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arXiv:1204.5559

Using Temporal Entanglement to Perform Thermodynamical Work

Vlatko Vedral

Published Apr 25, 2012• 3 citations
arXivHTMLPDF

Abstract

Here we investigate the impact of temporal entanglement on a system's ability to perform thermodynamical work. We show that while the quantum version of the Jarzynski equality remains satisfied even in the presence of temporal entanglement, the individual thermodynamical work moments in the expansion of the free energy are, in fact, sensitive to the genuine quantum correlations. Therefore, while individual moments of the amount of thermodynamical work can be larger (or smaller) quantumly than classically, when they are all combined together into the (exponential of) free energy, the total effect vanishes to leave the Jarzynski equality intact. Whether this is a fortuitous coincidence remains to be seen, but it certainly goes towards explaining why the laws of thermodynamics happen to be so robust as to be independent of the underlying micro-physics. We discuss the relationship between this result and thermodynamical witnesses of spatial entanglement as well as explore the subtle connection with the "quantum arrow of time".

DOI
10.48550/arxiv.1204.5559

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Here we investigate the impact of temporal entanglement on a system's ability to perform thermodynamical work. We show that while the quantum version of the Jarzynski equality remains satisfied even in the presence of temporal entanglement, the individual thermodynamical work moments in the expansion of the free energy are, in fact, sensitive to the genuine quantum correlations. Therefore, while individual moments of the amount of thermodynamical work can be larger (or smaller) quantumly than classically, when they are all combined together into the (exponential of) free energy, the total effect vanishes to leave the Jarzynski equality intact. Whether this is a fortuitous coincidence remains to be seen, but it certainly goes towards explaining why the laws of thermodynamics happen to be so robust as to be independent of the underlying micro-physics. We discuss the relationship between this result and thermodynamical witnesses of spatial entanglement as well as explore the subtle connection with the "quantum arrow of time".
We first derive the Jarzynski relation [1] between the average exponential of the thermodynamical work and the exponential of the difference between the initial and final free energy. We then comment on the information-theoretic underpinning of Jarzynski’s reasoning which helps explain why the Jarzynski relation holds identically both quantumly and classically [2]. We then present a scheme to verify the quantum non-equilibrium fluctuation relations as encapsulated by Jarzynski. We show that the characteristic function of the work distribution of a quantum system (which is basically equal to the Wick rotated average exponential of the thermodynamical work) can be extracted from Ramsey interferometry of a single probe qubit (which need not itself be pure, though it must not be fully depolarized) [3,4].We first derive the Jarzynski relation [1] between the average exponential of the thermodynamical work and the exponential of the difference between the initial and final free energy. We then comment on the information-theoretic underpinning of Jarzynski’s reasoning which helps explain why the Jarzynski relation holds identically both quantumly and classically [2]. We then present a scheme to verify the quantum non-equilibrium fluctuation relations as encapsulated by Jarzynski. We show that the characteristic function of the work distribution of a quantum system (which is basically equal to the Wick rotated average exponential of the thermodynamical work) can be extracted from Ramsey interferometry of a single probe qubit (which need not itself be pure, though it must not be fully depolarized) [3,4]. An interesting fact is that while the quantum version of the Jarzynski equality remains satisfied even in the presence of quantum correlations, the individual thermodynamical work moments in the expansion of the free energy are, in fact, sensitive to the genuine quantum correlations [5]. Whether this is a fortuitous coincidence remains to be seen, but it certainly goes towards explaining why the laws of thermodynamics happen to be so robust as to be independent of the underlying micro-physics.We intend to elucidate the subtle connection between Jarzynski’s relation and the “quantum arrow of time”. Finally we comment on the fact that our scheme for measuring the quantum work characteristic function belongs to the computational class known as DCQ1 [6], namely all computations that can be performed with only one pure qubit (and N maximally mixed ones).
The concept of time presents a profound challenge at the intersection of quantum mechanics and thermodynamics. While fundamental microscopic laws are largely time-symmetric, macroscopic phenomena universally exhibit a distinct thermodynamic arrow of time, characterized by increasing entropy. This paper explores the hypothesis that quantum entanglement plays a crucial role in the emergence of this thermodynamic arrow. We review how the entanglement between a quantum system and its environment leads to decoherence, effectively driving the system towards a state of higher entropy and classical-like behavior. By analyzing concepts such as von Neumann entropy, entanglement entropy, and the Page-Wootters mechanism, we propose a theoretical framework where the degradation and spreading of entanglement act as the underlying mechanism for the perceived unidirectional flow of time. This approach offers a potential resolution to the "problem of time" in quantum gravity and provides a unified perspective on the genesis of irreversibility from the inherently reversible laws of quantum mechanics. We discuss the implications of this entanglement-driven temporal emergence for our understanding of the universe's initial low-entropy state and the fundamental nature of reality.
I give an explanation of the thermodynamic arrow-of-time (namely entropy increases with time) within a quantum mechanical framework. This entails giving a solution to the Loschmidt paradox, i.e. showing how an irreversible macro-dynamics can arise from a reversible micro-dynamics. I argue that, in accordance to the reversible dynamics, both entropy-increasing and entropy-decreasing transformations take place, but entropy-decreasing transformations cannot leave any information of their having happened. This is indistinguishable from their not having happened at all. The second law of thermodynamics is then reduced to a tautology: the only transformations that can be seen are those where entropy does not decrease. However, typicality arguments seem to prevent this argument to be used as a complete solution to the arrow-of-time dilemma: it might still be necessary to postulate a low entropy initial state for the system under consideration.
We discuss quantum entanglement in the context of the thermodynamic arrow of time. We review the role of correlations in entropy-decreasing events and prove that the occurrence of a transformation between two thermodynamic states constitutes a new type of entanglement witness, one not defined as a separating plane in state space between separable and entangled states, but as a physical process dependent on the local initial properties of the states. Extending work by Partovi, we consider a general entangled multipartite system that allows large reversals of the thermodynamic arrow of time. We describe a hierarchy of arrows that arises from the different correlations allowed in a quantum state and examine these features in the context of Maxwell's Demon. We examine in detail the case of three qubits, and also propose some simple experimental demonstrations possible with small numbers of qubits.
This work investigates the fundamental connection between quantum mechanics and thermodynamics through the concept of the arrow of time. While the second law of thermodynamics identifies the arrow of time with the monotonic increase of entropy in isolated systems, closed quantum systems evolve unitarily and conserve von Neumann entropy, making the origin of irreversibility less apparent. Here we establish a no-go theorem proving that correlations in unknown states of closed quantum systems cannot be universally removed by any physical operation. This result demonstrates that correlation generation is inherently irreversible, providing a microscopic and universal basis for the arrow of time. In thermodynamic settings, this irreversibility ensures that heat flows spontaneously from hotter to colder subsystems, reproducing the Clausius formulation of the second law. More generally, the irreversible growth of correlations explains entropy increase, the approach to equilibrium, and decoherence as observable manifestations of the same principle. Our findings ground a quantum-mechanical foundation for the second law of thermodynamics and demonstrate the universality of the arrow of time.
The role of quantum entanglement in thermodynamical systems remains elusive. Does entanglement result in thermodynamic advantages or does it impose fundamental limitations? Here, we unambiguously quantify the amount of heat and work in a quantum system that is due to the presence of entanglement. This is achieved by constraining the system's non-equilibrium dynamics to separable states, thereby isolating the impact entanglement has on thermodynamic effects. Unlike thermodynamic entanglement measures, which signify a loose connection between entanglement and thermodynamic properties, imposing a constraint constitutes an active intervention into a system -- answering how much of a system's thermodynamics is caused by (not correlated with) its quantumness. We benchmark our theory by applying the constrained dynamics to several multipartite systems, including quantum batteries and quantum refrigerators.