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arXiv:1209.1401 · Physical Review A

Memory effects in spontaneous emission processes

Arne L. Grimsmo, Asle Heide Vaskinn, Per Kristian Rekdal, Bo-Sture Skagerstam

Published Feb 4, 2013• 11 citations
arXivHTMLPDF

Abstract

We consider a quantum-mechanical analysis of spontaneous emission in terms of an effective two-level system with a vacuum decay rate ${\ensuremath{\Gamma}}_{0}$ and transition angular frequency ${\ensuremath{\omega}}_{A}$. Our analysis is in principle exact, even though presented as a numerical solution of the time evolution including memory effects. The results so obtained are confronted with previous discussions in the literature. In terms of the dimensionless lifetime $\ensuremath{\tau}=t{\ensuremath{\Gamma}}_{0}$ of spontaneous emission, we obtain deviations from exponential decay of the form $O(1/\ensuremath{\tau})$ for the decay amplitude as well as the previously obtained asymptotic behaviors of the form $O(1/{\ensuremath{\tau}}^{2})$ or $O(1/\ensuremath{\tau}{\mathrm{ln}}^{2}\ensuremath{\tau})$ for $\ensuremath{\tau}\ensuremath{\gg}1$. The actual asymptotic behavior depends on the adopted regularization procedure as well as on the physical parameters at hand. We show that for any reasonable range of $\ensuremath{\tau}$ and for a sufficiently large value of the required angular frequency cutoff ${\ensuremath{\omega}}_{c}$ of the electromagnetic fluctuations, i.e., ${\ensuremath{\omega}}_{c}\ensuremath{\gg}{\ensuremath{\omega}}_{A}$, one obtains either a $O(1/\ensuremath{\tau})$ or a $O(1/{\ensuremath{\tau}}^{2})$ dependence. In the presence of physical boundaries, which can change the decay rate with many orders of magnitude, the conclusions remains the same after a suitable rescaling of parameters.

DOI
10.1103/physreva.87.022101

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A mathematically rigorous treatment of the Weisskopf-Wigner model of atomic spontaneous emission is presented. For the first time to the authors' knowledge, it is shown that in the correct asymptotic treatment with a cutoff frequency at which the dipole approximation breaks down, the main contribution to the long-time deviation from the exponential decay is of the order of 1/(t ln2{\mathrm{ln}}^{2}ln2t). This contradicts the results of previous authors who have obtained a long-time behavior of the order of 1/t2{t}^{2}t2 by nonrigorous mathematical treatment of the same model in the dipole approximation. However, we will show that the result 1/t2{t}^{2}t2 can still be obtained if the retardation effects are taken into account, i.e., if no dipole approximation is made.
In the frames of quantum electrodynamics, the behavior of spontaneous decay is investigated for a single two-level atom embedded into a microscopic object (cluster). The transition frequency of cluster atoms is supposed to be considerably detuned from the transition frequency of decaying atom. The consideration is performed on the base of fully microscopic quantum-electrodynamical approach with simultaneous solution of Heisenberg equations for atomic and quantum field operators. The special attention is paid to the investigation of renormalization of spontaneous emission rate due to proper account of discrete structure of medium. The formula for decay rate is obtained without using the notion of refractive index. It is obtained that spontaneous decay strongly depends on the geometrical arrangement of atoms in microstructure. For some form of clusters, decay rate is found to be considerably large compared to its vacuum value that is not the case for macroscopically large dielectrics.
A critical examination of the theory of resonance radiation has been carried through, employing the mathematical technique of Laplace and Stieltjes transforms. Particular attention has been devoted to the question of the temporal behavior of the excited state. With no restrictions on the interaction between atom and radiation field other than that it be real, and that processes of sufficiently high frequency contribute only negligible effects, one can prove that the probability amplitude of the excited state cannot decay according to the general law ${\ensuremath{\Sigma}}_{\ensuremath{\mu},\ensuremath{\nu}}{C}_{\ensuremath{\mu}\ensuremath{\nu}}{t}^{{\ensuremath{\lambda}}_{\ensuremath{\mu}}}{e}^{\ensuremath{-}{\ensuremath{\beta}}_{\ensuremath{\nu}}t},$ where the ${\ensuremath{\lambda}}_{\ensuremath{\mu}}$ and ${\ensuremath{\beta}}_{\ensuremath{\nu}}$ are complex constants lying in the right half-plane and the ${C}_{\ensuremath{\mu}\ensuremath{\nu}}$ are arbitrary complex coefficients. The deviation from the law just cited can be termed a straggling phenomenon since exact analysis shows that the probability amplitude, for sufficiently long times, is greater than that defined according to the radioactive decay law.Rigorous analysis of the source of this apparently anomalous behavior reveals the following explanation. Although the probability amplitude of the excited state is, strictly speaking, a functional of the interaction between the transition current in the atom and the photon states of the electromagnetic field, the essential features are determined principally by those states lying near the resonance frequency. Three elementary observations are immediately apparent. First, a particularly tractable analytical approximation for the interaction can be made such that the value of the actual interaction is reproduced at the resonance frequency and such that the behavior for high and low frequency photon states is at least qualitatively correct. Exact solutions in closed form can be obtained for this interaction. Second, in terms of the preceding representation it is possible to show that, associated with the transition between two atomic states, one is presented with a concomitant picture of a damped oscillation of charge describable in purely classical terms. Third, this classical motion can be interpreted as forming a source function for a continuous stochastic process in terms of which one finally derives the representation of the probability amplitude of the excited state. The straggling phenomenon previously cited is therefore that associated with all diffusion processes. The consideration of the exact interaction leads to more involved diffusion phenomena but does not in any case permit a radioactive decay law.
We revisit the problem of spontaneous emission by a two-level system in a cavity, concentrating in particular on those aspects associated with the finite propagation time of light between the atom and the cavity boundaries. We find that spontaneous emission always occurs first at the free space rate and there is then an abrupt change in these dynamics when light reflected by the cavity mirrors returns to the atom, leading to interference effects that result either in an enhancement or a reduction of this rate or in a periodic exchange of excitation between the atom and the cavity field. From this point of view, reversible spontaneous emission in terms of single-mode ``vacuum Rabi oscillations'' can be interpreted as resulting from the interference between the multimode partial waves reflected at the cavity mirrors and the instantaneously radiated light. \textcopyright{} 1996 The American Physical Society.
It has been shown for various systems that the decay rate of an unstable quantum system deviates from exponential behavior in short- and long-time regimes associated with memory effects. In particular, it is widely believed that in the short-time regime, the decay is quadratic, inducing the quantum Zeno effect, in which the decay is suppressed by rapidly repeated measurements. In our study, we find that when the environment of the unstable system has an energy spectrum with a lower bound but without an upper one, the decay rate in both regimes is scaled in terms of the spatial dimension and the exponent of the energy dispersion of the environment. Surprisingly, we find that in the short-time regime the decay exhibits fractional scaling, which leads to a quantum Zeno effect with a different scaling of the Zeno time.
The spontaneous decay of an excited atom by photon emission is one of the most common and elementary physical process present in nature and in laboratories. The decay is random in time with constant probability density, as it can be inferred by the exponential law observed experimentally. Despite the simplicity of the process, in Quantum Mechanics the decay itself is considered a law of nature which is not further analyzed or explained. However it is legitimate to ask for the reason of its randomness and for the dynamics of the atom around the decay. The decay process of an isolated atom is usually assumed to be instantaneous, the so called Quantum jumps. Particular experimental arrangements can widen the duration of the transition from an excited state to the ground state to a finite time. In general this is due to the quantum back action of the detector. The development of Quantum Optics has enormously enriched the possibilities to study in detail the process, and new illuminating insights have been obtained, but the question is still valid and its answer is still elusive. In this paper we analyze the spontaneous decay within the new prospect introduced by a recent model that complete standard Quantum Mechanics in a formalism which is able to describe the dynamics of measurement and of spontaneous decay. Comparison is made with more phenomenological theories, the Quantum Mechanics of open system and the Stochastic wave function model. In the new model the stochastic photon emission by an excited atom is triggered by the vacuum fluctuations. It is suggested how to re-analyze three types of experiments, already realized in many laboratories, in order to reveal the presence and the effect of these fluctuations.