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arXiv:1105.4227 · Physical Review E

Ideal quantum gas in an expanding cavity: Nature of nonadiabatic force

Katsuhiro Nakamura, S. K. Avazbaev, Zarifboy A. Sobirov, Davron U. Matrasulov, Takaaki Monnai

Published Apr 28, 2011• 25 citations

Abstract

We consider a quantum gas of noninteracting particles confined in the expanding cavity and investigate the nature of the nonadiabatic force which is generated from the gas and acts on the cavity wall. First, with use of the time-dependent canonical transformation, which transforms the expanding cavity to the nonexpanding one, we can define the force operator. Second, applying the perturbative theory, which works when the cavity wall begins to move at time origin, we find that the nonadiabatic force is quadratic in the wall velocity and thereby does not break the time-reversal symmetry, in contrast with general belief. Finally, using an assembly of the transitionless quantum states, we obtain the nonadiabatic force exactly. The exact result justifies the validity of both the definition of the force operator and the issue of the perturbative theory. The mysterious mechanism of nonadiabatic transition with the use of transitionless quantum states is also explained. The study is done for both cases of the hard- and soft-wall confinement with the time-dependent confining length.

DOI: 10.1103/physreve.83.041133

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We consider a quantum gas of noninteracting particles confined in the expanding cavity and investigate the nature of the nonadiabatic force which is generated from the gas and acts on the cavity wall. First, with use of the time-dependent canonical transformation, which transforms the expanding cavity to the nonexpanding one, we can define the force operator. Second, applying the perturbative theory, which works when the cavity wall begins to move at time origin, we find that the nonadiabatic force is quadratic in the wall velocity and thereby does not break the time-reversal symmetry, in contrast with general belief. Finally, using an assembly of the transitionless quantum states, we obtain the nonadiabatic force exactly. The exact result justifies the validity of both the definition of the force operator and the issue of the perturbative theory. The mysterious mechanism of nonadiabatic transition with the use of transitionless quantum states is also explained. The study is done for both cases of the hard- and soft-wall confinement with the time-dependent confining length.

With use of the scheme of fast forward which realizes quasistatic or adiabatic dynamics in shortened timescale, we investigate a thermally isolated ideal quantum gas confined in a rapidly dilating one-dimensional (1D) cavity with the time-dependent size L=L(t). In the fast-forward variants of equation of states, i.e., Bernoulli's formula and Poisson's adiabatic equation, the force or 1D analog of pressure can be expressed as a function of the velocity (L[over ̇]) and acceleration (L[over ̈]) of L besides rapidly changing state variables like effective temperature (T) and L itself. The force is now a sum of nonadiabatic (NAD) and adiabatic contributions with the former caused by particles moving synchronously with kinetics of L and the latter by ideal bulk particles insensitive to such a kinetics. The ratio of NAD and adiabatic contributions does not depend on the particle number (N) in the case of the soft-wall confinement, whereas such a ratio is controllable in the case of hard-wall confinement. We also reveal the condition when the NAD contribution overwhelms the adiabatic one and thoroughly changes the standard form of the equilibrium equation of states.

We consider a heavy external object moving in an ideal gas of light particles. Collisions with the gas particles transfer momentum to the object, leading to a force that is proportional to the object's velocity but in the opposite direction. In an ideal classical gas at temperature T, the force acting on the object is proportional to T. Quantum statistics causes a deviation from the T-dependence and shows that the force scales with T2 at low temperatures. At T = 0, the force vanishes in a Bose gas but is finite in a Fermi gas.

The Schrödinger equation is solved for the case of a particle confined to a small region of a box with infinite walls. If walls of the well are moved, then, due to an effective quantum nonlocal interaction with the boundary, even though the particle is nowhere near the walls, it will be affected. It is shown that this force apart from a minus sign is equal to the expectation value of the gradient of the quantum potential for vanishing at the walls boundary condition. Variation of this force with time is studied. A selection of Bohmian trajectories of the confined particle is also computed.

Trajectories of a Bohmian particle confined in time-dependent cylindrical and spherical traps are computed for both contracting and expanding boxes. Quantum effective force is considered in arbitrary directions. It is seen that in contrast to the problem of a particle in an infinite rectangular box with one wall in motion, if particle initially is in an energy eigenstate of a tiny box the force is zero in all directions. Trajectories of a two-body system confined in the spherical trap are also computed for different statistics. Computations show that there are situations for which distance between bosons is greater than the fermions. However, results of average separation of the particles confirm our expectation about the statistics.

We study quantum dynamics of one-electron atom confined in a spherical impenetrable box with time-dependent radius. The behavior of the atomic electron interacting with the moving walls of the box is analyzed by computing average binding energy, average force and pressure. Linearly extending, contracting and harmonically breathing boxes are considered in the non-adiabatic regime i.e. when the wall of the box moves with high velocities. It is shown that linearly extending box leads to de-excitation of the atom, while the rapidly contracting box causes the creation of very high pressure on the atom and transition of the atomic electron into the unbound state. In harmonically breathing box diffusive excitation of atomic electron and ionization may occur in analogy with that for atom in a microwave field.