Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:1201.5184 · Physical Review B

Vibrational exciton mediated quantum state transfer: Simple model

Vincent Pouthier

Published Jun 14, 2012• 16 citations
arXivHTMLPDF

Abstract

A communication protocol is proposed in which quantum state transfer is mediated by a vibrational exciton. We consider two distant molecular groups grafted on the sides of a one-dimensional lattice. These groups behave as two quantum computers where the information in encoded and received. The lattice plays the role of a communication channel along which the exciton propagates and interacts with a phonon bath. Special attention is paid to describing the system involving an exciton dressed by a single phonon mode. The Hamiltonian is thus solved exactly so that the relevance of the perturbation theory is checked. Within the nonadiabatic weak-coupling limit, it is shown that the system supports three quasidegenerate states that define the relevant paths followed by the exciton to tunnel between the computers. When the model parameters are judiciously chosen, constructive interferences take place between these paths. Phonon-induced decoherence is minimized and a high-fidelity quantum state transfer occurs over a broad temperature range.

DOI
10.1103/physrevb.85.214303

Related papers

Vibrational exciton-mediated quantum state transfert: a simple model

Vincent Pouthier

A communication protocol is proposed in which quantum state transfer is mediated by a vibrational exciton. We consider two distant molecular groups grafted on the sides of a lattice. These groups behave as two quantum computers where the information in encoded and received. The lattice plays the role of a communication channel along which the exciton propagates and interacts with a phonon bath. Special attention is paid for describing the system involving an exciton dressed by a single phonon mode. The Hamiltonian is thus solved exactly so that the relevance of the perturbation theory is checked. Within the nonadiabatic weak-coupling limit, it is shown that the system supports three quasi-degenerate states that define the relevant paths followed by the exciton to tunnel between the computers. When the model parameters are judiciously chosen, constructive interferences take place between these paths. Phonon-induced decoherence is minimized and a high-fidelity quantum state transfer occurs over a broad temperature range.

•Jan 24, 2012•0 citations

Vibrons in finite size molecular lattices: a route for high-fidelity quantum state transfer at room temperature

Vincent Pouthier

A communication protocol is proposed in which vibron-mediated quantum state transfer takes place in a molecular lattice. We consider two distant molecular groups grafted on each side of the lattice. These groups form two quantum computers where vibrational qubits are implemented and received. The lattice defines the communication channel along which a vibron delocalizes and interacts with a phonon bath. Using quasi-degenerate perturbation theory, vibron-phonon entanglement is taken into account through the effective Hamiltonian concept. A vibron is thus dressed by a virtual phonon cloud whereas a phonon is clothed by virtual vibronic transitions. It is shown that three quasi-degenerate dressed states define the relevant paths followed by a vibron to tunnel between the computers. When the coupling between the computers and the lattice is judiciously chosen, constructive interference takes place between these paths. Phonon-induced decoherence is minimized and a high-fidelity quantum state transfer occurs over a broad temperature range.

Journal of Physics Condensed Matter•Oct 9, 2012•13 citations

Excitonic coherence in a confined lattice: A simple model to highlight the relevance of perturbation theory

Vincent Pouthier

The exciton-phonon system in a confined environment is revisited within standard perturbation theory. Special attention is paid to describing the time evolution of the excitonic coherences at finite temperature. To proceed, the system involving an exciton dressed by a single phonon mode is considered. Owing to its simplicity, it is solved exactly so that the relevance of the perturbation theory is checked. Within the nonadiabatic weak-coupling limit, it is shown that several time scales govern the coherence dynamics. In the short-time limit, the coherences behave as if the exciton was insensitive to the phonon bath. Then, quantum decoherence takes place. Finally the coherences recur almost periodically at specific revival times. Coherence decay and revival strongly depend on the nature of the excitonic states. In particular, for odd lattice sizes, the coherence of the state exactly located at the band center survives over a very long-time scale. Therefore, confinement-induced decoherence softening favors high-fidelity quantum-state transfer and allows to encode the information on a quantum bit almost insensitive to quantum decoherence.

Physical Review B•Feb 22, 2011•11 citations

Quantum simulation of charge and exciton transfer in multi-mode models using engineered reservoirs

Visal So, Midhuna Duraisamy Suganthi, Mingjian Zhu +7 more

Abstract Quantum simulation offers a route to study open-system molecular dynamics in non-perturbative regimes by programming the interactions among electronic, vibrational, and environmental degrees of freedom on similar energy scales. Trapped-ion systems possess this capability, with their native spins, phonons, and tunable dissipation integrated within a single platform. Here, we demonstrate an open-system quantum simulation of charge and exciton transfer in a multi-mode linear vibronic coupling model. Employing tailored spin-phonon interactions alongside reservoir engineering techniques, we emulate a system with two dissipative vibrational modes coupled to donor and acceptor electronic sites and follow its non-equilibrium dynamics. We continuously tune the system from the charge transfer (CT) regime to the vibrationally assisted exciton transfer (VAET) regime by controlling the vibronic coupling strengths. We find that degenerate modes enhance CT and VAET rates at large energy gaps, while non-degenerate modes activate slow-mode pathways that reduce the energy-gap dependence, thus enlarging the window for efficient transfer. These results show that the presence of one additional vibration introduces interfering vibrationally assisted pathways and reshapes non-perturbative quantum excitation transfer. Our work establishes a scalable route to simulating chemically relevant, many-mode vibronic processes with engineered environments, guiding the design of next-generation organic photovoltaics and molecular electronics.

arXiv:2505.22729•Nature Communications•Dec 5, 2025•5 citations

Environment-mediated quantum state transfer

Yue Yin, S N Evangelou

We propose a scheme for quantum state transfer (QST) between two qubits, which is based on their individual interaction with a common boson environment. The corresponding single-mode spin-boson Hamiltonian is solved by mapping it into a wave propagation problem in a semi-infinite ladder and the fidelity is obtained. High fidelity occurs when the qubits are equally coupled to the boson while the fidelity becomes smaller for nonsymmetric couplings. The complete phase diagram for such an arbitrary QST mediated by bosons is discussed.

arXiv:0706.4410•Journal of Physics A Mathematical and Theoretical•Feb 12, 2008•1 citation

Dynamics of elastic and inelastic energy transfer between quantum dots in a microcavity

Kaijie Xu, Carlo Piermarocchi

We develop a theory of exciton energy transfer dynamics between two quantum dots in a planar microcavity. We study the dynamics of quantum dot excitons in three different cases: (i) a single dot coupled only to cavity modes, (ii) two dots coupled to cavity modes, and (iii) two dots coupled to cavity modes and to acoustic phonons. In the latter case, we focus on the process of phonon-assisted inelastic exciton energy transfer between the quantum dots. We take into account phonon effects by introducing a light-matter Hamiltonian with operators describing the exciton-photon-phonon coupling and we truncate the Hilbert space by assuming that at most one excitation is present in the system. Using this approach we simulate the exciton dynamics with realistic parameters in the zero temperature limit. From the dynamics we extract the dependence of the characteristic energy transfer rate as a function of the interdot separation. This theoretical approach can be used to optimize exciton energy transfer by designing structures with engineered photon and phonon density of states.

Physical Review B•Sep 21, 2011•8 citations
A communication protocol is proposed in which quantum state transfer is mediated by a vibrational exciton. We consider two distant molecular groups grafted on the sides of a one-dimensional lattice. These groups behave as two quantum computers where the information in encoded and received. The lattice plays the role of a communication channel along which the exciton propagates and interacts with a phonon bath. Special attention is paid to describing the system involving an exciton dressed by a single phonon mode. The Hamiltonian is thus solved exactly so that the relevance of the perturbation theory is checked. Within the nonadiabatic weak-coupling limit, it is shown that the system supports three quasidegenerate states that define the relevant paths followed by the exciton to tunnel between the computers. When the model parameters are judiciously chosen, constructive interferences take place between these paths. Phonon-induced decoherence is minimized and a high-fidelity quantum state transfer occurs over a broad temperature range.
A communication protocol is proposed in which quantum state transfer is mediated by a vibrational exciton. We consider two distant molecular groups grafted on the sides of a lattice. These groups behave as two quantum computers where the information in encoded and received. The lattice plays the role of a communication channel along which the exciton propagates and interacts with a phonon bath. Special attention is paid for describing the system involving an exciton dressed by a single phonon mode. The Hamiltonian is thus solved exactly so that the relevance of the perturbation theory is checked. Within the nonadiabatic weak-coupling limit, it is shown that the system supports three quasi-degenerate states that define the relevant paths followed by the exciton to tunnel between the computers. When the model parameters are judiciously chosen, constructive interferences take place between these paths. Phonon-induced decoherence is minimized and a high-fidelity quantum state transfer occurs over a broad temperature range.
A communication protocol is proposed in which vibron-mediated quantum state transfer takes place in a molecular lattice. We consider two distant molecular groups grafted on each side of the lattice. These groups form two quantum computers where vibrational qubits are implemented and received. The lattice defines the communication channel along which a vibron delocalizes and interacts with a phonon bath. Using quasi-degenerate perturbation theory, vibron-phonon entanglement is taken into account through the effective Hamiltonian concept. A vibron is thus dressed by a virtual phonon cloud whereas a phonon is clothed by virtual vibronic transitions. It is shown that three quasi-degenerate dressed states define the relevant paths followed by a vibron to tunnel between the computers. When the coupling between the computers and the lattice is judiciously chosen, constructive interference takes place between these paths. Phonon-induced decoherence is minimized and a high-fidelity quantum state transfer occurs over a broad temperature range.
The exciton-phonon system in a confined environment is revisited within standard perturbation theory. Special attention is paid to describing the time evolution of the excitonic coherences at finite temperature. To proceed, the system involving an exciton dressed by a single phonon mode is considered. Owing to its simplicity, it is solved exactly so that the relevance of the perturbation theory is checked. Within the nonadiabatic weak-coupling limit, it is shown that several time scales govern the coherence dynamics. In the short-time limit, the coherences behave as if the exciton was insensitive to the phonon bath. Then, quantum decoherence takes place. Finally the coherences recur almost periodically at specific revival times. Coherence decay and revival strongly depend on the nature of the excitonic states. In particular, for odd lattice sizes, the coherence of the state exactly located at the band center survives over a very long-time scale. Therefore, confinement-induced decoherence softening favors high-fidelity quantum-state transfer and allows to encode the information on a quantum bit almost insensitive to quantum decoherence.
Abstract Quantum simulation offers a route to study open-system molecular dynamics in non-perturbative regimes by programming the interactions among electronic, vibrational, and environmental degrees of freedom on similar energy scales. Trapped-ion systems possess this capability, with their native spins, phonons, and tunable dissipation integrated within a single platform. Here, we demonstrate an open-system quantum simulation of charge and exciton transfer in a multi-mode linear vibronic coupling model. Employing tailored spin-phonon interactions alongside reservoir engineering techniques, we emulate a system with two dissipative vibrational modes coupled to donor and acceptor electronic sites and follow its non-equilibrium dynamics. We continuously tune the system from the charge transfer (CT) regime to the vibrationally assisted exciton transfer (VAET) regime by controlling the vibronic coupling strengths. We find that degenerate modes enhance CT and VAET rates at large energy gaps, while non-degenerate modes activate slow-mode pathways that reduce the energy-gap dependence, thus enlarging the window for efficient transfer. These results show that the presence of one additional vibration introduces interfering vibrationally assisted pathways and reshapes non-perturbative quantum excitation transfer. Our work establishes a scalable route to simulating chemically relevant, many-mode vibronic processes with engineered environments, guiding the design of next-generation organic photovoltaics and molecular electronics.
We propose a scheme for quantum state transfer (QST) between two qubits, which is based on their individual interaction with a common boson environment. The corresponding single-mode spin-boson Hamiltonian is solved by mapping it into a wave propagation problem in a semi-infinite ladder and the fidelity is obtained. High fidelity occurs when the qubits are equally coupled to the boson while the fidelity becomes smaller for nonsymmetric couplings. The complete phase diagram for such an arbitrary QST mediated by bosons is discussed.
We develop a theory of exciton energy transfer dynamics between two quantum dots in a planar microcavity. We study the dynamics of quantum dot excitons in three different cases: (i) a single dot coupled only to cavity modes, (ii) two dots coupled to cavity modes, and (iii) two dots coupled to cavity modes and to acoustic phonons. In the latter case, we focus on the process of phonon-assisted inelastic exciton energy transfer between the quantum dots. We take into account phonon effects by introducing a light-matter Hamiltonian with operators describing the exciton-photon-phonon coupling and we truncate the Hilbert space by assuming that at most one excitation is present in the system. Using this approach we simulate the exciton dynamics with realistic parameters in the zero temperature limit. From the dynamics we extract the dependence of the characteristic energy transfer rate as a function of the interdot separation. This theoretical approach can be used to optimize exciton energy transfer by designing structures with engineered photon and phonon density of states.