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arXiv:1104.1294 · Journal of Physics Condensed Matter

Quantum Zeno and anti-Zeno effects in surface diffusion of interacting adsorbates

H C Peñate-Rodríguez, R Martínez-Casado, Germán A. Rojas-Lorenzo, Ángel S. Sanz, Salvador Miret-Artés

Published Feb 21, 2012• 5 citations
arXivHTMLPDF

Abstract

Surface diffusion of interacting adsorbates is here analyzed within the context of two fundamental phenomena of quantum dynamics, namely the quantum Zeno effect and the anti-Zeno effect. The physical implications of these effects are introduced here in a rather simple and general manner within the framework of non-selective measurements and for two (surface) temperature regimes: high and very low (including zero temperature). The quantum intermediate scattering function describing the adsorbate diffusion process is then evaluated for flat surfaces, since it is fully analytical in this case. Finally, a generalization to corrugated surfaces is also discussed. In this regard, it is found that, considering a Markovian framework and high surface temperatures, the anti-Zeno effect has already been observed, though not recognized as such.

DOI
10.1088/0953-8984/24/10/104013

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Stochastic wave function formalism is briefly introduced and applied to study the dynamics of open quantum systems; in particular, the diffusion of Xe atoms adsorbed on a Pt(111) surface. By starting from a Lindblad functional and within the microscopic Caldeira–Leggett model for linear dissipation, a stochastic differential equation (Ito^-type differential equation) is straightforwardly obtained. The so-called intermediate scattering function within the ballistic regime is obtained, which is observable in Helium spin echo experiments. An ideal two-dimensional gas has been observed in this regime, leading to this function behaving as a Gaussian function. The influence of surface–adsorbate interaction is also analyzed by using the potential of two interactions describing flat and corrugated surfaces. Very low surface coverages are considered and, therefore, the adsorbate–adsorbate interaction is safely neglected. Good agreement is observed when our numerical results are compared with the corresponding experimental results and previous standard Langevin simulations.

Mathematics•Feb 11, 2021•3 citations
Surface diffusion of interacting adsorbates is here analyzed within the context of two fundamental phenomena of quantum dynamics, namely the quantum Zeno effect and the anti-Zeno effect. The physical implications of these effects are introduced here in a rather simple and general manner within the framework of non-selective measurements and for two (surface) temperature regimes: high and very low (including zero temperature). The quantum intermediate scattering function describing the adsorbate diffusion process is then evaluated for flat surfaces, since it is fully analytical in this case. Finally, a generalization to corrugated surfaces is also discussed. In this regard, it is found that, considering a Markovian framework and high surface temperatures, the anti-Zeno effect has already been observed, though not recognized as such.
Surface diffusion of small adsorbates is analyzed in terms of the so-called intermediate scattering function and dynamic structure factor, observables in experiments using the well-known quasielastic Helium atom scattering and Helium spin echo techniques. The linear theory applied is an extension of the neutron scattering due to van Hove and considers the time evolution of the position of the adsorbates in the surface. This approach allows us to use a stochastic trajectory description following the classical, quantum and Bohmian frameworks. Three different regimes of motion are clearly identified in the diffusion process: ballistic, Brownian and intermediate which are well characterized, for the first two regimes, through the mean square displacements and Einstein relation for the diffusion constant. The Langevin formalism is used by considering Ohmic friction, moderate surface temperatures and small coverages. In the Bohmian framework, analyzed here, the starting point is the so-called Schrödinger-Langevin equation which is a nonlinear, logarithmic differential equation. By assuming a Gaussian function for the probability density, the corresponding quantum stochastic trajectories are given by a dressing scheme consisting of a classical stochastic trajectory followed by the center of the Gaussian wave packet, and issued from solving the Langevin equation (particle property), plus the time evolution of its width governed by the damped Pinney differential equation (wave property). The Bohmian velocity autocorrelation function is the same as the classical one when the initial spread rate is assumed to be zero. If not, in the diffusion regime, the Brownian-Bohmian motion shows a weak anomalous diffusion.
We investigate the quantum Zeno and anti-Zeno effects in quantum dissipative systems by employing a hierarchical equations of motion approach which is beyond the usual Markovian approximation, the rotating wave approximation, and the perturbative approximation. The quantum Zeno and anti-Zeno dynamics of a biased qubit-boson model and a biased qutrit-boson model are provided as illustrative examples. It is found that (i) there exists multiple Zeno--anti-Zeno crossover phenomena, (ii) the non-Markovian characteristic of the bath may be favorable for the accessibility of the Zeno dynamics, and (iii) high bath temperature may add the difficulty in observing the quantum Zeno effect in quantum dissipative systems.
Abstract The so-called quantum-to-classical transition is studied in the surface diffusion dynamics. This continuous and smooth transition is carried out from the Liouville-von Neumann equation by scaling Planck’s constant. As an application, the Brownian motion of an adsorbate on a flat surface is analyzed within the Caldeira–Leggett master equation formalism for the reduced density matrix and the two extreme time behaviors, the ballistic and diffusive motions. In the ballistic time regime, the intermediate scattering function displays a Gaussian function which is governed by the thermal velocity in the classical regime, whereas in the quantum regime, by the initial spreading velocity of the wave packet. Adsorbates behave as a classical or quantum ideal gas. Finally, in the diffusive regime, and starting from the Chudley–Elliott model, the well-known H-function is calculated for three different surface temperatures in the diffusion of H and D on a Pt(111) surface. The main goal of this analysis is whether one can discriminate the irreversibility coming from tunneling or thermal activation diffusion.
In studies of the quantum Zeno and anti-Zeno effects, it is usual to consider rapid projective measurements with equal time intervals being performed on the system to check whether or not the system is in the initial state. These projective measurements are selective measurements in the sense that the measurement results are read out and only the case where all the measurement results correspond to the initial state is considered in the analysis of the effect of the measurements. In this paper, we extend such a treatment to consider the effect of repeated non-selective measurements - only the final measurement is required to correspond to the initial state, while we do not know the results of the intermediate measurements. We present a general formalism to derive the effective decay rate of the initial quantum state with such non-selective measurements. Importantly, we show that there is a difference between using non-selective measurements and the usual approach of considering only selective measurements only if we go beyond the weak system-environment coupling regime in models other than the usual population decay models. As such, we then apply our formalism to investigate the quantum Zeno and anti-Zeno effects for three exactly solvable system-environment models: a single two-level system undergoing dephasing, a single two-level system interacting with an environment of two-level systems, and a large spin undergoing dephasing. Our results show that the quantum Zeno and anti-Zeno effects in the presence of non-selective measurements can differ very significantly as compared to the repeated selective measurement scenario.
The quantum Zeno effect is a striking feature of quantum mechanics with foundational implications and practical applications in quantum control, error suppression, and error correction. In recent years, the effect has branched off into a variety of different interpretations, making it easy to miss its underlying unifying features. In particular, the quantum Zeno effect has been studied in the context of both selective and nonselective measurements; for both pulsed and continuous interactions; for suppression and enhancement of decay (Zeno / anti-Zeno effects); and even in the absence of measurement entirely. This tutorial presents a unified picture of these effects by examining how they all arise in the pedagogical example of a driven qubit subjected to measurements or dissipation. Zeno and anti-Zeno effects appear as regimes of a unified effect that appears when a measurement-like process competes with non-commuting evolution. The current landscape of Zeno and anti-Zeno effects is examined through this unifying lens, with a focus on experimental applications and implementations. Thus, this tutorial is ideal for new researchers interested in learning about cutting-edge tools in quantum control and measurement, while remaining highly relevant to quantum computing specialists aiming to understand the quantum Zeno effect's applications in adjacent subfields or apply it in a novel way in their own research. The quantum Zeno effect is found to be both ubiquitous and essential for the future of near-term quantum computing.
Stochastic wave function formalism is briefly introduced and applied to study the dynamics of open quantum systems; in particular, the diffusion of Xe atoms adsorbed on a Pt(111) surface. By starting from a Lindblad functional and within the microscopic Caldeira–Leggett model for linear dissipation, a stochastic differential equation (Ito^-type differential equation) is straightforwardly obtained. The so-called intermediate scattering function within the ballistic regime is obtained, which is observable in Helium spin echo experiments. An ideal two-dimensional gas has been observed in this regime, leading to this function behaving as a Gaussian function. The influence of surface–adsorbate interaction is also analyzed by using the potential of two interactions describing flat and corrugated surfaces. Very low surface coverages are considered and, therefore, the adsorbate–adsorbate interaction is safely neglected. Good agreement is observed when our numerical results are compared with the corresponding experimental results and previous standard Langevin simulations.