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arXiv:1107.1018 · Physical Review E

Relaxation to equilibrium of the expectation values in macroscopic quantum systems

Takaaki Monnai

Published Jul 18, 2011• 6 citations
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Abstract

A quantum mechanical explanation of the relaxation to equilibrium is shown for macroscopic systems for nonintegrable cases and numerically verified. The macroscopic system is initially in an equilibrium state, subsequently externally perturbed during a finite time, and then isolated for a sufficiently long time. We show a quantitative explanation that the initial microcanonical state typically reaches a state whose expectation values are well approximated by the average over another microcanonical ensemble.

DOI
10.1103/physreve.84.011126

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A quantum mechanical explanation of the relaxation to equilibrium is shown for macroscopic systems for nonintegrable cases and numerically verified. The macroscopic system is initially in an equilibrium state, subsequently externally perturbed during a finite time, and then isolated for a sufficiently long time. We show a quantitative explanation that the initial microcanonical state typically reaches a state whose expectation values are well approximated by the average over another microcanonical ensemble.
In conclusion, by assuming that the initial state is prepared as a microcanonical ensemble, the actual state at time t=T can be replaced by another microcanonical ensemble in the evaluation of macroscopic quantities. The derivation is based on the high dimensionality of the Hilbert space, and restrictions for the system size dependence of observables as well as the perturbative treatment of the unitary transformation of the energy eigenstates. The validity of the uniformly random sampling assumption for [numerical formula] is numerically verified for a nonintegrable spin chain. It is also remarked that the initial state can be out of equilibrium, i.e. the initial density matrix is [numerical formula] with a unitary transformation U_0, since this can be regarded as the state evolved from an actual initial state [numerical formula].
The irreversible relaxation to equilibrium is explained for macroscopic quantum systems with an emphasis on the behavior of expectation values and extremely high dimensionality of the Hilbert space. We consider a large but isolated system that is initially out of equilibrium and eventually relaxes to equilibrium. The relaxation is described by the deviation of the expectation value of the quantity of interest from the long-time average. After relaxation, the amount of deviation from equilibrium is discussed based on probabilistic arguments, which are available for nonintegrable systems. We also evaluate how long the system stays near equilibrium.
We consider isolated many-body quantum systems which do not thermalize; i.e., expectation values approach an (approximately) steady longtime limit which disagrees with the microcanonical prediction of equilibrium statistical mechanics. A general analytical theory is worked out for the typical temporal relaxation behavior in such cases. The main prerequisites are initial conditions which appreciably populate many energy levels and do not give rise to significant spatial inhomogeneities on macroscopic scales. The theory explains very well the experimental and numerical findings in a trapped-ion quantum simulator exhibiting many-body localization, in ultracold atomic gases, and in integrable hard-core boson and XXZ models.
We propose a new approach to justify the use of the microcanonical ensemble for isolated macroscopic quantum systems. Since there are huge number of independent observables in a macroscopic system, we cannot see all of them. Actually what we observe can be written in a rather simple combination of local observables. Considering this limitation, we show that almost all states in a energy shell are practically indistinguishable from one another, and hence from the microcanonical ensemble. In particular, the expectation value of a macroscopic observable is very close to its microcanonical ensemble average for almost all states.
For a macroscopic, isolated quantum system in an unknown pure state, the expectation value of any given observable is shown to hardly deviate from the ensemble average with extremely high probability under generic equilibrium and nonequilibrium conditions. Special care is devoted to the uncontrollable microscopic details of the system state. For a subsystem weakly coupled to a large heat bath, the canonical ensemble is recovered under much more general and realistic assumptions than those implicit in the usual microcanonical description of the composite system at equilibrium.
We treat the problem of the approach to thermal equilibrium by only resorting to quantum dynamics of an isolated macroscopic system. Inspired by the two important works in 2009 and in 1929, we have noted that a condition we call "thermodynamic normality" for a macroscopic observable guarantees the approach to equilibrium (in the sense that a measurement of the observable at time ttt almost certainly yields a result close to the corresponding microcanonical average for a sufficiently long and typical ttt). A crucial point is that we make no assumptions on the initial state of the system, except that its energy is distributed close to a certain macroscopic value. We also present three (rather artificial) models in which the thermodynamic normality can be established, thus providing concrete examples in which the approach to equilibrium is rigorously justified. Note that this kind of results which hold for ANY initial state are never possible in classical systems. We are thus dealing with a mechanism which is peculiar to quantum systems. The present note is written in a self-contained (and hopefully readable) manner. It only requires basic knowledge in quantum physics and equilibrium statistical mechanics.