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arXiv:1110.3337

Effective quantum equations for the semiclassical description of the Hydrogen atom

Guillermo Chacón‐Acosta, Héctor H. Hernández

Published Oct 14, 2011• 1 citation
arXivHTMLPDF

Abstract

We study the Hydrogen atom as a quantum mechanical system with a Coulomb like potential, with a semiclassical approach based on an effective description of quantum mechanics. This treatment allows us to describe the quantum state of the system as a system of infinite many classical equations for expectation values of configuration variables, their moments and quantum dispersions. It also provides a semiclassical description of the orbits and the evolution of observables and spreadings and their back-reaction on the evolution.

DOI
10.48550/arxiv.1110.3337

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We study the Hydrogen atom as a quantum mechanical system with a Coulomb like potential, with a semiclassical approach based on an effective description of quantum mechanics. This treatment allows us to describe the quantum state of the system as a system of infinite many classical equations for expectation values of configuration variables, their moments and quantum dispersions. It also provides a semiclassical description of the orbits and the evolution of observables and spreadings and their back-reaction on the evolution.
In this work, we study the quantum tunnel effect through a potential barrier within a semiclassical formulation of quantum mechanics based on expectation values of configuration variables and quantum dispersions as dynamical variables. The evolution of the system is given in terms of a dynamical system for which we are able to determine numerical effective trajectories for individual particles, similar to the Bohmian description of quantum mechanics. We obtain a complete description of the possible trajectories of the system, finding semiclassical reflected, tunneled and confined paths due to the appearance of an effective time-dependent potential.
Our work utilizes the quantum model of the hydrogen atom which is based on the Schrödinger equation with Coulomb potential. Specifically, we concentrate on the angular components of the wave eigenfunctions derived from this model. We consider the quantum states with n ≤ 4. In order to visualize the orbital shapes of these states, we built in the spherical coordinates system their 3D geometric representations. Furthermore, we use the corresponding spherical harmonics, to calculate the θ nodal values that describe the configurations of these orbital states.
In this work we analyze the effective evolution of a one dimensional Bose-Einstein Condensate (BEC) within a semiclassical description of quantum systems based on expectation values of quantum dispersions and physical observables, known as momentous quantum mechanics. We show that the most prominent features and physical parameters of the system can be determined from the dynamics of the corresponding semiclassical system, consisting of an extended phase space including original classical observables and quantum dispersions, and we also show that particle trajectories for expectation values of observables are a particular characteristic in this framework. We also demonstrate that interactions with several potentials can be implemented in an intuitive way.
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We analyze the problem of one dimensional quantum particle falling in a constant gravitational field, also known as the {\it bouncing ball}, employing a semiclassical approach known as momentous effective quantum mechanics. In this formalism the quantum evolution is described through a dynamical system of infinite dimension for the position, the momentum and all dispersions. Usually the system is truncated to have a finite dimensional one, however, in this case equations of motion decouple and the system can be solved. For a specific set of initial conditions we find that the time dependent dispersion in position is always around the classical trajectory.