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arXiv:1202.0201 · Physical Chemistry Chemical Physics

Decoherence effects on superpositions of chiral states in a chiral molecule

M. Bahrami, A. Shafiee, Angelo Bassi

Published Jan 1, 2012• 12 citations
arXivHTMLPDF

Abstract

The superposition of chiral states of chiral molecules, as delocalized quantum states of a many-particle system, can be used for the experimental investigations of decoherence theory. In this regard, a great challenge is the precise quantification of the robustness of these superpositions against environmental effects. The methods so far proposed need the detailed specification of the internal states of the molecule, usually requiring heavy numerical calculations. Here, by using the linearized quantum Boltzmann equation and by borrowing ideas employed for analyzing other quantum systems, we present a general and simple approach, of wide applicability, which can be used to compute the dominant contribution to the decoherence rate for the superpositions of chiral states of chiral molecules, due to environmental scattering.

DOI
10.1039/c2cp40920h

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The superposition of chiral states of chiral molecules, as delocalized quantum states of a many-particle system, can be used for the experimental investigations of decoherence theory. In this regard, a great challenge is the precise quantification of the robustness of these superpositions against environmental effects. The methods so far proposed need the detailed specification of the internal states of the molecule, usually requiring heavy numerical calculations. Here, by using the linearized quantum Boltzmann equation and by borrowing ideas employed for analyzing other quantum systems, we present a general and simple approach, of wide applicability, which can be used to compute the dominant contribution to the decoherence rate for the superpositions of chiral states of chiral molecules, due to environmental scattering.
In this paper we investigate the effect of many Rayleigh scattering events on decoherence of superpositions of chiral states of a molecule, by taking these events as measurement-like interactions in the sense that the scattered photon state depends on the state of the molecule—both its centre-of-mass position and its chirality. This gives rise to two contributions to decoherence: one due to the position measurement and the other due to the chirality measurement. It is found that under identical conditions, the decoherence timescale for chiral molecules can be different from that for achiral molecules depending on the chiral sensitivity of scattering.
We study the tunnel dynamics of a chiral molecule between its left (L) and right (R) conformations, under the global effect of collisional decoherence together with the effect of a mean-field generated by the environment where an energetic difference, K, between homochiral and heterochiral interactions is assumed. We show that this decoherence leads unavoidably to equal populations of the L and R chiral conformations even for a high enough value of K which tends to keep localized an initial chiral state. However, we also show that K contributes to the stabilization of an initial L or R state for times that could be many orders of magnitude larger than the tunneling time, in the case the decoherence rate is much greater than the tunneling rate. In this case, an estimation of this stabilization time and a critical tunneling time is made. Even in the case in which the tunneling rate is greater than the decoherence rate, the effect of K is to keep localized the initial chiral state for times greater than the tunneling time. A possible slight chiral asymmetry is also considered.
The decoherence of a two-state tunneling molecule, such as a chiral molecule or ammonia, due to collisions with a buffer gas is analyzed in terms of a succession of quantum states of the molecule satisfying the conditions for a consistent family of histories. With $\ensuremath{\hbar}\ensuremath{\omega}$ the separation in energy of the levels in the isolated molecule and $\ensuremath{\gamma}$ a decoherence rate proportional to the rate of collisions, we find for $\ensuremath{\gamma}\ensuremath{\gg}\ensuremath{\omega}$ (strong decoherence) a consistent family in which the molecule flips randomly back and forth between the left- and right-handed chiral states in a stationary Markov process. For $\ensuremath{\gamma}<\ensuremath{\omega}$ there is a family in which the molecule oscillates continuously between the different chiral states, but with occasional random changes of phase, at a frequency that goes to zero at a phase transition $\ensuremath{\gamma}=\ensuremath{\omega}$. This transition is similar to the behavior of the inversion frequency of ammonia with increasing pressure, but will be difficult to observe in chiral molecules such as D2{}_{2}2​S2{}_{2}2​. There are additional consistent families both for $\ensuremath{\gamma}>\ensuremath{\omega}$ and for $\ensuremath{\gamma}<\ensuremath{\omega}$. In addition, we relate the speed with which chiral information is transferred to the environment to the rate of decrease of complementary types of information (e.g., parity information) remaining in the molecule itself.
This paper presents a comprehensive model for quantum decoherence, grounded in the principles of quantum field theory (QFT) and statistical mechanics. The core argument is that traditional decoherence models often oversimplify the process, failing to adequately capture the intricate interactions arising from the quantum effects of the surrounding environment. This work introduces a framework that explicitly incorporates the scattering of quantum states by the environment, treated as a QFT system, and then analyzes the resultant impact using statistical mechanics. The model aims to provide a more accurate and nuanced understanding of decoherence, particularly in scenarios involving strong environmental interactions. Specifically, the model utilizes the formalism of quantum scattering theory to describe the interaction between a quantum system and its environment. The resulting dynamics are then analyzed using the framework of statistical mechanics, allowing for the calculation of decoherence rates as a function of environmental parameters such as temperature and density. The key contributions of this work include a detailed mathematical description of the decoherence process, a clear separation of the quantum and classical aspects of the problem, and a framework for extending the model to more complex systems. The model predicts that decoherence is not simply a loss of quantum information, but rather a fundamental process of state transformation driven by the statistical properties of the environment. This work offers a significant step forward in our ability to understand and potentially mitigate the effects of decoherence in quantum technologies.
This paper is a straightforward generalization of Maierle-Harris proposal regarding parity implications on the superpositions of chiral states of a molecule. It is shown that the inclusion of electric quadrupole and magnetic dipole interactions removes several of restrictions on the preparation of superpositions of mid R:L and mid R:R states of a chiral molecule. It is also found that the dephasing of mid R:L and mid R:R superpositions, due to the spontaneous emission from the chiral molecule, has opposing contributions from electric quadrupole-magnetic dipole and electric dipole interactions.