not matter, just for the remarkable fact that almost all quantum states behave essentially in the same way. By virtue of this typicality the study of the behaviour of the typical values of the thermodynamic function become meaningful. Notably, under certain conditions, one recovers the results of standard statistical mechanics, that is, the equilibrium average of the state of a subsystem can be cast in the Boltzmann canonical form at the temperature given by the usual thermodynamical relation . In the second part of the thesis we consider the dynamical aspects of the equilibrium state of a subsystem interacting with its environment. The fluctuations around the equilibrium average critically depends on the entanglement between the system and the environment and on the form of the interaction Hamiltonian. The connection between the dynamics of the fluctuations of an observable at the equilibrium and the relaxation toward the equilibrium from a “non typical” initial value is also investigated with the aid of simple model systems. The study presented in this thesis was partly motivated by a critical analysis of the statistical methods available for the theoretical modelling of magnetic resonance experiments. One of these, the Stochastic Liouville Equation, has been employed in a work completed during the first year of my Ph.D. program in order to interpret some feature of a two dimensional electron spin resonance experiment, [Fresch B., Frezzato D., Moro G. J., Kothe G., Freed J. H.; J. Phys. Chem. B., 110, 24238, (2006)].
Abstract We consider time-dependent relaxation of observables in quantum systems of chaotic and regular type. Using statistical arguments and exact numerical solutions we show that the spread of the initial wave function in the Hilbert space and the main characteristics of evolution of observables have certain generic features. The study compares examples of regular dynamics, a completely chaotic case of the Gaussian orthogonal ensemble, a bosonic system with random interactions, and a fully realistic case of the time evolution of various initial non-stationary states in the nuclear shell model. In the case of the Gaussian orthogonal ensemble we show that the survival probability obtained analytically also fully defines the relaxation timescale of observables. This is not the case in general. Using the realistic nuclear shell model and the quadrupole moment as an observable we demonstrate that the relaxation time is significantly longer than defined by the survival probability of the initial state. The full analysis does not show the presence of an analog of the Lyapunov exponent characteristic for examples of classical chaos.
The study of generic properties of quantum states has led to an abundance of insightful results.A meaningful set of states that can be efficiently prepared in experiments are ground states of gapped local Hamiltonians, which are well approximated by matrix product states.In this work, we introduce a picture of generic states within the trivial phase of matter with respect to their nonequilibrium and entropic properties.We do so by rigorously exploring nontranslation-invariant matrix product states drawn from a local independent and identically distributed Haar measure.We arrive at these results by exploiting techniques for computing moments of random unitary matrices and by exploiting a mapping to partition functions of classical statistical models, a method that has lead to valuable insights on local random quantum circuits.Specifically, we prove that such disordered random matrix product states equilibrate exponentially well with overwhelming probability under the time evolution of Hamiltonians featuring a nondegenerate spectrum.Moreover, we prove two results about the entanglement Rényi entropy: the entropy with respect to sufficiently disconnected subsystems is generically extensive in the system size, and for small connected systems, the entropy is almost maximal for sufficiently large bond dimensions.