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arXiv:1212.1239 · The European Physical Journal Plus

Entropy of quantum states: Ambiguities

A. P. Balachandran, Amilcar R. de Queiroz, Sachindeo Vaidya

Published Oct 1, 2013• 17 citations
arXivHTMLPDF
DOI
10.1140/epjp/i2013-13112-3

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NOTES ON QUANTUM ENTROPY

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The von Neumann entropy of a generic quantum state is not unique unless the state can be uniquely decomposed as a sum of extremal or pure states. Therefore one reaches the remarkable possibility that there may be many entropies for a given state. We show that this happens if the GNS representation (of the algebra of observables in some quantum state) is reducible, and some representations in the decomposition occur with non-trivial degeneracy. This ambiguity in entropy, which can occur at zero temperature, can often be traced to a gauge symmetry emergent from the non-trivial topological character of the configuration space of the underlying system. We also establish the analogue of an H-theorem for this entropy by showing that its evolution is Markovian, determined by a stochastic matrix. After demonstrating this entropy ambiguity for the simple example of the algebra of 2 × 2 matrices, we argue that the degeneracies in the GNS representation can be interpreted as an emergent broken gauge symmetry, and play an important role in the analysis of emergent entropy due to non-Abelian anomalies. We work out the simplest situation with such non-Abelian symmetry, that of an ethylene molecule.
In a quantum system, there may be many density matrices associated with a state on an algebra of observables. For each density matrix, one can compute its entropy. These are, in general, different. Therefore, one reaches the remarkable possibility that there may be many entropies for a given state [R. Sorkin (private communication)]. This ambiguity in entropy can often be traced to a gauge symmetry emergent from the nontrivial topological character of the configuration space of the underlying system. It can also happen in finite-dimensional matrix models. In the present work, we discuss this entropy ambiguity and its consequences for an ethylene molecule. This is a very simple and well-known system, where these notions can be put to tests. Of particular interest in this discussion is the fact that the change of the density matrix with the corresponding entropy increase drives the system towards the maximally disordered state with maximum entropy, where Boltzman's formula applies. Besides its intrinsic conceptual interest, the simplicity of this model can serve as an introduction to a similar discussion of systems such as colored monopoles and the breaking of color symmetry.
The Categorical Compositional Distributional (DisCoCat) model has been proven to be very successful in modelling sentence meaning as the interaction of word meanings. Words are modelled as quantum states, interacting guided by grammar. This model of language has been extended to density matrices to account for ambiguity in language. Density matrices describe probability distributions over quantum states, and in this work we relate the mixedness of density matrices to ambiguity in the sentences they represent. The von Neumann entropy and the fidelity are used as measures of this mixedness. Via the process of amplitude encoding, we introduce classical data into quantum machine learning algorithms. First, the findings suggest that in quantum natural language processing, amplitude-encoding data onto a quantum computer can be a useful tool to improve the performance of the quantum machine learning models used. Second, the effect that these encoded data have on the above-introduced relation between entropy and ambiguity is investigated. We conclude that amplitude-encoding classical data in quantum machine learning algorithms makes the relation between the entropy of a density matrix and ambiguity in the sentence modelled by this density matrix much more intuitively interpretable.