The uncertainty relation based on the Shannon entropies of the probability densities in position and momentum spaces is improved for quantum systems in arbitrary D -dimensional spherically symmetric potentials. To find this, we have used the L p – L q norm inequality of De Carli and the logarithmic uncertainty relation for the Hankel transform of Omri. Applications to some relevant three-dimensional central potentials are shown.
The uncertainty relation based on the Shannon entropies of the probability densities in position and momentum spaces is improved for quantum systems in arbitrary D -dimensional spherically symmetric potentials. To find this, we have used the L p – L q norm inequality of De Carli and the logarithmic uncertainty relation for the Hankel transform of Omri. Applications to some relevant three-dimensional central potentials are shown.
The Rényi and Shannon entropies are information-theoretic measures, which have enabled to formulate the position–momentum uncertainty principle in a much more adequate and stringent way than the (variance-based) Heisenberg-like relation. Moreover, they are closely related to various energetic density functionals of quantum systems. Here we derive upper bounds on these quantities in terms of the second-order moment 〈r2〉 for general central potentials. This improves previous results of this type. The proof uses the Rényi maximization procedure with a covariance constraint due to Costa et al. [in Proceedings of the Fourth International Workshop on Energy Minimization Methods in Computer Vision and Pattern Recognition (EMMCVPR), edited by A. Rangarajan, M. A. T. Figueiredo, and J. Zerubia (Springer-Verlag, Lisbon, 2003), [Lect. Notes Comput. Sci. 52, 211 (2003).]] The contributions to these bounds coming from the radial and angular parts of the physical wave functions are taken into account. Finally, the application to the d-dimensional (d ⩾ 3) hydrogenic and oscillator-like systems is provided.
The spreading of the stationary states of the multidimensional single-particle systems with a central potential is quantified by means of Heisenberg-like measures (radial and logarithmic expectation values) and entropy-like quantities (Fisher, Shannon, Rényi) of position and momentum probability densities. Since the potential is assumed to be analytically unknown, these dispersion and information-theoretical measures are given by means of inequality-type relations which are explicitly shown to depend on dimensionality and state's angular hyperquantum numbers. The spherical-symmetry and spin effects on these spreading properties are obtained by use of various integral inequalities (Daubechies-Thakkar, Lieb-Thirring, Redheffer-Weyl, ...) and a variational approach based on the extremization of entropy-like measures. Emphasis is placed on the uncertainty relations, upon which the essential reason of the probabilistic theory of quantum systems relies.
The Fisher information functional occupies a very special position among the uncertainty measures of quantum systems of any dimensionality. In contrast with (global) entropic measures of Shannon, Renyi or Tsallis types, it contitutes a local measure in the sense that it is sensitive to the oscillatory character of the probability density distribution. Moreover, the Fisher information is closely related to various macroscopic properties of the system described by different density functionals. Here, we review its main analytical properties such as, inequality-based relationships with some radial expectation values and its uncertainty relation. Tighter versions of these inequalities are shown for those systems subject to an arbitrary central potential. Moreover, the Fisher information is computed for D-dimensional hydrogenic systems explicitly in terms of the radial and angular hyperquantum numbers characterizing the quantum states of the system in both position and momentum spaces. Finally, the utility of this quantity is discussed for various physico-chemical processes of recent interest: Abstraction and nucleophilic substitution reactions.
The purpose of this article is to calculate the numerical values of the Shannon (S) and Fisher (I) information entropies along with their Shannon power (J) and Fisher-Shannon product (P) for a free particle in three dimensions. In both coordinate and momentum space, the numerical values have been calculated for various values of the cubical box's length (L). Further, the validity of the entropic uncertainty relations such as the Bialynicki-Birula and Myceilski (BBM) inequality relation, Stam-Cramer-Rao inequalities (better known as the Fisher based uncertainty relation) and the Fisher-Shannon product relation have been investigated. The Fisher-Shannon product has been introduced and analyzed, which can be considered as a new correlation measure. The article is basically based on the concept, measurements and on the behaviour of the Shannon entropy, Fisher information entropy, Shannon power and the Fisher-Shannon product. Here, the plane wave solution of the free particle in three dimensions is considered and the wave function is normalized in an arbitrarily large but finite cube. The Fourier transforms of the coordinate space wave function provided the momentum space wave function. The probability densities corresponding to the respective wave functions have been employed to compute the numerical values of the information theoretic quantities such as Shannon entropy, Fisher entropy, Shannon power and the Fisher-Shannon product both in the coordinate and momentum space and the computed values have been presented in the respective tables. Finally, the entropic uncertainty relations investigated have been found consistently satisfying the corresponding inequalities such as Bialynicki-Birula and Mycielski (BBM) inequality, the Stam-Cramer-Rao inequalities and the Fisher-Shannon product relation. The study establishes the validity of the entropic uncertainty relations for the motion of a free particle in three dimensions.
The position-momentum Shannon and R\'enyi uncertainty products of general quantum systems are shown to be bounded not only from below (through the known uncertainty relations), but also from above in terms of the Heisenberg-Kennard product $\ensuremath{\langle}{r}^{2}\ensuremath{\rangle}\ensuremath{\langle}{p}^{2}\ensuremath{\rangle}$. Moreover, the Cram\'er-Rao, Fisher-Shannon, and L\'opez-Ruiz, Mancini, and Calbet shape measures of complexity (whose lower bounds have been recently found) are also bounded from above. The improvement of these bounds for systems subject to spherically symmetric potentials is also explicitly given. Finally, applications to hydrogenic and oscillator-like systems are done.
The entropic moments of the probability density of a quantum system in position and momentum spaces describe not only some fundamental and/or experimentally accessible quantities of the system but also the entropic uncertainty measures of Rényi type, which allow one to find the most relevant mathematical formalizations of the position-momentum Heisenberg’s uncertainty principle, the entropic uncertainty relations. It is known that the solution of difficult three-dimensional problems can be very well approximated by a series development in 1/D in similar systems with a non-standard dimensionality D; moreover, several physical quantities of numerous atomic and molecular systems have been numerically shown to have values in the large-D limit comparable to the corresponding ones provided by the three-dimensional numerical self-consistent field methods. The D-dimensional hydrogenic atom is the main prototype of the physics of multidimensional many-electron systems. In this work, we rigorously determine the leading term of the Rényi entropies of the D-dimensional hydrogenic atom at the limit of large D. As a byproduct, we show that our results saturate the known position-momentum Rényi-entropy-based uncertainty relations.