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arXiv:1105.3615

An analysis of states in the phase space: the anharmonic oscillator

Sebastiano Tosto

Published May 18, 2011• 2 citations
arXivHTMLPDF

Abstract

The paper introduces a simple quantum model to calculate in a general way allowed frequencies and energy levels of the anharmonic oscillator. The theoretical basis of the approach has been introduced in two early papers aimed to infer the properties of quantum systems exploiting the uncertainty principle only. For clarity the anharmonic oscillator is described having in mind the lattice oscillations of atoms/ions, yet quantum formalism of the model and approach have general character and can be extended to any oscillating system. The results show that the harmonic energy levels split into a complex system of energy levels dependent upon the number of anharmonic terms that characterize the oscillator.

DOI
10.48550/arxiv.1105.3615

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The paper introduces a simple quantum model to calculate in a general way allowed frequencies and energy levels of the anharmonic oscillator. The theoretical basis of the approach has been introduced in two early papers aimed to infer the properties of quantum systems exploiting the uncertainty principle only. For clarity the anharmonic oscillator is described having in mind the lattice oscillations of atoms/ions, yet quantum formalism of the model and approach have general character and can be extended to any oscillating system. The results show that the harmonic energy levels split into a complex system of energy levels dependent upon the number of anharmonic terms that characterize the oscillator.
In this article the anharmonic oscillator in quantum mechanics is discussed. First propagators of less complex systems are found by using the path integral method. With perturbation theory an expression, up to any order, has been found for the vacuum propagator of the anharmonic oscillator. In this article only the first and second order were calculated and by looking at the n-pointfunctions the Feynman diagrams of these orders were found. It appears that the anharmonic term up to first order causes a change in the frequency of the system. Looking at second order perturbation theory gives five diagrams. The first four of these diagrams are simple diagrams and again these diagrams alter the frequency of the system. The change in the frequency looks a lot like a series and it is possible to ’guess’ a general expression up to any order for all simple diagrams. This expression seems to fit qualitatively for higher orders however the prefactors were not checked nor is there a proof formulated. The fifth diagrams is a complex diagram and this diagram has not been solved in a satisfying way. Finally some recommendations for additional research are given.
The present review is devoted to the study of certain aspects of anharmonic, time-dependent and damped oscillator(s) system using different theoretical techniques. A theoretical understanding of these systems is important for application in many problems in physics, mechanics and other fields. We discuss in detail the difficulties in the theoretical analysis of the problem. In particular we discuss here the regular, well-behaved perturbative solution, the large quantum number behaviour of anharmonic oscillator(s) using the technique of coherent states, exact solution of quantum anharmonic oscillators, the electromagnetic radiation emitted by a charged particle executing damped anharmonic oscillator motion using Krylov-Bogoliubov approximation method, use of invariants to obtain solution and coherent states of time-dependent oscillator(s), the derivation of perturbative frequencies of a damped coupled anharmonic oscillators system using suitable canonical transformation in the framework of Hamilton-Jacobi formalism and the quantisation and construction of coherent states of a damped oscillator using time-dependent operators.
Hilbert Spaces of anharmonic oscillators are studied. It is shown that the eigenvalue structure of all anharmonic oscillators have the same general form and are dependent on only the ground state energy of the system and a single function \\lambda(H) of the Hamiltonian H whose form depends explicitly on H. It is also found that the Hilbert Space of the anharmonic oscillator is unitarily ``inequivalent'' to the Hilbert Space of the simple harmonic oscillator, providing an explicit example of Haag's Theorem.
In this article, for pedagogical purposes we have discussed the application of nondegenerate perturbation theory up to the third order to compute energy eigenvalues and wave functions for the quantum anharmonic oscillator. Energy levels of a single quartic oscillator for 𝜆 values in range of 0.1-1 are given. Perturbed and non-perturbed wave functions of the levels up to the fourth excited level are compared. Ground, first and second excited energy levels are also calculated by applying finite differences method and, results are compared with the ones obtained via perturbation theory. It is found that perturbation theory gives comparable results only for a small 𝜆 parameter and for the ground state. The quartic term in the Hamiltonian of the anharmonic oscillator leads to a more effective confinement of the particle which is deduced from the plots of wavefunctions and probability distributions. Meanwhile, the number of zero crossing nodes of the wavefunctions increases as the energy level increases, which is an expected result for both the harmonic and anharmonic oscillator.
This is an investigation of the energy levels and wavefunctions of an anharmonic oscillator characterised by the potential 1/2 (omega 2 q 2 + lambda q 4 ). As a lowest-order approximation an extremely simple formula for energy levels, E i (0) = (i + 1/2)1/4(3/alpha i + alpha i ), is derived (i being the quantum number of the energy level), which covers any (lambda, i). alpha i is the real positive root of a cubic equation: y i alpha i 3 + alpha i 2 - 1 = 0, with y i = 6lambda(2i 2 + 2i + 1)/(2i+1). This formula reproduces the exact energy levels within an error of about 1% for any ( lambda ,i) (the worst case is 2% for i = 0, lambda to infinity). Systematically higher orders of this perturbation theory are developed, which contains the 'usual' perturbation theory for the limiting case of small lambda , but this perturbation theory is valid for any (i, lambda). The second-order perturbation theory reduces the errors of our lowest-order results by a factor of about 1/5 in general. Various ranges (large, intermediate, small) of (i, lambda ) are investigated and compared with the exact values obtained by the Montroll group (1975, 1978). For i = 0, 1, even the fourth-order perturbation calculation can be elaborated explicitly, which reduces the error to about 0.01% for any lambda . For small lambda it gives correct numerical coefficients up to lambda 4 terms, as it should.